羧烷基-季铵两性壳聚糖的制备及其阻垢杀菌性能

化工进展

羧烷基-季铵两性壳聚糖的制备及其阻垢杀菌性能

张惠欣，葛丽环，周宏勇，朱玉超，王枫

河北工业大学化工学院，天津 300130

出版日期:2011-09-05 发布日期:2011-09-05

Prepration of amphoteric carboxyalkyl-quaternary ammonia chitosan derivatives and performances on both scaling inhibition and bacterial inhibition

ZHANG Huixin，GE Lihuan，ZHOU Hongyong，ZHU Yuchao，WANG Feng

School of Chemical Engineering，Hebei University of Technology，Tianjin 300130，China

Online:2011-09-05 Published:2011-09-05

摘要/Abstract

摘要：

采用氯乙酸、丙烯酸和2,3-环氧丙基三甲基氯化铵对壳聚糖（CTS）改性，制得羧甲基-季铵壳聚糖（CMQAC）和羧乙基-季铵壳聚糖（CEQAC），并通过IR、¹H NMR、XRD对产物进行了结构确证。用静态阻垢的方法对两性壳聚糖衍生物阻硫酸钙垢的性能进行了评价，结果表明两性壳聚糖用量为16 mg/L、[Ca²⁺]<2000 mg/L、[SO₄²^－]<4800 mg/L时，阻垢率可达到100%。用小瓶测试法测定不同季铵取代度（DS）的两性壳聚糖对异养菌的杀菌效果。研究结果表明，在用量为30 mg/L时，CMQAC季铵取代度为0.73时杀菌率为99.7% ，CEQAC季铵取代度为0.50时杀菌率为99.2%，改性后壳聚糖衍生物的阻垢和杀菌性能与壳聚糖相比有了明显提高。

Abstract:

Chitosan was modified by chloroacetic acid，acrylic acid and 2,3-epoxypropyl trimethyl ammonium chloride to obtain amphoteric carboxymethyl-quaternary ammonium chitosan（CMQAC）and amphoteric carboxyethyl-quaternary ammonium chitosan（CEQAC），then the structures of the products were confirmed by IR，¹H NMR and XRD. The performance of scaling inhibition of amphoteric chitosan derivatives with respect to CaSO₄were evaluated by static antiscaling experiment，and the results showed that the inhibition rate could be up to 100% when the dosage of amphoteric chitosan derivatives was 16 mg/L，[Ca²⁺]<2000 mg/L and [SO₄²^－]<4800 mg/L. The bacterial inhibition of amphoteric chitosan derivatives with different degrees of substitution（DS）of quaternary ammonium was measured with the vial method. The results showed that the sterilizing rates can be up to 99.7% and 99.2% with chitosan derivative addition of 30mg/L when the DS of quaternary ammonium was 0.73 and 0.50 respectively for CMQAC and of CEQAC. The modification resulted in a great improvement in scaling inhibition and bacterial inhibition of chitosan derivatives in comparison with chitosan.

张惠欣，葛丽环，周宏勇，朱玉超，王枫. 羧烷基-季铵两性壳聚糖的制备及其阻垢杀菌性能 [J]. 化工进展.

ZHANG Huixin，GE Lihuan，ZHOU Hongyong，ZHU Yuchao，WANG Feng. Prepration of amphoteric carboxyalkyl-quaternary ammonia chitosan derivatives and performances on both scaling inhibition and bacterial inhibition[J]. Chemical Industry and Engineering Progree.