B2O3-K2O-Sb2O3系统玻璃的光学折射率及带隙

doi:10.16085/j.issn.1000-6613.2019-1402

化工进展 ›› 2020, Vol. 39 ›› Issue (5): 1882-1887.DOI: 10.16085/j.issn.1000-6613.2019-1402

B₂O₃-K₂O-Sb₂O₃系统玻璃的光学折射率及带隙

林社宝¹(), 史东阳¹, 冯爱玲¹, 刘春晓², 许强¹, 赵磊¹, 郭佳伟¹, 王伟³

^1.宝鸡文理学院物理与光电技术学院，陕西宝鸡 721016
^2.南京邮电大学电子与光学工程学院、微电子学院，江苏南京 210023
^3.陕西宝光真空电器股份有限公司，陕西宝鸡 721006

出版日期:2020-05-05 发布日期:2020-05-25
通讯作者: 林社宝
作者简介:林社宝（1977—），男，博士，讲师，硕士生导师，研究方向为功能玻璃。E-mail：linshebao@163.com。
基金资助:
国家自然科学基金(51801001);宝鸡市科技攻关项目(14GYGG-5-1);宝鸡文理学院校级重点项目(ZK15041);陕西省大学生创新创业训练计划资助项目(2017dc068)

Optical refrative index and band gap of B₂O₃-K₂O-Sb₂O₃ system glasses

Shebao LIN¹(), Dongyang SHI¹, Ailing FENG¹, Chunxiao LIU², Qiang XU¹, Lei ZHAO¹, Jiawei GUO¹, Wei WANG³

^1.Institute of Physics & Optoelectronics Technology, Baoji University of Arts and Sciences, Baoji 721016, Shaanxi, China
^2.College of Electronic and Optical Engineering & College of Microelectronics, Nanjing University of Posts and Telecommunications, Nanjing 210023, Jiangsu, China
^3.Shaanxi Baoguang Vacuum Electric Device Co. , Ltd. , Baoji 721006, Shaanxi, China

Online:2020-05-05 Published:2020-05-25
Contact: Shebao LIN

摘要/Abstract

摘要：

高折射率和非线性光学玻璃可以用于高速光开关、光学存储器、新型光纤和光学运算元件等，其研究受到各国科技工作者的高度重视，本文采用熔融淬冷法制备了组成为(85-x)B₂O₃-15K₂O-xSb₂O₃(x=70, 75, 80, 85)的4组玻璃，测试了玻璃样品的密度、折射率、热学性能、拉曼光谱和吸收光谱，利用玻璃样品的吸收光谱计算了其直接允许光学带隙、间接允许光学带隙及Urbach能量。结果表明：随着Sb₂O₃含量的增加，玻璃样品的密度从4.445g/cm³逐渐增加到4.767g/cm³，折射率从1.9438增加到2.0058，玻璃转变温度从291℃降低到260℃，玻璃析晶温度从463℃降低到370℃，直接光学带隙从3.2775eV降低到3.1379eV，间接光学带隙从3.1444eV降低到3.0256eV，Urbach能量从0.137eV逐渐减小到0.107eV。说明Sb₂O₃-K₂O-B₂O₃系统玻璃可以作为新型的非线性光学玻璃候选材料之一。

关键词: 三氧化二锑玻璃, 折射率, 光学带隙, Urbach能量, 热学性能

Abstract:

Nonlinear optical glasses can be used in high-speed optical switch, optical memory, new optical fibers, optical operational elements and so on, so the research on non-linear optical glass has attracted great attention of scientists and technicians all over the world. In this paper, four groups of glasses (85-x) B₂O₃-15K₂O-xSb₂O₃ (x=70, 75, 80, 85) were prepared by melt quenching method. The density, refractive index, thermal properties, Raman spectra and absorption spectra of the samples were measured. The direct and indirect allowed band gaps and Urbach energy were calculated by the absorption spectra of the samples. The results showed that with the increase of Sb₂O₃ content, the density of glass sample increased from 4.445g/cm³ to 4.767g/cm³, the refractive index increased from 1.9438 to 2.0058, the glass transition temperature decreased from 291℃ to 260℃, the crystallization temperature of glass decreases from 463℃ to 370℃, the direct optical band gap decreased from 3.2775eV to 3.1379eV, the indirect optical band gap decreased from 3.1444eV to 3.0256eV and the Urbach energy decreased from 0.137eV to 0.107eV. It was concluded that Sb₂O₃-K₂O-B₂O₃ system glass can be used as one of the new non-linear optical glass candidates.

Key words: diantimony trioxide glass, refrative index, optical bandgap, Urbach energy, thermal properties

中图分类号:

TQ171

林社宝, 史东阳, 冯爱玲, 刘春晓, 许强, 赵磊, 郭佳伟, 王伟. B₂O₃-K₂O-Sb₂O₃系统玻璃的光学折射率及带隙[J]. 化工进展, 2020, 39(5): 1882-1887.

Shebao LIN, Dongyang SHI, Ailing FENG, Chunxiao LIU, Qiang XU, Lei ZHAO, Jiawei GUO, Wei WANG. Optical refrative index and band gap of B₂O₃-K₂O-Sb₂O₃ system glasses[J]. Chemical Industry and Engineering Progress, 2020, 39(5): 1882-1887.

