调剖驱油技术中弱凝胶体系研究进展

doi:10.16085/j.issn.1000-6613.2015.05.024

化工进展 ›› 2015, Vol. 34 ›› Issue (05): 1323-1331.DOI: 10.16085/j.issn.1000-6613.2015.05.024

调剖驱油技术中弱凝胶体系研究进展

许定佳¹, 郑永付², 张松¹, 赵莹莹¹, 李文卓¹, 沈丁丰¹

1. 南京林业大学化学与材料系, 江苏南京 210037;
2. 辽宁辽河油田康达实业集团有限公司, 辽宁盘锦 124010

收稿日期:2014-09-01 修回日期:2014-12-30 出版日期:2015-05-05 发布日期:2015-05-05
通讯作者: 李文卓,副教授,主要从事材料化学研究.E-mailwzli@njfu.com.cn.
作者简介:许定佳(1989—),男,硕士研究生.
基金资助:
江苏省自然基金面上项目(BK20141471)及“钻井粘土新材料的研发和以天然有机资源合成采油助剂的研究”校企合作课题.

Application progress of weak gel systems in oilfield profile control technology

XU Dingjia¹, ZHENG Yongfu², ZHANG Song¹, ZHAO Yingying¹, LI Wenzhuo¹, SHEN Dingfeng¹

1. Department of Chemistry and Material Science, Nanjing Forestry University, Nanjing 210037, Jiangsu, China;
2. Liaoning Liaohe Oilfield Kangda Industrial Group Co., Ltd., Panjin 124010, Liaoning, China

Received:2014-09-01 Revised:2014-12-30 Online:2015-05-05 Published:2015-05-05

摘要/Abstract

摘要： 弱凝胶体系调驱技术是通过降低油田高渗透层渗透率、提高水驱波及系数、改善水驱开发效果来实现原油稳产的重要手段.本文综述了近年来原油开采过程中用于调驱技术的弱凝胶体系基本组成,不同交联剂对弱凝胶体系的成胶机理和成胶条件及弱凝胶体系性能的评价方法.总结了稳定剂、杀菌剂、抗盐剂、延迟剂等助剂和温度、矿化度、pH值等环境因素对弱凝胶体系性能的影响;概述了弱凝胶体系的矿场应用技术现状和现有弱凝胶体系在调剖应用中仍存在的问题.提出在传统表观方法研究弱凝胶交联机理的基础上,利用激光光散射法、原子力显微镜和计算机分子动力学模拟等技术加强对弱凝胶交联微观机理研究,为开发新型长效且廉价的调剖剂提供理论依据.

关键词: 弱凝胶, 调剖, 成胶机理, 评价方法, 计算机分子动力学模拟

Abstract: Oil production can be improved by profile control technologies,including the decrease of the permeability of high permeable zone and the increase of water-flooded sweep efficiency contributions. The most important chemical systems applied in present profile control technologies are weak gel systems with many great merits in promoting oil output. In this paper,we make a summarization on following aspects:The basic component of weak gel systems used in oil exploration by profile control technologies in recent years,the mechanism and condition of the formation of weak gel systems initiated by different crosslinking agents,and the evaluation methods of the performance of weak gel systems. It is also discussed that how additives,including stabilizing agents,bactericides,salt resistances,delay agents,etc.,and environmental factors,such as temperature,salinity,pH,etc.,affect the properties of weak gel systems. Based on the current application of weak gel systems,it is pointed out that there are still some problems unsolved in the profile control processes when the weak gel systems are employed. To develop new effective and inexpensive profile control agents and make the corresponding theoretical basis to new agents,methods to investigate the gelling mechanism of weak gel systems need to be improved. The improvement is going to be a transition from traditional macroscopic research methods to microscopic research methods,such as the laser light scattering,atomic force microscope and computer molecular dynamic simulation,etc.

Key words: weak gel, profile control, gelling mechanism, evaluation method, computer molecular dynamic simulation

中图分类号:

TE35

许定佳, 郑永付, 张松, 赵莹莹, 李文卓, 沈丁丰. 调剖驱油技术中弱凝胶体系研究进展[J]. 化工进展, 2015, 34(05): 1323-1331.

XU Dingjia, ZHENG Yongfu, ZHANG Song, ZHAO Yingying, LI Wenzhuo, SHEN Dingfeng. Application progress of weak gel systems in oilfield profile control technology[J]. Chemical Industry and Engineering Progree, 2015, 34(05): 1323-1331.

参考文献

[1] 张宇. 弱凝胶体系成胶性能影响因素研究[J]. 天然气与石油,2013,31(4):70-72.

[2] Su Z,Jiang Z,Huang G,et al. Mechanism of formation of partially crosslinked polyacrylamide complexes[J]. Journal of Macromolecular Science,Part B,2013,52(1):22-35.

