生物炭的制备、改性及其在环境修复中应用的研究进展

doi:10.16085/j.issn.1000-6613.2020-1210

摘要/Abstract

摘要：

介绍了生物炭的制备、改性及表征，尤其是在环境修复中的应用。阐述了生物炭常用的制备方法包括热解法、气化法和水热碳化法，指出生物炭的制备原料和条件决定了生物炭的吸附性能。为了提高生物炭的吸附性能，常通过酸、碱、氧化剂、金属氧化物、有机化合物、紫外辐射、等离子体、复合材料、蒸汽及气体吹扫等方式对其进行改性处理，而改性方法的选择主要取决于应用的环境领域。虽然生物炭已在土壤修复及改良、固碳、有机固废堆肥、废水净化及大气污染治理等领域取得了良好的效果，但是生物炭的固碳效果还需要在不同土壤条件进一步验证，生物炭提高土壤质量的原因还需要进一步研究，生物炭去除土壤中有机污染物的作用机理也有待进一步探明。此外，利用生物炭进行环境修复时，应注意生物炭的稳定性问题，以免造成二次污染。综上所述，生物炭在环境修复中具有广阔的应用前景，但也存在一些问题和挑战需要解决。

关键词: 生物炭, 表征, 改性, 吸附, 环境修复

Abstract:

This review introduces the production, modification and characterization of biochar, especially its application in environment remediation. Pyrolysis, gasification and hydrothermal carbonization are the common methods for biochar production. The adsorption properties of biochar are influenced by the raw materials and production conditions. To improve the adsorption properties of biochar, it can be modified by acid, alkali, oxidizing agents, metal ions, organic compound, ultraviolet radiation, non-thermal plasma, combined materials, steam and gas purging. The selected modification methods depend on the fields of environment application. Although biochar has been used for soil remediation and improvement, carbon sequestration, organic solid waste compost, decontamination of water and wastewater, air pollution control with great success, however, whether biochar could sequester carbon needs further investigation at different soil conditions; the reasons why biochar improves soil quality need to be further study; the mechanism of organic pollutants removal by biochar in soils needs further investigation. In addition, more attention should be paid to the stability of biochar to avoid secondary pollution when biochar is used for environment remediation. In summary, biochar has a broad application prospect in environment remediation but there are still some problems and challenges to be solved.

Key words: biochar, characterization, modification, adsorption, environment remediation

中图分类号:

王申宛, 郑晓燕, 校导, 郑丽丽, 杨旸, 艾斌凌, 钟爽, 盛占武. 生物炭的制备、改性及其在环境修复中应用的研究进展[J]. 化工进展, 2020, 39(S2): 352-361.

Shenwan WANG, Xiaoyan ZHENG, Dao XIAO, Lili ZHENG, Yang YANG, Binling AI, Shuang ZHONG, Zhanwu SHENG. Research progress of production, modification and application in environment remediation of biochar[J]. Chemical Industry and Engineering Progress, 2020, 39(S2): 352-361.

