化工进展

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氮掺杂非贵金属氧还原催化剂研究进展

杨 伟1,陈胜洲2,邹汉波2,林维明1,2   

  1. 1华南理工大学化学与化工学院,广东 广州510640;2广州大学化学化工学院,广东 广州510006
  • 出版日期:2010-11-05 发布日期:2010-11-05

Progress in nitrogen-doped non-noble catalysts for oxygen reduction

YANG Wei1,CHEN Shengzhou2,ZOU Hanbo2,LIN Weiming1,2   

  1. 1 School of Chemistry and Chemical Engineering,South China University of Technology,Guangzhou 510640,Guangdong,China;2School of Chemistry and Chemical Engineering,Guangzhou University,Guangzhou 510006,Guangdong,China
  • Online:2010-11-05 Published:2010-11-05

摘要:

综述了近几年来用于直接甲醇燃料电池阴极氧还原反应的含氮碳催化材料发展状况,包括催化剂制备过程中热处理条件、金属的种类及负载量、碳载体、新型合成方法等影响催化剂氧还原活性的几个因素。针对当前研究工作的局限展开了评论,指出催化机理和优化制备过程是氮掺杂碳材料负载非贵金属氧还原催化剂深入研究的重点和主要方向。

Abstract:

The development of non-noble catalysts such as M-N/C catalysts for the oxygen reduction reactionORRis reviewed. Parameters that affect catalyst activity towards the ORRsuch as thermal-treatment conditionsmetal precursors and loadingcarbon supports and synthesis methodsare summarizedand the limitations of existing research works are discussed. In order to obtain commercially feasiblecost-effective and innovative non-noble electrocatalystscatalytic mechanism study and catalyst synthesis optimization are two crucial points for the discovery of new catalyst with good performance.

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