高耐盐性AA–AMPS共聚高吸水性树脂合成

化工进展

高耐盐性AA–AMPS共聚高吸水性树脂合成

廖列文，崔英德，尹国强，黎新明，史爱华

仲凯农业技术学院绿色化工研究所；广东工业大学轻工化工学院

出版日期:2006-03-25 发布日期:2006-03-25

Synthesis of AA-AMPS copolymer super absorbent of high salt tolerance

LIAO Liewen， CUI Yingde ，YIN Guoqiang ，LI Xinming，SHI Aihua

Institute of Green Chemical Engineering，Zhongkai University of Agriculture and Technology；Faculty of Chemical Engineering and Light Industry，
Guangdong University of Technology

Online:2006-03-25 Published:2006-03-25

摘要/Abstract

摘要： 以AMPS和丙烯酸（AA）为原料，N，N-亚甲基双丙烯酰胺为交联剂，采用静置水溶液聚合法合成了耐盐性能较好的高吸水性树脂。经正交实验研究了合成反应的工艺条件，在n(AA)/n(AMPS)为85/15，交联剂质量分数为0.0125%，引发剂质量分数为0.05%，中和度为90%，单体质量分数为35%，反应温度55～75℃。合成树脂的吸水率大于900 g/g，在0.9%的生理盐水中吸液能力达到125 g/g以上，在1.8%盐水中的吸液能力依然超过100 g/g。

Abstract: With AA and AMPS as main raw materials，NMBA as crosslinking agent，a super absorbent of high salt tolerance was synthesized in aqueous solution. The mol ratio of AA/AMPS was 85/15，the mass of cross–linking agent was 0.0125%，and the mass of initiatoris was 0.05%. AA was neutralized partially by 90% sodium hydroxide，the mass of monomer was 35% in solution，and reaction temperature was 55～75℃. The results showed that super absorbent synthesized could absorb water as high as 900 g/g，125 g/g in 0.9% NaCl solution and 100 g/g in 1.8% NaCl solution.

廖列文，崔英德，尹国强，黎新明，史爱华. 高耐盐性AA–AMPS共聚高吸水性树脂合成 [J]. 化工进展.

LIAO Liewen， CUI Yingde ，YIN Guoqiang ，LI Xinming，SHI Aihua. Synthesis of AA-AMPS copolymer super absorbent of high salt tolerance[J]. Chemical Industry and Engineering Progree.