图/表 6

参考文献 60

1	RIZWAN Muhammad, Shafaqat ALI, QAYYUM Muhammad Farooq, et al. Mechanisms of biochar-mediated alleviation of toxicity of trace elements in plants: a critical review[J]. Environmental Science and Pollution Research International, 2015, 23(3): 2230-2248.
2	YI Yunqiang, HUANG Zhexi, LU Baizhou, et al. Magnetic biochar for environmental remediation: a review[J]. Bioresource Technology, 2020, 298: 122468.
3	Jin-Sun CHA, PARK Sung-Hoon, JUNG Sang-Chu, et al. Production and utilization of biochar: a review[J]. Journal of Industrial and Engineering Chemistry, 2016, 40: 1-15.
4	PONNUSAMY Vinoth Kumar, SENTHIL Nagappan, BHOSALE Rahul R, et al. Review on sustainable production of biochar through hydrothermal liquefaction: physico-chemical properties and applications[J]. Bioresource Technology, 2020, 310: 123414.
5	BENAVENTE Verónica, FULLANA Andres. Torrefaction of olive mill waste[J]. Biomass and Bioenergy, 2015, 73: 186-194.
6	王思源, 申健, 李盟军, 等. 不同改性生物炭功能结构特征及其对铵氮吸附的影响[J]. 生态环境学报, 2019, 28(5): 1037-1045.
	WANG Siyuan, SHEN Jian, LI Mengjun, et al. Functional and structural characteristics of different modified biochar and its impacts on ammonium nitrogen adsorption[J]. Ecology and Environmental Sciences, 2019, 28(5): 1037-1045.
7	徐大勇，张苗，杨伟伟，等. 氧化铝改性污泥生物炭粒制备及其对Pb(Ⅱ)的吸附特性[J]. 化工进展, 2020, 39(3): 1153-1166.
	XU Dayong，ZHANG Miao，YANG Weiwei, et al. Preparation of alumina modified sludge biochar coal particles and their adsorption characteristics for Pb(Ⅱ)[J]. Chemical Industry and Engineering Progress, 2020, 39(3): 1153-1166.
8	HE Rao, YUAN Xingzhong, HUANG Zhongliang, et al. Activated biochar with iron-loading and its application in removing Cr(Ⅵ) from aqueous solution[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2019, 579: 123642.
9	ZHANG Junjie, SHAO Jingai, JIN Qianzheng, et al. Effect of deashing on activation process and lead adsorption capacities of sludge-based biochar[J]. Science of the Total Environment, 2020, 716:137016.
10	GHANIM Bashir, MUENANE John G, Lisa O'DONGHUE, et al. Removal of vanadium from aqueous solution using a red mud modified saw dust biochar[J]. Journal of Water Process Engineering, 2020, 33: 101076.
11	LI Yanfei, ZIMMERMAN Andrew R, HE Feng, et al. Solvent-free synthesis of magnetic biochar and activated carbon through ball-mill extrusion with Fe₃O₄ nanoparticles for enhancing adsorption of methylene blue[J]. Science of the Total Environment, 2020, 722: 137972.
12	XIANG Wei, ZHANG Xueyang, CHEN Kuiqing, et al. Enhanced adsorption performance and governing mechanisms of ball-milled biochar for the removal of volatile organic compounds (VOCs)[J]. Chemical Engineering Journal, 2020, 385: 123842.
13	WANG Shuqi, ZHANG Han, HUANG Haiyan, et al. Influence of temperature and residence time on characteristics of biochars derived from agricultural residues: a comprehensive evaluation[J]. Process Safety and Environmental Protection, 2020, 139: 218-229.
14	ZHANG Peng, LIU Shaobo, TAN Xiaofei, et al. Microwave-assisted chemical modification method for surface regulation of biochar and its application for estrogen removal[J]. Process Safety and Environmental Protection, 2019, 128: 329-341.
15	PENG Peng, LANG Yinhai, WANG Xiaomei. Adsorption behavior and mechanism of pentachlorophenol on reed biochars: pH effect, pyrolysis temperature, hydrochloric acid treatment and isotherms[J]. Ecological Engineering, 2016, 90: 225-233.
16	MAHDI Zainab, HANANDEH Ali El, YU Qiming Jimmy. Preparation, characterization and application of surface modified biochar from date seed for improved lead, copper, and nickel removal from aqueous solutions[J]. Journal of Environmental Chemical Engineering, 2019, 7(5): 103379.
17	WANG Yan, LIU Ronghou. H₂O₂ treatment enhanced the heavy metals removal by manure biochar in aqueous solutions[J]. Science of the Total Environment, 2018, 628/629: 1139-1148.
18	HUFF Matthew D, James W LEE. Biochar-surface oxygenation with hydrogen peroxide[J]. Journal of Environmental Management, 2016, 165(1): 17-21.
19	余伟光，黎吉辉，王敦，等. 香蕉茎秆生物炭的制备及其对铜离子的吸附特性[J]. 化工进展, 2017, 36(4): 1499-1505.
	YU Weiguang，LI Jihui，WANG Dun, et al. The preparation of biochar from pre-oxidation of banana stem and its adsorption of Cu²⁺[J]. Chemical Industry and Engineering Progress, 2017, 36(4): 1499-1505.
20	ODRIGUEZ-NARVAEZ Oscar M, PERALTA-HERNANDEZ Juan Manuel, GOONETILLEKE Ashantha, et al. Biochar-supported nanomaterials for environmental applications[J]. Journal of Industrial and Engineering Chemistry, 2019, 78: 21-33.
