蓖麻油基下游产物及蓖麻油增塑剂的研究及其应用进展

doi:10.16085/j.issn.1000-6613.2015.07.029

摘要/Abstract

摘要： 随着全球化石资源消耗量的不断剧增, 能源危机问题引起了广泛的关注。在植物资源能源化的利用中, 以蓖麻油为原料开发高附加值下游产品已成为研究热点。本文介绍了国内外蓖麻油基下游产品的制备方法、产品性能及应用领域等方面。回顾了脱水蓖麻油、酯交换蓖麻油、环氧化蓖麻油、蓖麻油基聚氨酯等下游产物的制备与应用性能研究。简述了蓖麻油基增塑剂的种类及应用领域, 具体分析了环氧乙酰蓖麻油酸甲酯的制备方法及产品特性。提出了在我国蓖麻油基增塑剂的生产过程中反应温度、催化剂用量等因素影响环氧基团稳定性的问题, 指出目前我国催化合成蓖麻油基增塑剂的趋势和发展方向。

关键词: 蓖麻油, 聚氨酯, 增塑剂, 环氧化

Abstract: With the rapid consumption of fossil resources, the global energy crisis has caused serious concern. In the utilization of plant resources, the exploitation of downstream products, during which castor oil used as raw materials, has become to be a hot research area. The preparation methods, performance as well as the application fields of castor oil-based downstream products were introduced in this work. The preparation and properties of some castor oil-based downstream products, such as dehydrated castor oil, transesterification of castor oil, exploitation of castor oil, polyurethane of castor oil and so on, were reviewed. The types and application areas of castor oil-based plasticizers were sketched and the preparation methods and the properties of epoxidized methyl acetorieinoleate were analyzed. The problems of the effects of the reaction temperature and the dosage of catalyst on the stability of epoxy group in the production process of the castor oil-based plasticizer were discussed, and the developing trends in the field of castor oil-based plasticizers were proposed.

Key words: castor oil, polyurethane, plasticizers, epoxidation

中图分类号:

TQ414.5

许伟, 葛小东, 金丽珠, 邵荣. 蓖麻油基下游产物及蓖麻油增塑剂的研究及其应用进展[J]. 化工进展, 2015, 34(07): 1983-1988,2002.

XU Wei, GE Xiaodong, JIN Lizhu, SHAO Rong. Research and application progress of castor oil-based downstream products and its plasticizer[J]. Chemical Industry and Engineering Progree, 2015, 34(07): 1983-1988,2002.

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