Mg1.5Ti1.25O4用于锂离子交换的实验研究

doi:10.16085/j.issn.1000-6613.2016-2216

化工进展 ›› 2017, Vol. 36 ›› Issue (08): 3002-3005.DOI: 10.16085/j.issn.1000-6613.2016-2216

Mg_1.5Ti_1.25O₄用于锂离子交换的实验研究

江津河¹, 刘方旺², 闫永美¹, 曹长青²

1. 潍坊学院化学化工学院, 山东潍坊 261061;
2. 青岛科技大学化工学院, 山东青岛 266042

收稿日期:2016-11-30 修回日期:2017-04-07 出版日期:2017-08-05 发布日期:2017-08-05
通讯作者: 江津河(1971-),男,博士,副教授,主要从事锂电池材料及离子交换材料方向研究。
作者简介:江津河(1971-),男,博士,副教授,主要从事锂电池材料及离子交换材料方向研究。E-mail:jiangjinhe2020@163.com。
基金资助:
国家自然科学基金项目（51541205）。

Experimental study of Mg_1.5Ti_1.25O₄ for Li⁺ ion-exchange

JIANG Jinhe¹, LIU Fangwang², YAN Yongmei¹, CAO Changqing²

1. Department of Chemistry and Chemical Engineering, Weifang University, Weifang 261061, Shandong, China;
2. Department of Chemical Engineering, Qingdao University of Science and Technology, Qingdao 266000, Shandong, China

Received:2016-11-30 Revised:2017-04-07 Online:2017-08-05 Published:2017-08-05

摘要/Abstract

摘要： 一定温度下，用固相反应结晶的方法合成具有尖晶石结构的金属复合氧化物Mg_1.5Ti_1.25O₄。尖晶石型金属复合氧化物在化学组分及化学计量数方面有非常灵活的特性，在维持自身晶体结构不变的条件下，通过改变自身化学计量数的方法可插入或者抽出一些替换离子。尖晶石型金属复合氧化物作为离子交换剂具有热稳定性强、抗辐射能力强、合成简单以及良好的选择性等优点。本文对合成的尖晶石型金属复合氧化物Mg_1.5Ti_1.25O₄进行了实验表征，包括X射线衍射仪结构表征，检测酸性条件下Li⁺的抽出值、饱和交换容量值测量、分配系数测定等。实验研究结果表明，本复合氧化物结构稳定，能够插入或者抽出Li⁺，具有较高的Li⁺选择性和离子记忆性。用硝酸处理过的样品对Li⁺交换容量达到9.7mmol/g。

关键词: 尖晶石型结构, 复合金属氧化物, 离子交换容量

Abstract: The metal compound oxide Mg_1.5Ti_1.25O₄ with a spinel-type structure was synthesized by the method of solid state reaction crystallization at fixed temperature. This spinel had versatile characteristics in respect of its chemical composition and stoichiometric number. It could be inserted or extracted some substitutable ions through changing stoichiometric number while keeping its own structure. Spinel-type metal compound oxide had advantages of better thermal stability, strong radiation resistance, simple preparation and good selectivity. The properties of Mg_1.5Ti_0.25O₄ such as XRD, Li⁺ extraction value, saturation capacity of exchange and distribution coefficient have been determined. The experimental results showed that this compound oxide had a stable structure. It could be inserted or extracted Li⁺ and has good Li⁺ selectivity and ion memory property. The samples which were treated by nitirc acid have a 9.7mmol/g ion exchange capacity for Li⁺.

Key words: spinel-type structure, metal compound oxide, ion exchange capacity

中图分类号:

TQ016.1

江津河, 刘方旺, 闫永美, 曹长青. Mg_1.5Ti_1.25O₄用于锂离子交换的实验研究[J]. 化工进展, 2017, 36(08): 3002-3005.

JIANG Jinhe, LIU Fangwang, YAN Yongmei, CAO Changqing. Experimental study of Mg_1.5Ti_1.25O₄ for Li⁺ ion-exchange[J]. Chemical Industry and Engineering Progress, 2017, 36(08): 3002-3005.

