TiO2可见光催化研究进展及其应用前景

摘要/Abstract

摘要： 综述了最近二氧化钛可见光催化改性的研究进展,并展望了二氧化钛光催化剂的应用前景。二氧化钛可见光催化剂改性方法包括:金属离子掺杂、非金属离子掺杂、半导体复合、表面光敏化及共掺杂等主要方法。其中运用最广泛的方法是共掺杂,因为共掺杂能集合其他改性方法的优点,可以同时在降低禁带宽度、提高吸光能力与降低电子与空穴复合等方面提高二氧化钛的性能。同时总结了其最近在环境污染物降解、有机物还原、太阳能电池等多方面的实验研究,展示其在多个领域的应用潜力。最后展望了未来二氧化钛可见光催化剂的发展方向及其应用前景。

关键词: 二氧化钛, 光催化剂, 环境, 改性, 降解

Abstract: This paper reviewed the progress in the modification of photacatalysis under visible light of titanium dioxide, and prospected the applied prospect of titanium dioxide.The modification methods of titanium dioxide photacatalyst under visible light includes: metal ions doped, non-metallic ions doped, semiconductors compound, surface sensitization of light and co-doped.Among this the most widely used method is co-doped, because it set the advantages of other methods, to improve the performance of titanium dioxide in reducing the band gap, improving the light-absorbing capacity, reducing the electron and hole recombination and other aspects.Meanwhile summarizes its recent experimental study on the degradation of pollutants in the environment, reduction of organic matter, solar cells and so on, showing its potential applications in many fields.Finally, this paper prospected the future direction and applied prospect of titanium dioxide catalyst under visible light.

Key words: titanium dioxide, photocatalyst, environment, modification, degradation

何东林, 黄洪, 钟理. TiO₂可见光催化研究进展及其应用前景[J]. 化工进展, 2015, 34(s1): 104-109.

HE Donglin, HUANG Hong, ZHONG Li. Research progress and applied prospect of TiO₂ visible light photocatalysis[J]. Chemical Industry and Engineering Progree, 2015, 34(s1): 104-109.

参考文献

[1] Zhou H, Qu Y, Zeid T, et al.Towards highly efficient photocatalysts using semiconductor nanoarchitectures[J]. Energy & Environmental Science,2012, 5(5): 6732.

[2] Fujishima A, Honda K.Electrochemical photolysis of water at a semiconductor electrode[J].Nature,1972, 37: 238-245.

[3] Linsebinler A L, Lu G, Yates J T.Photocatalysis on TiO₂ surfaces: Principles, mechanisms, and selected results[J]. Chem. Rev., 1995, 95 (3): 735-758.

[4] 廖建军,李士普,曹献坤,等.有序TiO₂纳米管阵列光催化性能研究进展[J].化工进展,2011, 30(9):2003-2012.

[5] Choi W, Termin A,Hoffmann M R.The role of metal ion dopants in quantum-sized TiO₂:Correlation between photoreactivity and charge carrier recombination dynamics[J].J.Phys.Chem., 1994, 98(51): 13669-13679.

[6] Tian B Z,Li C,Gu F,et al.Flame sprayed V-doped TiO₂ nanoparticles with enhanced photocatalytic activity under visible light irradiation[J].Chemical Engineering Journal, 2009,151(1-3): 220-227.

[7] Chen Y Y, Xie Y, Yang J, et al.Double layered, one-pot hydrothermal synthesis of M-TiO₂ (M = Fe³⁺, Ni²⁺, Cu²⁺ and Co²⁺) and their application in photocatalysis[J]. Science China Chemistry,2013,56(12): 1783-1789.

[8] Asahi R,Morikawa T,Ohwaki T,et al.Visible-light photo catalysis in nitrogen-doped titanium oxides[J].Science,2001,293: 269-271.

[9] Jiang Z, Yang F, Luo N, et al.Solvothermal synthesis of N-doped TiO₂ nanotubes for visible-light-responsive photocatalysis [J].Chemical Communications,2008 (47): 6372-6374.

[10] Liu S H, Syu H-R.One-step fabrication of N-doped mesoporous TiO₂ nanoparticles by self-assembly for photocatalytic water splitting under visible light[J]. Applied Energy,2012,100: 148-154.

[11] Liu L, Yang W, Li Q,et al.Synthesis of Cu₂O nanospheres decorated with TiO₂ nanoislands, their enhanced photoactivity and stability under visible light illumination, and their post-illumination catalytic memory[J].ACS Applied Materials & Interfaces,2014,6(8): 5629-5639.

[12] Zhong J B, Li J, Zeng J, et al.Enhanced photocatalytic activity of In₂O₃-decorated TiO₂[J].Applied Physics A,2013, 115(4): 1231-1238.

[13] Wang J, Lin Z.Dye-sensitized TiO₂ nanotube solar cells with markedly enhanced performance via rational surface engineering[J].Chemistry of Materials,2010, 22(2): 579-84.

[14] Dimitrijevic N M, Tepavcevic S, Liu Y, et al. Nanostructured TiO₂/polypyrrole for visible light photocatalysis[J].The Journal of Physical Chemistry C,2013, 117(30): 15540-15544.

[15] Huang D G, Liao S J, Liu J M, et al.Preparation of visible-light responsive N-F-codoped TiO₂ photocatalyst by a sol-gel-solvothermal method[J].Journal of Photochemistry and Photobiology A: Chemistry,2006, 184(3): 282-288.

