化工进展

• 工业催化 • 上一篇    下一篇

MoVTeNbO催化剂用于丙烷选择氧化与氨氧化研究进展

王 鉴,李安莲,邴国强,乔 岩,赵洪坤,王绪文   

  1. 东北石油大学化学化工学院,石油与天然气化工省重点实验室,黑龙江 大庆 163318
  • 出版日期:2010-12-05 发布日期:2010-12-05

Progress in MoVTeNbO catalysts for propane selective oxidation and ammoxidation

WANG Jian,LI Anlian,BING Guoqiang,QIAO Yan,ZHAO Hongkun,WANG Xuwen   

  1. Provincial Key Laboratory of Oil&Gas Chemical Technology,College of Chemistry&Chemical Engineering,Northeast Petroleum University,Daqing 163318,Heilongjiang,China
  • Online:2010-12-05 Published:2010-12-05

摘要:

综述了复合金属氧化物催化剂MoVTeNbO的研究进展,重点介绍了制备过程中溶液的pH值、干燥方式的选择及热处理过程对催化剂活性相形成的影响,阐述了在晶相结构方面最新的研究成果以及晶相结构与催化反应性能的关系。总结了在该催化剂上丙烷氧化制丙烯酸和氨氧化制丙烯腈的反应机理。优化制备条件、提高晶格氧的扩散速率,调控催化剂的酸碱性以及引发活化烃或氧的活性中心是获得优良催化性能的关键因素。

Abstract:

Recent progress in MoVTeNbO mixed metal oxide catalysts are reviewed with focuses on the preparation procedure on the formation of catalyst active phasesuch as the solution pH valuedrying and thermal treatment method. The crystal structure study in the latest literatures are summaried and the relationship between catalyst structure and catalytic performance are illustrated. The reaction mechanism of propane selective oxidation to acrylic acid and ammoxidation to acrylonitrile over MoVTeNbO catalyst are discussed. Optimization in preparation conditionsimprovement in the diffusion rate of lattice oxygenregulation in surface acidity and active center initiation are critical to achieve superior catalytic properties

京ICP备12046843号-2;京公网安备 11010102001994号
版权所有 © 《化工进展》编辑部
地址:北京市东城区青年湖南街13号 邮编:100011
电子信箱:hgjz@cip.com.cn
本系统由北京玛格泰克科技发展有限公司设计开发 技术支持:support@magtech.com.cn