参考文献

1	DOWEIDAR H, EL-EGILI K, RAMADAN R, et al. Structural investigation and properties of Sb₂O₃-PbO-B₂O₃ glasses[J]. Journal of Non-Crystalline Solids, 2018, 497: 93.
2	WANG Y, DAI S, CHEN F, et al. Physical properties and optical band gap of new tellurite glasses within the TeO₂-Nb₂O₅-Bi₂O₃ system[J]. Materials Chemistry and Physics, 2009, 113(1): 407.
3	HASHIMOTO T, YOKO T, SAKKA S. Sol–gel preparation and third-order nonlinear optical properties of TiO₂ thin films[J]. Bulletin of the Chemical Society of Japan, 1994, 67(3): 653.
4	NASU H, MATSUOKA J, KAMIYA K. Second-and third-order optical non-linearity of homogeneous glasses[J]. Journal of Non-Crystalline Solids, 1994, 178: 23.
5	NASU H, ITO T, HASE H, et al. Third-order optical non-linearity of Bi₂O₃-based glasses[J]. Journal of Nnon-Crystalline Solids, 1996, 204(1): 78.
6	陈飞飞, 戴世勋, 沈祥, 等. Bi₂O₃-B₂O₃-BaO系玻璃的光学折射率与带隙[J]. 硅酸盐学报, 2008, 36(4): 515.
6	CHEN Feifei, DAI Shixun, SHEN Xiang, et al. Refractive index and band gap of Bi₂O₃-B₂O₃-BaO glasses[J]. Journal of the Chinese Ceramic Society, 2008, 36(4): 515.
7	SALEM S M, SHALTOUTH I. Structure, electrical, and optical properties of ZnO-substituted PbO for the Er³⁺/Yb³⁺co-doped Bi₂O₃-GeO₂-Na₂O glass system[J]. Journal of Materials Science, 2010, 45(7): 1837.
8	章健良, 聂秋华, 戴世勋, 等. Bi₂O₃-B₂O₃-Ga₂O₃玻璃的光学折射率和带隙研究[J]. 硅酸盐通报, 2010, 29(2): 340.
8	ZHANG Jianliang, NIE Qiuhua, DAI Shixun, et al. Refractive index and band gap investigation in Bi₂O₃-B₂O₃-Ga₂O₃ glass[J]. Bulletin of the Chinese Ceramic Society, 2010, 29(2): 340.
9	MALLUR S B, CZARNECKI T, ADHIKARI A, et al. Compositional dependence of optical band gap and refractive index in lead and bismuth borate glasses[J]. Materials Research Bulletin, 2015, 68: 27.
10	TICHA H, SCHWARZ J, TICHY L. On the structural arrangement and optical band gap (PbO)_x(ZnO)₁₀(TeO₂)_90-_x glasses[J]. Journal of Non-Crystalline Solids, 2017, 459: 63.
11	陈东丹. 掺稀土碲酸盐玻璃与光纤应用基础问题研究[D]. 广州: 华南理工大学, 2010.CHEN Dongdan. Rare-earth doped tellurite glasses and tellurite glass optical fiber[D]. Guangzhou: South China University of Technology, 2010.
12	SOM T, KARMAKAR B. Enhancement of Er³⁺ upconverted luminescence in Er³⁺Au-antimony glass dichroic nanocomposites containing hexagonal Au nanoparticles[J]. Journal of the Optical Society of America B, 2009, 26(12): B21.
13	YOUNGMAN R E, SEN S, CORNELIUS L K, et al. Novel structural aspects of Sb₂O₃- B₂O₃ glasses[J]. Physics and Chemistry of Glasses, 2003, 44(2): 69.
14	TERASHIMA K, HASHIMOTO T, UCHINO T, et al. Structure and nonlinear optical properties of Sb₂O₃-B₂O₃ binary glasses[J]. Journal- Ceramic Society Japan, 1996, 104(11): 1008.
15	罗渝然.化学键能数据数据手册[M]. 北京:科学技术出版社, 2005: 299.
15	LUO Yuran. Handbook of chemical bond energy data[M]. Beijing: Science and Technology Press, 2005: 299.
16	宋天佑，徐家宁，程功臻.无机化学[M]. 北京: 高等教育出版社, 2004: 418.
16	SONG Tianyou, XU Jianing, CHENG Gongzhen. Inorganic chemistry[M]. Beijing: Higher Education Press, 2004: 418.
17	DAI S, WU J, ZHANG J, et al. The spectroscopic properties of Er³⁺-doped TeO₂-Nb₂O₅ glasses with high mechanical strength performance[J]. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 2005, 62(1/3): 431.
18	刘恩科，朱秉升，罗晋生.半导体物理学[M]. 北京: 电子工业出版社, 2008: 420.
18	LIU Enke, ZHU Bingsheng, LUO Jinsheng. Semiconductor physics[M].Beijing: Electronic Industry Press, 2008: 420.
19	王慧, 符博, 邵竹锋，等. 石英玻璃激光损伤阈值研究进展与现状[J]. 硅酸盐通报, 2017, 36(s): 316.
19	WANG Hui, FU Bo, SHAO Zhufeng, et al. Progresses and situation of quartz silica glass in the study of laser damage threshold[J]. Bulletin of The Chinese Ceramic Society, 2017, 36 (s): 316.

B₂O₃-K₂O-Sb₂O₃系统玻璃的光学折射率及带隙

Optical refrative index and band gap of B₂O₃-K₂O-Sb₂O₃ system glasses

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