生物质制备5-羟甲基糠醛的研究进展

化工进展

生物质制备5-羟甲基糠醛的研究进展

姜　楠1，齐　崴1，2，黄仁亮1，苏荣欣1，何志敏1，2

1天津大学化工学院化学工程研究所，2化学工程联合国家重点实验室（天津大学），天津 300072

出版日期:2011-09-05 发布日期:2011-09-05

Research progress of synthesis of 5-hydroxymethylfurfural from biomass

JIANG Nan 1，QI Wei 1，2，HUANG Renliang 1，SU Rongxin 1，HE Zhimin 1，2

1Chemical Engineering Research Center，School of Chemical Engineering and Technology，Tianjin University；2State Key Laboratory of Chemical Engineering（Tianjin University），Tianjin 300072，China

Online:2011-09-05 Published:2011-09-05

摘要/Abstract

摘要：

5-羟甲基糠醛（HMF）是一种重要的平台化合物，具有广阔的应用前景。目前很多研究者已对如何提高HMF的产率和降低HMF的制备成本开展了多方面研究。本文综述了2006—2010年HMF的主要制备方法及研究特色，并对原料（单糖、多糖）、催化剂（固体酸、均相催化剂）、溶剂体系（单相体系、双相体系）及其它辅助条件（微波加热法、添加调节剂法）进行了系统总结与全面分析；同时，介绍了HMF的重要衍生物及其应用；最后指出了目前研究中存在的突出问题，并对其中的主要研究方向进行了归纳。

Abstract:

5-Hydroxymethylfurfural（HMF）is an important platform chemical with great application value. Enhancing the efficiency of synthesis and reducing the cost of production for HMF have been investigated by many researchers. Firstly，this paper introduced the generation mechanism of HMF. Based on the reaction scheme，many kinds of synthetic method of HMF from year 2006 to 2010 were summarized，and categorized as raw materials（monosaccharide and polysaccharides），catalysts（solid acid catalysts and homogeneous acid catalysts），reaction solvents（single-phase system and two-phase system）and subsidiary conditions（microwave-assisted heating and supplementary modifiers）. Meanwhile，the HMF derivatives and their applications is briefly introduced. Finally，prominent problems of current studies are discussed，and main research fields are also analyzed.

姜　楠1，齐　崴1，2，黄仁亮1，苏荣欣1，何志敏1，2. 生物质制备5-羟甲基糠醛的研究进展 [J]. 化工进展.

JIANG Nan 1，QI Wei 1，2，HUANG Renliang 1，SU Rongxin 1，HE Zhimin 1，2. Research progress of synthesis of 5-hydroxymethylfurfural from biomass[J]. Chemical Industry and Engineering Progree.