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β-月桂烯在有机反应中的应用研究进展

连建伟1,夏建陵1,2,黄 坤1,杨小华1,汪 梅1   

  1. 1中国林业科学研究院林产化学工业研究所;生物质化学利用国家工程实验室;国家林业局林产化学工程重点开放性实验室;江苏省生物质能源与材料重点实验室,江苏 南京 210042;2中国林业科学研究院林业新技术研究所,北京 100091
  • 出版日期:2011-08-05 发布日期:2011-08-05

Research progress of application of β-myrcene in organic reactions

LIAN Jianwei1,XIA Jianling1,2,HUANG Kun1,YANG Xiaohua 1,WANG Mei1   

  1. 1Institute of Chemical Industry of Forestry Products,Chinese Academy of Forestry;National Engineering Lab. for Biomass Chemical Utilization;Key and Lab. on Forest Chemical Engineering,State Forestry Administration,Key Lab. of Biomass Energy and Material,Nanjing 210042,Jiangsu,China;2Institute of New Technology of Forestry,Chinese Academy of Forestry,Beijing 100091,China
  • Online:2011-08-05 Published:2011-08-05

摘要:

β-月桂烯是一种化学性质活泼的天然产物。本文综述了β-月桂烯在各种有机反应中的研究进展,回顾了β-月桂烯在还原反应、氧化反应和其它反应中的应用。重点介绍了其在Diels-Alder反应中的研究现状,包括了β-月桂烯与丙烯醛、丙烯酸甲酯和马来酸酐等亲二烯体的Diels-Alder反应,分析了不同亲二烯体与β-月桂烯反应的难易。最后,展望了β-月桂烯的应用研究方向。

Abstract:

β-Myrcene is a natural product with active chemical properties. The applications of β-myrcene in reduction reactionoxidation reaction and other reactions are reviewed and its research progress in various organic reactions is summarized. The research of β-myrcene in Diels-Alder reactions is mainly introducedincluding reactions between β-myrcene and dienophilessuch as acroleinmethyl acrylate and maleic anhydride and their degrees of difficulty are analyzed. Finallythe research directions of β-myrcene in applications are prospected.

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