参考文献

[1] DONG Dianquan,ZHONG Jie,LIU Dunlei,et al. Synthesis of LiCu_0.5Mn_1.5O₄ and its Li⁺ extraction/insertion reaction in aqueous solution[J]. Chinese Journal of Applied Chemistry,1998,15(3):11-16.
[2] PENG Zhenshun. Synthesis and electrochemical studies on spinel phase LiMn₂O₄ cathode materials prepared by different processes[J]. Rare Metals,1999,18(2):143-148.
[3] 赵丽丽,王榕树. 锂离子交换剂制备及交换反应动力学[J]. 物理化学学报,2003,19(10):933-937. ZHAO Lili,WANG Rongshu. Preparation of MnO₂(Li) and its ion exchange kinetics[J]. Acta Physico-Chimica Sinica,2003,19(10):933-937.
[4] 吉国佳,朱桂茹. 锂离子筛前驱体Li_1.6Mn_1.6O₄的制备及酸洗研究[J]. 无机盐工业,2015,47(12):38-42. JI Guojia,ZHU Guiru. Preparation and acid-pickling of Li_1.6Mn_1.6O₄ lithium-ion sieve precursor[J]. Inorganic Chemicals Industry,2015,47(12):38-42.
[5] 王松平,王晓伟,杜志辉. 无机离子交换剂去除放射性废水中137Cs的研究进展[J]. 核安全,2014,13(1):71-77. WANG Songping,WANG Xiaowei,DU Zhihui. Advance in the study of removal of cesium from radioactive wastewater by inorganic ion exchangers[J]. Nuclear Safety,2014,13(1):71-77.
[6] 王涛,孟庆祥,许海涛,等. 纳米纤维锂离子筛吸附剂的制备及表征[J]. 无机盐工业,2016,48(3):29-33. WANG Tao,MENG Qingxiang,XU Haitao,et al. Preparation and characterization of lithium ion sieve nanofibrous adsorbents[J]. Inorganic Chemicals Industry,2016,48(3):29-33.
[7] 杨珊珊,阮慧敏,沈江南,等. 尖晶石型锂锰氧化物离子筛的制备方法及构效性能分析[J]. 化工进展,2015,34(6):1690-1698. YANG Shanshan,RUAN Huimin,SHEN Jiangnan,et al. Preparation methods and analyses of structural performance of spinel-type lithium manganese oxide ion sieves[J]. Chemical Industry and Engineering Progress,2015,34(6):1690-1698.
[8] 孟庆祥,许海涛,许振良,等. 水热合成法制备锂离子筛工艺参数的研究[J]. 化学世界,2014,10:588-592. MENG Qingxiang,XU Haitao,XU Zhenliang,et al. Study on preparation of lithium ion sieve by hydrothermal synthesis method[J]. Chemical World,2014,10:588-592.
[9] ZHONG Hui. Property of H₂TiO₃ type ion exchangers and extraction of lithium from brine of natural gas wells[J]. Chinese Journal of Applied Chemistry,2000,17(3):307-312.
[10] JIANG Jinhe,DONG Dianquan,LI Jianlong. Synthesis of Li₄Mn_0.5Ti_0.5O₄ and its selectivity to Li⁺ exchange[J]. Chinese Journal of Applied Chemistry,2006,23(4):357-362.
[11] 李丹,邓天龙,孙柏. 无机离子交换法从卤水中提锂的研究进展[J]. 广东微量元素科学,2007,14(1):6-10. LI Dan,DENG Tianlong,SUN Bai. Progresses on lithium recovery from brine by inorganic-ion-exchange method[J]. Guangdong Trace Elements Science,2007,14(1):6-10.
[12] 纪永志,许长春,袁俊生,等.尖晶石型锂离子筛研究进展[J]. 化工进展,2005,24(12):1336-1341. JI Yongzhi,XU Changchun,YUAN Junsheng,et al. Progress of study on spinel lithium ion-sieve[J]. Chemical Industry and Engineering Progress,2005,24(12):1336-1341.
[13] 史鑫,蒲薇华,武玉玲,等. 锂离子电池正极材料层状LiMnO₂的研究进展[J]. 化工进展,2011,30(6):1264-1269. SHI Xin,PU Weihua,WU Yuling,et al. Research progress on layered lithium manganese oxide as cathode material for lithium-ion battery[J]. Chemical Industry and Engineering Progress,2011,30(6):1264-1269.
[14] 柏春,郭敏,张慧芳,等. 离子筛型锂吸附剂吸附法从盐湖卤水/海水中提锂的研究进展[J]. 化工进展,2017,36(3):802-809. BAI Chun,GUO Min,ZHANG Huifang,et al. The research progress of extracting lithium from brine by lithium ion sieve[J]. Chemical Industry and Engineering Progress,2017,36(3):802-809.

Mg_1.5Ti_1.25O₄用于锂离子交换的实验研究

Experimental study of Mg_1.5Ti_1.25O₄ for Li⁺ ion-exchange

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