化工进展

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非茂金属烯烃聚合催化剂的载体化研究进展

崔 崑;姚小利;李传峰;俞建勇;马 志   

  1. 东华大学纺织面料技术教育部重点实验室;扬子石油化工股份有限公司研究院;中国科学院上海有机化学研究所 金属有机化学国家重点实验室
  • 出版日期:2007-03-25 发布日期:2007-03-25

Recent progress in the immobilization of non-metallocene olefin polymerization catalyst

CUI Kun;YAO Xiaoli;LI Chuanfeng;YU Jianyong;MA Zhi   

  1. Key Lab of Textile Science & Technology,Ministry of Education,Donghua University;Research Institute of Yangzi Petrochemical Co.,Ltd.; State Key Lab of Organometallic Chemistry,Shanghai Institute of Organic Chemistry,Chinese Academy of Sciences
  • Online:2007-03-25 Published:2007-03-25

摘要: 综述了近年来非茂金属烯烃聚合催化剂的载体化研究的新进展。按照不同载体的分类,介绍了载体化非茂金属催化剂的制备方法及其表征,讨论并总结了载体化方法、聚合温度、助催化剂用量及种类、聚合压力等聚合条件对载体催化剂的催化烯烃聚合行为的影响,以及对所得聚合物相对分子质量、相对分子质量分布、熔点、形貌等性质的影响。

Abstract: The recent progress in the immobilization of non-metallocene olefin polymerization catalyst is reviewed. According to the different types of supports,this paper introduces the preparation and characterization of supported catalyst. The influence of the immobilization methods,polymerization temperature,the amount and type of co-catalyst,polymerization pressure and the effect of hydrogen on the behavior of supported catalysts in olefin polymerization are discussed. Moreover,the effects of such conditions mentioned above on the properties of the obtained polymers,such as molecular weight,molecular weight distribution,melting temperature,morphology,etc. are summarized.

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