21	TURAN Veysel, KHAN Shahbaz Ali, MAHMOOD Ur Rahman, et al. Promoting the productivity and quality of brinjal aligned with heavy metals immobilization in a wastewater irrigated heavy metal polluted soil with biochar and chitosan[J]. Ecotoxicology and Environmental Safety, 2018, 161(10): 409-419.
22	李桥, 高屿涛, 姜蔚, 等. 紫外辐照改性生物炭对土壤中Cd的稳定化效果[J]. 环境工程学报, 2017, 11(10): 5708-5714.
	LI Qiao, GAO Yutao, JIANG Wei, et al. Stabilization of Cd contaminated soil by ultraviolet irradiation modified biochar[J]. Chinese Journal of Environmental Engineering, 2017, 11(10): 5708-5714.
23	ZHANG Huicong, WANG Tao, Zifeng SUI, et al. Enhanced mercury removal by transplanting sulfur-containing functional groups to biochar through plasma[J]. Fuel, 2019, 253: 703-712.
24	WANG Tao, LIU Jun, ZHANG Yongsheng, et al. Use of a non-thermal plasma technique to increase the number of chlorine active sites on biochar for improved mercury removal[J]. Chemical Engineering Journal, 2018, 331: 536-544.
25	ZHANG Huicong, WANG Tao, ZHANG Yongsheng, et al. Promotional effect of NH₃ on mercury removal over biochar thorough chlorine functional group transformation[J]. Journal of Cleaner Production, 2020, 257: 120598.
26	高瑞丽, 唐茂, 付庆灵, 等. 生物炭、蒙脱石及其混合添加对复合污染土壤中重金属形态的影响[J]. 环境科学, 2017, 38(1):361-367.
	GAO Ruili, TANG Mao, FU Qingling, et al. Fractions transformation of heavy metals in compound contaminated soil treated with biochar, montmorillonite and mixed addition[J]. Environmental Science, 2017, 38(1): 361-367.
27	王海, 阳柠灿, 邱木清. 花生壳生物炭-黏土吸附水中的Cr(Ⅵ)(英文)[J]. 无机材料学报, 2020, 35(3):301-307.
	WANG Hai, YANG Ningcan, QIU Muqing. Adsorption of Cr(Ⅵ) from aqueous solution by biochar-clay derived from clay and peanut shell[J]. Journal of Inorganic Materials, 2020, 35(3):301-307.
28	王靖宜, 王丽, 张文龙, 等. 生物炭基复合材料制备及其对水体特征污染物的吸附性能[J]. 化工进展. 2019, 38(8): 3838-3851.
	WANG Jingyi，WANG Li，ZHANG Wenlong, et al. Preparation of biochar-based composites and their adsorption performances for characteristic contaminants in wastewater[J]. Chemical Industry and Engineering Progress. 2019, 38(8): 3838-3851.
29	陈雪娇, 林启美, 肖弘扬, 等. 改性油菜秸秆生物质炭吸附/解吸Cd²⁺特征[J]. 农业工程学报, 2019, 35(18): 220-227.
	CHEN Xuejiao, LIN Qimei, XIAO Hongyang, et al. Characteristics of Cd²⁺sorption/desorption of modified oilrape straw biochar[J]. Transactions of the Chinese Society of Agricultural Engineering, 2019, 35(18): 220-227.
30	KIM Youkwan, Jeong-Ik OH, VITHANAGE Meththika, et al. Modification of biochar properties using CO₂[J]. Chemical Engineering Journal, 2019, 372: 383-389.
31	MIAN Md Manik, LIU Guijian, YOUSAF Balal, et al. Simultaneous functionalization and magnetization of biochar via NH₃ ambiance pyrolysis for efficient removal of Cr(Ⅵ)[J]. Chemosphere, 2018, 208: 712-721.
32	Seunghyun YOO, KELLEY Stephen S, TILOTTA David C, et al. Structural characterization of loblolly pine derived biochar by X-ray diffraction and electron energy loss spectroscopy[J]. ACS Sustainable Chemistry & Engineering, 2018, 6(2): 2621-2629.
33	WANG Jia, LIAO Zhuwei, IFTHIKAR Jerosha, et al. One-step preparation and application of magnetic sludge-derived biochar on acid orange 7 removal via both adsorption and persulfate-based oxidation[J]. RSC Advances, 2017, 7(30): 18696-18796.
34	Ling Yu KAI, BENG Fye Lau, Loke Show PAU. Recent developments on algal biochar production and characterization[J]. Bioresource Technology, 2017, 246: 2-11.
35	YU Zhihong, QIU Weiwen, WANG Fei, et al. Effects of manganese oxide-modified biochar composites on arsenic speciation and accumulation in an indica rice (Oryza sativa L.) cultivar[J]. Chemosphere, 2017, 168: 341-349.
36	Beatriz GÁMIZ, VELARDE Pilar, SPOKAS Kurt A, et al. Biochar soil additions affect herbicide fate: importance of application timing and feedstock species[J]. Journal of Agricultural and Food Chemistry, 2017, 65(15): 3109-3117.
37	JIA Hui, LI Jian, LI Yi, et al. The remediation of PAH contaminated sediment with mangrove plant and its derived biochars[J]. Journal of Environmental Management, 2020, 268: 285-292.
38	CEDERLUND Harald, Elisabet BÖRJESSON, John STENSTRÖM. Effects of a wood-based biochar on the leaching of pesticides chlorpyrifos, diuron, glyphosate and MCPA[J]. Journal of Environmental Management, 2017, 191: 28-34.
39	GAO Ruili, HU Hongqing, FU Qingling, et al. Remediation of Pb, Cd, and Cu contaminated soil by co-pyrolysis biochar derived from rape straw and orthophosphate: speciation transformation, risk evaluation and mechanism inquiry[J]. Science of the Total Environment, 2020, 730: 139119.
