化工进展

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溶胶-凝胶法制备镍基CO选择性甲烷化催化剂

单 译,郭瓦力,孙业涛,宋 焱,吕海丽   

  1. 沈阳化工大学,辽宁 沈阳 110142
  • 出版日期:2011-02-05 发布日期:2011-02-05

Nickel-based catalyst for CO selective methanation prepared by sol-gel method

SHAN Yi,GUO Wali,SUN Yetao,SONG Yan,Lü Haili   

  1. Shenyang University of Chemical Technology,Shenyang 110142,Liaoning,China
  • Online:2011-02-05 Published:2011-02-05

摘要:

提出采用溶胶-凝胶法制备镍基催化剂的工艺,考察了NiO的担载量、焙烧温度等制备条件在氢气纯化中对催化活性的影响,利用SEMBET等手段对催化剂进行了表征。在一定条件下,CO可以降至0H2CO选择性大于99%,完全可以满足质子交换膜燃料电池对氢源的要求。

Abstract:

A nickel-based catalyst was prepared by the sol-gel processand the effect of preparation conditionsincluding NiO loading and calcination temperature on catalytic activity in hydrogen purification was investigated. The catalysts was characterized by means of SEMBET. Under specific conditionsCO content could be reduced to 0selectivity of H2 on CO was over 99%. The hydrogen requirements of proton exchange membrane fuel cell could be fully met.

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