[16] Xu J W, Gao Z D, Han K,et al.Synthesis of magnetically separable Ag₃PO₄/TiO₂/Fe₃O₄ heterostructure with enhanced photocatalytic performance under visible light for photoinactivation of bacteria[J].ACS Applied Materials & Interfaces,2014, 6(17):15122-15131.

[17] Chen Y F, Huang W, He D,et al.Construction of heterostructured g-C₃N₄/Ag/TiO₂ microspheres with enhanced photocatalysis performance under visible-light irradiation[J].ACS Applied Materials & Interfaces,2014, 6(16): 14405-14414.

[18] Li F, Li H, Guan L-x,et al.Nanocrystalline Co²⁺/F^－ codoped TiO₂-SiO₂ composite films for environmental applications[J].Chemical Engineering Journal,2014, 252: 1-10.

[19] Siuleiman S, Kaneva N, Bojinova A, et al.Photodegradation of orange II by ZnO and TiO₂ powders and nanowire ZnO and ZnO/TiO₂ thin films[J].Colloids and Surfaces A: Physicochemical and Engineering Aspects,2014, 460: 408-413.

[20] Khataee A, Sheydaei M, Hassani A, et al.Sonocatalytic removal of an organic dye using TiO₂/Montmorillonite nanocomposite[J].Ultrasonics Sonochemistry,2015, 22: 404-411.

[21] Hemalatha K, Ette P M, Madras G, et al.Visible light assisted photocatalytic degradation of organic dyes on TiO₂-CNT nanocomposites[J].Journal of Sol-Gel Science and Technology, 2014, 73(1): 72-82.

[22] Monteiro R A R, Miranda S M, Vilar V J P, et al.N-modified TiO₂ photocatalytic activity towards diphenhydramine degradation and escherichia coli inactivation in aqueous solutions[J].Applied Catalysis B: Environmental,2015, 162: 66-74.

[23] Jiang W F, Jiang J Y, Zhang W Z,et al.Preparation and application of multisensitive poly(NIPAM-co-AAc-co-CoMPc)/TiO₂ composites for dinitro butyl phenol wastewater treatment under visible light irradiation[J]. Journal of Chemical Technology & Biotechnology,2014, 89(12): 1910-1917.

[24] Apiwong-ngarm K, Pongwan P, Inceesungvorn B, et al. Photocatalytic activities of Fe-Cu/TiO₂ on the mineralization of oxalic acid and formic acid under visible light irradiation[J]. Powder Technology,2014, 266:447-55.

[25] Jiang W J, Zhang M, Wang J, et al.Dramatic visible activity in phenol degradation of TCNQ@TiO₂ photocatalyst with core-shell structure[J].Applied Catalysis B:Environmental, 2014, 160-161: 44-50.

[26] Zhang S L, Zhong Q, Zhao W, et al.Surface characterization studies on F-doped V₂O₅/TiO₂ catalyst for NO reduction with NH₃ at low-temperature[J].Chemical Engineering Journal,2014, 253: 207-216.

[27] Siuleiman S, Kaneva N, Bojinova A, et al.Photodegradation of orange II by ZnO and TiO₂ powders and nanowire ZnO and ZnO/TiO₂ thin films[J].Colloids and Surfaces A: Physicochemical and Engineering Aspects,2014, 460: 408-413.

[28] Khataee A, Sheydaei M, Hassani A, et al.Sonocatalytic removal of an organic dye using TiO₂/Montmorillonite nanocomposite [J].Ultrasonics Sonochemistry,2015, 22: 404-11.

[29] Matějová L, Ko?í K, Reli M, et al.Preparation,characterization and photocatalytic properties of cerium doped TiO₂: On the effect of Ce loading on the photocatalytic reduction of carbon dioxide[J].Applied Catalysis B: Environmental,2014, 152-153: 172-183.

[30] Tahir M, Amin N S.Indium-doped TiO₂ nanoparticles for photocatalytic CO₂ reduction with H₂O vapors to CH₄[J]. Applied Catalysis B: Environmental,2015,162: 98-109.

[31] Kim G, Lee S-H, Choi W.Glucose-TiO₂ charge transfer complex-mediated photocatalysis under visible light[J]. Applied Catalysis B: Environmental, 2015, 162: 463-469.

[32] Zhang Xiong, Zhang L, Zhao X S.One-step synthesis of metal@titania core-shell materials for visible-light photocatalysis and catalytic reduction reaction[J]. Chemistry,2014,20(45): 14715-14720.

[33] Yu L B, Li Z, Liu Y, et al.Synthesis of hierarchical TiO₂ flower-rod and application in CdSe/CdS co-sensitizedsolar cell[J].Journal of Power Sources,2014,270: 42-52.

[34] Xue B, Sun T, Wu JK, et al.AgI/TiO₂ nanocomposites: Ultrasound-assisted preparation, visible-light induced photocatalytic degradation of methyl orange and antibacterial activity[J].Ultrasonics Sonochemistry, 2015, 22: 1-6.

[35] Yang Z P, Yu X, Zhang Y, et al.Enhanced visible light-driven hydrogen production from water by a noble-metal-free system containing organic dye-sensitized titanium dioxide loaded with nickel hydroxide as the cocatalyst[J].Applied Catalysis B: Environmental,2014, 160-161: 173-178.

TiO₂可见光催化研究进展及其应用前景

Research progress and applied prospect of TiO₂ visible light photocatalysis

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