化工进展

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氢同位素气相色谱分析研究现状与展望

王晓英,陆光达,秦 城,吕俊波   

  1. 中国工程物理研究院,四川 绵阳 621900
  • 出版日期:2011-06-05 发布日期:2011-06-05

Current state and prospect of hydrogen isotope analysis by gas chromatography

WANG Xiaoying,LU Guangda,QIN Cheng,Lü Junbo   

  1. China Academy of Engineering Physics,Mianyang 621900,Sichuan,China
  • Online:2011-06-05 Published:2011-06-05

摘要:

氢同位素气体分析在氚处理工艺及聚变堆燃料循环系统中有着非常重要的应用。由于同位素具有相同的化学性质,其分析只能利用其物理性质的微小差别来实现,带有低温分离柱的气相色谱仪是分析氢同位素的重要方法之一,而近年来在研究应用方面取得重要进展的微气相色谱有望大幅缩短分析时间,实现在线分析,具有潜在的重要应用前景。本文阐述了气相色谱分析氢同位素色谱柱材料、检测器、载气、定量方法等方面研究现状,并对存在的问题及发展方向作了讨论。

Abstract:

In the tritium processing system and fuel cycle system of fusion reactorsanalysis of hydrogen isotopes is very importantBecause their chemical properties are the sameto analyze hydrogen isotopes can only be completed by using their minute difference in physical propertiesGas chromatographGCwith cryogenic separation column is one of the best methods for the analysis of hydrogen isotopesIn recent yearssignificant progress of micro GC has been made . It is expected to shorten analysis time and realize on-line analysiswith promising potential for applicationIn this reviewthe materials of chromatographic columndetectorcarrier gas and quantitative method are summarized and analyzedand the application and outlook are also reviewed

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