化工进展 ›› 2015, Vol. 34 ›› Issue (07): 1983-1988,2002.DOI: 10.16085/j.issn.1000-6613.2015.07.029

• 精细化工 • 上一篇    下一篇

蓖麻油基下游产物及蓖麻油增塑剂的研究及其应用进展

许伟1, 葛小东1,2, 金丽珠1,3, 邵荣1   

  1. 1 盐城工学院化学与生物工程学院, 江苏 盐城 224051;
    2 常州大学石油化工学院, 江苏 常州 213164;
    3 南京工业大学机械与动力工程学院, 江苏 南京 211816
  • 收稿日期:2014-11-21 修回日期:2014-12-30 出版日期:2015-07-05 发布日期:2015-07-05
  • 通讯作者: 邵荣,博士,教授。E-mail:shaor1973@163.com。
  • 作者简介:许伟(1976—),女,博士,副教授,主要从事生物催化、生物资源开发与利用。
  • 基金资助:
    江苏省盐城市农业科技创新(YK2012004)、江苏省大学生实践创新训练省指导项目(2014046)、盐城市2012年度农业科技指导性计划(YKN2012027)及江苏省"青蓝工程"项目。

Research and application progress of castor oil-based downstream products and its plasticizer

XU Wei1, GE Xiaodong1,2, JIN Lizhu1,3, SHAO Rong1   

  1. 1 College of Chemical and Biological Engineering, Yancheng Institute of Technology, Yancheng 224051, Jiangsu, China;
    2 Institute of Petrochemical Engineering, Changzhou University, Changzhou 213164, Jiangsu, China;
    3 College of Mechanical and Power Engineering, Nanjing Tech University, Nanjing 211816, Jiangsu, China
  • Received:2014-11-21 Revised:2014-12-30 Online:2015-07-05 Published:2015-07-05

摘要: 随着全球化石资源消耗量的不断剧增, 能源危机问题引起了广泛的关注。在植物资源能源化的利用中, 以蓖麻油为原料开发高附加值下游产品已成为研究热点。本文介绍了国内外蓖麻油基下游产品的制备方法、产品性能及应用领域等方面。回顾了脱水蓖麻油、酯交换蓖麻油、环氧化蓖麻油、蓖麻油基聚氨酯等下游产物的制备与应用性能研究。简述了蓖麻油基增塑剂的种类及应用领域, 具体分析了环氧乙酰蓖麻油酸甲酯的制备方法及产品特性。提出了在我国蓖麻油基增塑剂的生产过程中反应温度、催化剂用量等因素影响环氧基团稳定性的问题, 指出目前我国催化合成蓖麻油基增塑剂的趋势和发展方向。

关键词: 蓖麻油, 聚氨酯, 增塑剂, 环氧化

Abstract: With the rapid consumption of fossil resources, the global energy crisis has caused serious concern. In the utilization of plant resources, the exploitation of downstream products, during which castor oil used as raw materials, has become to be a hot research area. The preparation methods, performance as well as the application fields of castor oil-based downstream products were introduced in this work. The preparation and properties of some castor oil-based downstream products, such as dehydrated castor oil, transesterification of castor oil, exploitation of castor oil, polyurethane of castor oil and so on, were reviewed. The types and application areas of castor oil-based plasticizers were sketched and the preparation methods and the properties of epoxidized methyl acetorieinoleate were analyzed. The problems of the effects of the reaction temperature and the dosage of catalyst on the stability of epoxy group in the production process of the castor oil-based plasticizer were discussed, and the developing trends in the field of castor oil-based plasticizers were proposed.

Key words: castor oil, polyurethane, plasticizers, epoxidation

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