Sr掺杂对CaMnO3+δ基化合物高温电学性能的影响

化工进展

Sr掺杂对CaMnO3+δ基化合物高温电学性能的影响

贾坤，魏长平，许洁，吕志军，于敏娜

长春理工大学化学与环境工程学院，吉林长春 130022

出版日期:2011-05-05 发布日期:2011-05-05

Effects of Sr doping on high temperature electric properties of CaMnO3+δ - based compounds

JIA Kun，WEI Changping，XU Jie，Lü Zhijun，YU Minna

School of Chemistry and Environmental Engineering，Changchun University of Science and Technology，Changchun 130022，Jilin，China

Online:2011-05-05 Published:2011-05-05

摘要/Abstract

摘要：

以硝酸盐为原料，采用溶胶-凝胶法结合常压烧结制备出Ca₁_－xSr_xMnO₃陶瓷块体材料，研究了其物相、微观形貌以及Sr掺杂对其高温电学性能的影响。结果表明，制备出的块体材料为单一物相，为正交晶系钙钛矿结构，结构致密，Sr掺杂可以有效改变其电学性能，Sr取代Ca位的材料Seebeek系数变化不大但电阻率降低；当Sr的掺杂量为0.1时可获得最佳的电学性能，600 ℃时它的功率因子为24.03×10^－⁵W/(m·K²)。

Abstract:

Ca₁_－xSr_xMnO₃（x=0，0.05，0.1）ceramic samples were prepared by using the sol-gel method and sintering in air with nitrales as starting materials. The phase composition，microstructure and electric properties of Sr doped samples were investigated. The results showed that the Ca₁_－xSr_xMnO₃ ceramic samples was single phase and had condensed microstructure. Sr doped samples had better electric properties. The substitution of Sr for Ca had no significant effect on Seabeek coefficient but decreased its electrical resistivity，the highest power factor was 24.03×10^-5 W/（m·K²）at 600℃ for the sample of Ca_0.9Sr_0.1MnO₃.

贾坤，魏长平，许洁，吕志军，于敏娜. Sr掺杂对CaMnO3+δ基化合物高温电学性能的影响 [J]. 化工进展.

JIA Kun，WEI Changping，XU Jie，Lü Zhijun，YU Minna. Effects of Sr doping on high temperature electric properties of CaMnO3+δ - based compounds[J]. Chemical Industry and Engineering Progree.