[3] 包木太,巩元娇. 微生物固定法降解含油污水的研究进展[J]. 化工进展,2009,28(3):511-517.

[4] Rahul R,Jha U,Sen G,et al. A novel polymeric flocculant based on polyacrylamide grafted inulin: Aqueous microwave assisted synthesis[J]. Carbohydrate Polymers,2014,99:11-21.

[5] 谢锦龙,黄冲,王晓星. 中国碳酸盐岩油气藏探明储量分布特征[J]. 海相油气地质,2009,14(2):24-30.

[6] 吕宇玲,丁慎圆,何利民,等. 聚丙烯酰胺水溶液管道流动特性研究[J]. 化工进展,2014,33(10):2592-2597.

[7] Liu Y L,Qin Y. Improvement research of organic phenolic gel being used to be an organic deep profile control agent[J]. Advanced Materials Research,2014,908:46-50.

[8] Lu X,Liu J,Wang R,et al. Study of action mechanisms and properties of Cr³⁺ cross-linked polymer solution with high salinity[J]. Petroleum Science,2012,9(1):75-81.

[9] 包木太,周营营,陈庆国. 部分水解聚丙烯酰胺溶液稳定性的影响因素[J]. 化工进展,2011,30(s1):230-234.

[10] 杜忠磊,王健,沈群,等. 耐高温堵剂的室内研究[J]. 精细石油化工进展,2013,14(4):29-33.

[11] 王纪伟,付宗委,赵宇,等. 厄瓜多尔 Oriente 油田抗高温高盐聚合物驱油剂的研究[J]. 油田化学,2014,31(3):82-85.

[12] 袁瑞,李英,方洪波,等. 部分水解的疏水改性聚丙烯酰胺分子构型与体相行为的关系[J]. 物理化学学报,2013,29(4):706-714.

[13] 王惠厦,姚林,丁彬,等. 疏水改性聚丙烯酰胺溶液的分子模拟[J]. 高等学校化学学报,2013,34(5):1295-1302.

[14] Dou H M,Zhu X Y,Shi X W,et al. Research and application of a novel deep profile modification agent for complex sandstone reservoirs[J]. Applied Mechanics and Materials,2013,316:773-776.

[15] 韩冬,徐稳杰,韦莉,等. 聚丙烯酰胺与 Cr(Ⅲ)低聚物交联机理的研究[J]. 高分子学报,2001(6):716-719.

[16] Hua Z,Lin M,Dong Z,et al. Experimental study on the deep profile control and oil displacement technology of nanoscale polymer microspheres[J]. Structural Longevity,2013,9(2):119-129.

[17] Nguyen N T B,Tu T N,Bae W,et al. Gelation time optimization for an HPAM/chromium acetate system:The successful key of conformance control technology[J]. Energy Sources,Part A:Recovery,Utilization,and Environmental Effects,2012,34(14):1305-1317.

[18] 张艳英,蒲万芬,唐山,等. 低温油藏深部调驱用弱凝胶体系研究[J]. 应用化工,2012,41(4):570-572.

[19] 李文卓,许定佳,富强. 具有缓释性能的微凝胶稳定剂及其制备方法:中国,201410284100.1[P]. 2014-10-01.

[20] 刘平德,张松,冯爱丽,等. 延缓交联弱凝胶调驱剂的研制与性能评价[J]. 石油钻采工艺,2013,35(3):90-93.

[21] 胡晓蝶,王健,刘培培. 耐高温深部调驱剂实验研究[J]. 精细石油化工进展,2010,8:5-9.

[22] Dang T Q C,Chen Z,Nguyen T B N,et al. The development and optimization of a polymer conformance control technology in mature reservoirs:Laboratory experiments vs. Field scale simulation[J]. Energy Sources,Part A:Recovery,Utilization,and Environmental Effects,2014,36(11):1219-1233.

[23] Xin H,Chen H,Wang X,et al. Fabrication of the weak gel based on hydrolyzed polyacrylamide crosslinked by inorganic-organic mixed crosslinker[J]. Journal of Polymer Research,2013,20(12):1-7.

[24] 李丛妮,雷珂,朱明道. 柠檬酸铝交联剂的制备及其性能影响因素研究[J]. 化学工程师,2013(5):14-16.

[25] Taylor K C,Nasr-El-Din H A. Water-soluble hydrophobically associating polymers for improved oil recovery:A literature review[J]. Journal of Petroleum Science and Engineering,1998,19(3):265-280.

[26] 李超群,王增宝,闫国峰,等. 耐温抗盐型 HPAM/酚醛树脂冻胶体系研究[J]. 精细石油化工进展,2012,13(1):4-7.

[27] 邱玲,蒲万芬,张晶. 改进型酚醛树脂交联剂的合成与成胶性能[J]. 精细石油化工进展,2011,12(8):15-18.

