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超声波场下相分离法制备Ag/PA-6复合粒子

张 凯,范敬辉,马 艳,吴菊英   

  1. 中国工程物理研究院总体工程研究所,四川 绵阳 621900
  • 出版日期:2011-04-05 发布日期:2011-04-05

Preparation of Ag/PA-6 composite particles by phase separation method under ultrasonic irradiation

ZHANG Kai,FAN Jinghui,MA Yan,WU Juying   

  1. Institute of System Engineering,China Academy of Engineering Physics,Mianyang 621900,Sichuan,China
  • Online:2011-04-05 Published:2011-04-05

摘要:

在尼龙-6PA-6)的甲酸溶液中加入表面处理的Ag粒子,然后采用滴加非溶剂法和冷却降温法相结合的相分离法促使PA-6粒子的成型,同时在相分离及分散过程中引入超声波场,制备出Ag/PA-6复合粒子。通过对Ag/PA-6复合粒子的结构表征,发现Ag/PA-6复合粒子形状不规整,表面存在一定的缺陷,但结构非常致密,复合粒子周围及表面无游离的纳米Ag粒子存在,包覆率较高。在相同无机粒子添加量(质量分数20%)的条件下,采用相分离法制备的复合粒子的无机粒子包覆率(81%)高于原位分散聚合法(47%)。

Abstract:

Ag/PA-6 composite particles were prepared with the combined dropping nonsolvent method and cooling temperature method in the presence of Ag particles in PA-6 formic acid solution under ultrasonic irradiation. The characterization results showed that Ag/PA-6 composite particles had abnormity and compact surface structure. The almost whole of Ag particles were encapsulated by PA-6and no dissociative Ag particles surrounded PA-6 particles. With the same amount of 20% inorganic particlescomposite particles prepared with phase separation had larger encapsulation ratio than those prepared with dispersion polymerization. The former encapsulation ratio was 81%and the latter encapsulation ratio was 47%.

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