40	LU Kouping, YANG Xing, GERTY Gielen, et al. Effect of bamboo and rice straw biochars on the mobility and redistribution of heavy metals (Cd, Cu, Pb and Zn) in contaminated soil[J]. Journal of Environmental Management, 2017, 186(2): 285-292.
41	SUO Fengyue, YOU Xiangwei, MA Yongqiang, et al. Rapid removal of triazine pesticides by P doped biochar and the adsorption mechanism[J]. Chemosphere, 2019, 235(9): 918-925.
42	Honghong LYU, ZHAO Hang, TANG Jingchun, et al. Immobilization of hexavalent chromium in contaminated soils using biochar supported nanoscale iron sulfide composite[J]. Chemosphere, 2018, 194: 360-369.
43	HUFF Matthew D, MARSHALL Sarah, SAEED Haitham A, et al. Surface oxygenation of biochar through ozonization for dramatically enhancing cation exchange capacity[J]. Bioresources and Bioprocessing, 2018, 5(1):1-9.
44	HE Kang, HE Guo, WANG Congpeng, et al. Biochar amendment ameliorates soil properties and promotes miscanthus growth in a coastal saline-alkali soil[J]. Applied Soil Ecology, 2020, 155(10): 103674.
45	ZHU Qian, KONG Lingjian, SHAN Yuzi, et al. Effect of biochar on grain yield and leaf photosynthetic physiology of soybean cultivars with different phosphorus efficiencies[J]. Journal of Integrative Agriculture, 2019, 18(10): 2242-2254.
46	FARRAR Michael B, WALLACE Helen M, XU Chengyuan, et al. Short-term effects of organo-mineral enriched biochar fertiliser on ginger yield and nutrient cycling[J]. Journal of Soils and Sediments, 2019, 19(2): 668-682.
47	LIN Lu, JIANG Wenbin, XU Pei. Comparative study on pharmaceuticals adsorption in reclaimed water desalination concentrate using biochar: impact of salts and organic matter[J]. The Science of the Total Environment, 2017, 601/602: 857-864.
48	刘剑楠, 封吉猛, 李丹, 等. 牛粪和核桃壳生物炭对水溶液中Cd²⁺和Zn²⁺的吸附研究[J]. 农业环境科学学报, 2019, 38(5): 1142-1150.
	LIU Jiannan, FENG Jimeng, LI Dan, et al. The adsorption of Cd²⁺and Zn²⁺in aqueous solutions by dairy manure and walnut shell biochar[J]. Journal of Agro-Environment Science, 2019,38(5):1142-1150.
49	WEI Anlei, MA Jing, CHEN Jingjing, et al. Enhanced nitrate removal and high selectivity towards dinitrogen for groundwater remediation using biochar-supported nano zero-valent iron[J]. Chemical Engineering Journal, 2018, 353: 595-605.
50	LIU Juan, CHENG Wanyi, YANG Xiaoyu, et al. Modification of biochar with silicon by one-step sintering and understanding of adsorption mechanism on copper ions[J]. The Science of the Total Environment, 2020, 704: 135252.
51	WANG Zhanghong, SHEN Dekui, SHEN Fei, et al. Phosphate adsorption on lanthanum loaded biochar[J]. Chemosphere, 2016, 150: 1-7.
52	HUANG Jinsheng, ZIMMERMAN Andrew R, CHEN Hao, et al. Ball milled biochar effectively removes sulfamethoxazole and sulfapyridine antibiotics from water and wastewater[J]. Environmental Pollution, 2020, 258: 113809.
53	牛强. 等离子体氧化-活性炭吸附技术脱除燃煤烟气中SO₂、NO和Hg⁰的实验研究[D]. 厦门: 厦门大学, 2017.
	NIU Qiang. Experimental study on the removal of SO₂, NO and Hg⁰ from coal-fired flue gas by plasma oxidation-activated carbon adsorption technology[D]. Xiamen: Xiamen University, 2017.
54	LIU Yuxue, GAO Chengxiang, WANG Yuying, et al. Vermiculite modification increases carbon retention and stability of rice straw biochar at different carbonization temperatures[J]. Journal of Cleaner Production, 2020, 254: 120111.
55	GAO Suduan, DOLL David A, STANGHELLINI Michael S, et al. Deep injection and the potential of biochar to reduce fumigant emissions and effects on nematode control[J]. Journal of Environmental Management, 2018, 223: 469-477.
56	SÁNCHEZ-MONEDERO M A, SÁNCHEZ-GARCÍA M, ALBURQUERQUE J A, et al. Biochar reduces volatile organic compounds generated during chicken manure composting[J]. Bioresource Technology, 2019, 288: 121584.
57	ZAINUDIN Mohd Huzairi, MUSTAPHA Nurul Asyifah, MAEDA Toshinari, et al. Biochar enhanced the nitrifying and denitrifying bacterial communities during the composting of poultry manure and rice straw[J]. Waste Management, 2020, 106: 240-249.
58	HUANG Mei, LI Zhongwu, LUO Ninglin, et al. Application potential of biochar in environment: insight from degradation of biochar-derived DOM and complexation of DOM with heavy metals[J]. Science of the Total Environment, 2019, 646: 220-228.
59	RUAN Xiuxiu, SUN Yuqing, DU Weimeng, et al. Formation, characteristics, and applications of environmentally persistent free radicals in biochars: a review[J]. Bioresource Technology, 2019, 281: 457-468.
60	DONG Chengdi, CHEN Chiuwen, TSAI Meiling, et al. Degradation of 4-nonylphenol in marine sediments by persulfate over magnetically modified biochars[J]. Bioresource Technology, 2019, 281: 143-148.

