Abstract: V2O5 was synthesized by the sol-gel process. Graphite was doped into V2O5 through ball milling. Scanning electron microscopy (SEM)，X-ray diffraction (XRD), cyclic voltammetry, and electrochemical impedance spectroscopy indicated that graphite could change the microstructure and composition of V2O5 electrodes. The non-symmetric electrochemical capacitors consisting of V2O5/C composite material and graphite, 1mol/L LiClO4(EC:DEC =1:1)organic solution as electrolyte, reached the specific energy of 18.3wh/kg and the capacity attenuation of 25.68% after cycling 400 times. The specific capacity and cycling performance were dramatically improved as compared with V2O5 without doping.