金刚烃类化合物研究进展（Ⅰ）结构与性质

化工进展

金刚烃类化合物研究进展（Ⅰ）结构与性质

朱华1，郭建维1，刘卅2，杨楚芬1，彭进平1，崔亦华1，蔡璐1

（1广东工业大学轻工化工学院，广东广州 510006；2华南理工大学材料科学与工程学院，广东广州510640）

出版日期:2011-03-05 发布日期:2011-03-05

Research progress of diamondoids（Ⅰ）Structure and properties

ZHU Hua1，GUO Jianwei1，LIU Sa2，YANG Chufen1，PENG Jinping1，CUI Yihua1，CAI Lu1

（1Faculty of Chemical Engineering and Light Industry，Guangdong University of Technology，Guangzhou 510006，Guangdong，China；2School of Materials Science and Engineering，South China University of Technology，Guangzhou 510640，Guangdong，China）

Online:2011-03-05 Published:2011-03-05

摘要/Abstract

摘要：

金刚烃是由多个环己烷构成的饱和笼状烃，此类有机化合物的分子式为C_4n+6H_4n+12。金刚烷则是最小的金刚烃化合物（即n=1时），其C原子骨架类似于金刚石的一个晶格单元。由于其独特的笼状结构和特殊的化学、物理和药理学性质，因此其逐渐成为研究的热点。本文介绍了金刚烃的结构、命名、性质，重点介绍了金刚烃的化学性质及其衍生物的合成。

Abstract:

Diamondoids are cage-like saturated hydrocarbons consisting of fused cyclohexane rings. This family of organic compounds follows the general chemical formula of C_4n+6 H_4n+12. Adamantane is the smallest member of the diamondoids family with n=1, whose C skeleton structure is similar to the diamond lattice. Due to the special cage structure and the superexcellent physical，chemical and pharmacological properties，diamondoids have been a hot topic of research. Structure，nomenclature，properties of diamondiods，especially chemical properties and synthesis of the derivatives of diamondoids are reviewed.

朱华1，郭建维1，刘卅2，杨楚芬1，彭进平1，崔亦华1，蔡璐1. 金刚烃类化合物研究进展（Ⅰ）结构与性质 [J]. 化工进展.

ZHU Hua1，GUO Jianwei1，LIU Sa2，YANG Chufen1，PENG Jinping1，CUI Yihua1，CAI Lu1. Research progress of diamondoids（Ⅰ）Structure and properties[J]. Chemical Industry and Engineering Progree.