制备方法	温度	产物	操作	特点
热解	300～900℃	固体、液体、气体	限氧条件下，将原料放入反应容器，达到所需温度后反应或待原料达到所需温度后放入反应容器	速度慢、产量高
气化	＞700℃	固体、液体、气体	利用气化剂氧化原料	产量低于热解法
水热炭化	＜250℃	固体、液体	将原料放在反应容器中与水混合，然后升高温度和压力	产量高于热解和气化法
快速炭化	300～600℃	固体、气体	在1～2MPa压力条件下反应	反应时间通常为30min
烘焙炭化	200～300℃	疏水性固体	在限氧条件下反应	产物氧碳比低、吸附性差

制备方法	温度	产物	操作	特点
热解	300～900℃	固体、液体、气体	限氧条件下，将原料放入反应容器，达到所需温度后反应或待原料达到所需温度后放入反应容器	速度慢、产量高
气化	＞700℃	固体、液体、气体	利用气化剂氧化原料	产量低于热解法
水热炭化	＜250℃	固体、液体	将原料放在反应容器中与水混合，然后升高温度和压力	产量高于热解和气化法
快速炭化	300～600℃	固体、气体	在1～2MPa压力条件下反应	反应时间通常为30min
烘焙炭化	200～300℃	疏水性固体	在限氧条件下反应	产物氧碳比低、吸附性差

原料	制备温度/℃	pH	有机碳含量/%	官能团	比表面积/m^-1·g^-1	参考文献
小麦秸秆	450	8.34	42.90	OH、CO、CC、CO、CH、CC、SO	0.93	[6]
污泥	500	6.76	16.82	CC、CO、CO、CN	34.348	[7]
竹子	675	9.4	58.43	OH、CH、CO	13.9	[8]
牛粪	700	6.04	47.66	CH、OH、COOH、CO	3.153	[9]
核桃	700	9.42	47.67	CH、OH、COOH、CO	4.631	[9]
木屑	550	6.2	41.00	CC、CO、CO、CN、CO、COH	9.6	[10]
山核桃	600	8.4	83.50	CC、CO、COH、CC、FeO、OH	277.4	[11]
山核桃木	600	7.1	69.10	OH、CH、CC、CO	221.5	[12]

