化工进展

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聚氨酯中间体生产过程氯循环利用的生态工业模式

张林浩,梁日忠   

  1. 上海大学环境与化学工程学院,上海 200072
  • 出版日期:2011-12-05 发布日期:2011-12-05

Eco-industry mode study on the process of polyurethane intermediate production with chlorine element recycle

ZHANG Linhao,LIANG Rizhong   

  1. College of Environmental and Chemical Engineering,Shanghai University,Shanghai 200072,China
  • Online:2011-12-05 Published:2011-12-05

摘要:

以聚氨酯中间体生产过程为研究对象,运用工业代谢方法,在对传统聚氨酯中间体生产过程中氯元素的工业代谢分析的基础上,提出通过氯化氢催化氧化制氯技术实现氯元素循环利用的思想;综合过程中含盐废水以及光气回收的资源化利用和其它副产物的处理,应用生态工业和系统工程原理,提出聚氨酯中间体生产过程氯循环利用的生态工业模式,并分析了该模式中氯元素的工业代谢情况,提出了该生态工业模式的实施方案。

Abstract:

Based on the industrial metabolic analysis on chlorine element in the process of polyurethane intermediate productiona thought of chlorine recycle was proposedin which chloride was obtained by catalytic oxidation of hydrogen chloride. An eco-industry mode of chlorine recyclesalinity wastewaterphosgene and other by-products in the process of polyurethane intermediate production was mapped out by applying the principles of system engineering and eco-industry. The industrial metabolic situation of chlorine element in this mode was analyzed. The implementation of the eco-industry mode is put forward at the end of this paper.

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