化工进展

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有机硅高沸物催化裂解制单硅烷催化剂研究进展

熊艳锋,张 宁   

  1. 南昌大学理学院化学系
  • 出版日期:2006-08-25 发布日期:2006-08-25

Research on advances of converting organosilicon high-boiling components
to methylchlorosilane by catalytic decomposition

XIONG Yanfeng,ZHANG Ning   

  1. Department of Chemistry,College of Science,Nanchang University
  • Online:2006-08-25 Published:2006-08-25

摘要: 介绍了近年来通过高温裂解法、催化裂解法将有机硅高沸物转化成单硅烷的研究进展,重点评述了催化裂解高沸物的氯化铝及其复合含盐催化剂、有机胺及其盐催化剂、过渡金属及其化合物催化剂、分子筛和活性炭催化剂。

Abstract: Advances in utilizing the organosilicon high-boiling components formed during the preparation of methylchlorosilane via direct synthesis to produce valuable methylchlorosilanes are reviewed. The catalytic conversion of the organosilicon high-boiling components to methyldichlorosilanes by splitting decomposition is particularly presented. The utilization of organosilicon high-boiling components in China is briefly described. The development of utilizing organosilicon high-boiling components is discussed.

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