原料	制备温度/℃	pH	有机碳含量/%	官能团	比表面积/m^-1·g^-1	参考文献
小麦秸秆	450	8.34	42.90	OH、CO、CC、CO、CH、CC、SO	0.93	[6]
污泥	500	6.76	16.82	CC、CO、CO、CN	34.348	[7]
竹子	675	9.4	58.43	OH、CH、CO	13.9	[8]
牛粪	700	6.04	47.66	CH、OH、COOH、CO	3.153	[9]
核桃	700	9.42	47.67	CH、OH、COOH、CO	4.631	[9]
木屑	550	6.2	41.00	CC、CO、CO、CN、CO、COH	9.6	[10]
山核桃	600	8.4	83.50	CC、CO、COH、CC、FeO、OH	277.4	[11]
山核桃木	600	7.1	69.10	OH、CH、CC、CO	221.5	[12]

[1]	王胜岩, 邓帅, 赵睿恺. 变电吸附二氧化碳捕集技术研究进展[J]. 化工进展, 2023, 42(S1): 233-245.
[2]	时永兴, 林刚, 孙晓航, 蒋韦庚, 乔大伟, 颜彬航. 二氧化碳加氢制甲醇过程中铜基催化剂活性位点研究进展[J]. 化工进展, 2023, 42(S1): 287-298.
[3]	王家庆, 宋广伟, 李强, 郭帅成, DAI Qingli. 橡胶混凝土界面改性方法及性能提升路径[J]. 化工进展, 2023, 42(S1): 328-343.
[4]	戴欢涛, 曹苓玉, 游新秀, 徐浩亮, 汪涛, 项玮, 张学杨. 木质素浸渍柚子皮生物炭吸附CO₂特性[J]. 化工进展, 2023, 42(S1): 356-363.
[5]	崔守成, 徐洪波, 彭楠. 两种MOFs材料用于O₂/He吸附分离的模拟分析[J]. 化工进展, 2023, 42(S1): 382-390.
[6]	陈崇明, 陈秋, 宫云茜, 车凯, 郁金星, 孙楠楠. 分子筛基CO₂吸附剂研究进展[J]. 化工进展, 2023, 42(S1): 411-419.
[7]	许春树, 姚庆达, 梁永贤, 周华龙. 共价有机框架材料功能化策略及其对Hg(Ⅱ)和Cr(Ⅵ)的吸附性能研究进展[J]. 化工进展, 2023, 42(S1): 461-478.
[8]	顾永正, 张永生. HBr改性飞灰对Hg⁰的动态吸附及动力学模型[J]. 化工进展, 2023, 42(S1): 498-509.
[9]	郭强, 赵文凯, 肖永厚. 增强流体扰动强化变压吸附甲硫醚/氮气分离的数值模拟[J]. 化工进展, 2023, 42(S1): 64-72.
[10]	朱杰, 金晶, 丁正浩, 杨会盼, 侯封校. 化学链气化中准东煤灰对CaSO₄载氧体改性及其作用机理[J]. 化工进展, 2023, 42(9): 4628-4635.
[11]	王晋刚, 张剑波, 唐雪娇, 刘金鹏, 鞠美庭. 机动车尾气脱硝催化剂Cu-SSZ-13的改性研究进展[J]. 化工进展, 2023, 42(9): 4636-4648.
[12]	葛亚粉, 孙宇, 肖鹏, 刘琦, 刘波, 孙成蓥, 巩雁军. 分子筛去除VOCs的研究进展[J]. 化工进展, 2023, 42(9): 4716-4730.
[13]	杨莹, 侯豪杰, 黄瑞, 崔煜, 王兵, 刘健, 鲍卫仁, 常丽萍, 王建成, 韩丽娜. 利用煤焦油中酚类物质Stöber法制备碳纳米球用于CO₂吸附[J]. 化工进展, 2023, 42(9): 5011-5018.
[14]	王浩然, 殷全玉, 方明, 侯建林, 李军, 何斌, 张明月. 近临界水处理废弃烟梗工艺优化[J]. 化工进展, 2023, 42(9): 5019-5027.
[15]	李雪佳, 李鹏, 李志霞, 晋墩尚, 郭强, 宋旭锋, 宋芃, 彭跃莲. 亲水和疏水改性膜的抗结垢和润湿能力的对比[J]. 化工进展, 2023, 42(8): 4458-4464.