[28] Moghadam A M,Sefti M V,Salehi M B,et al. Bulk and rheological properties of polyacrylamide hydrogels for water shutoff treatment[J]. Korean Journal of Chemical Engineering,2014,31(3):532-539.

[29] 包木太,彭杰,陈庆国. 微生物对聚丙烯酰胺降解作用的研究进展[J]. 化工进展,2011,30(9):2080-2086.

[30] Zhao G,Dai C,Zhao M,et al. The use of environmental scanning electron microscopy for imaging the microstructure of gels for profile control and water shutoff treatments[J]. Journal of Applied Polymer Science,2014,131(14):1-7.

[31] 张荣明,夏树斌,马冬晖,等. 碱性铬溶胶原位交联剂制备[J]. 石油化工高等学校学报,2014,27(1):75-78.

[32] Rafipoor M,Sefti M V,Salimi F,et al. Investigation of rheological properties of polyacrylamide/chromium triacetate hydrogels performed for water shutoff treatment in oil reservoirs[J]. Journal of Dispersion Science and Technology,201,35(1):56-63.

[33] Liu X J,Cao G S,Gao B C,et al. Chemical agents formula of deep profile controlling for Niuxintuo fractured reservoir[J]. Advanced Materials Research,2014,1008:281-284.

[34] 秦义,徐方向,刘志辉,等. 聚丙烯酰胺/酚醛弱凝胶体系调剖堵剂的优化[J]. 精细石油化工,2013,30(5):30-32.

[35] 曹绪龙,刘坤,韩玉贵,等. 耐温抗盐缔合聚合物的合成及性能评价[J]. 油气地质与采收率,2014,21(2):10-14.

[36] Koohi A D,Moghaddam A Z,Sefti M V,et al. Swelling and gelation time behavior of sulfonated polyacrylamide/chromium triacetate hydrogels[J]. Journal of Macromolecular Science,Part B,2011,50(10):1905-1920.

[37] Zhao G,Dai C,You Q,et al. Study on formation of gels formed by polymer and zirconium acetate[J]. Journal of Sol-gel Science and Technology,2013,65(3):392-398.

[38] Kedir A S,Seland J G,Skauge A,et al. Nanoparticles for enhanced oil recovery:Phase transition of aluminum-cross-linked partially hydrolyzed polyacrylamide under low-salinity conditions by rheology and nuclear magnetic resonance[J]. Energy & Fuels,2014,28(5):2948-2958.

[39] Jung J C,Zhang K,Chon B H,et al. Rheology and polymer flooding characteristics of partially hydrolyzed polyacrylamide for enhanced heavy oil recovery[J]. Journal of Applied Polymer Science,2013,127(6):4833-4839.

[40] 韦强,张文军,冯向东. 长庆低渗透裂缝性油藏调剖技术研究[J].辽宁化工,2013,42(9):1125-1131.

[41] Li G,Zhang G,Wang L. Smart profile control by salt-reversible flocculation of cationic microgels and polyacrylamide[J]. Energy & Fuels,2013,27(11):6632-6636.

[42] Liu J,Lu X,Sui S. Synthesis,evaluation and gelation mechanism of organic chromium[J]. Journal of Applied Polymer Science,2012,124(5)3669-3677.

[43] Dai C,Zhao G,You Q,et al. A study on environment-friendly polymer gel for water shut-off treatments in low-temperature reservoirs[J]. Journal of Applied Polymer Science,2014,131(8):1-7.

[44] 张明霞,杨全安,王守虎. 堵水调剖剂的凝胶性能评价方法综述[J]. 钻采工艺,2007,30(4):130-133.

[45] Yang G,Zhang J,Xue X S,et al. Development and evaluation of salt-resisting polymer gel profile control agent[J]. Advanced Materials Research,2013,781:426-430.

[46] 曲波,战洪浩,鲁印龙,等. 锦 90 块弱凝胶深部调驱配方体系的筛选[J]. 精细石油化工进展,2012,13(8):29-31.

[47] 杨红斌,蒲春生,李淼,等. 自适应弱凝胶调驱性能评价及矿场应用[J]. 油气地质与采收率,2013,20(6):83-86.

[48] 李道山,于娣,汪娟娟,等. 大港油田复杂断块高温高盐油藏深部调剖研究[J]. 石油地质与工程,2014,28(1):134-143.

[49] Li W Z,Wang J L,Xu D J,et al. Study on adsorption and desorption of urea in lignosulfonate with molecular simulations[J]. Computational and Theoretical Chemistry,2014,32(1):60-66.

调剖驱油技术中弱凝胶体系研究进展

Application progress of weak gel systems in oilfield profile control technology

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 5

编辑推荐

Metrics

本文评价

[1]	李卫华, 吴寅凯, 孙英杰, 尹俊权, 辛明学, 赵友杰. 垃圾焚烧飞灰重金属毒性浸出评价方法研究进展[J]. 化工进展, 2023, 42(5): 2666-2677.
[2]	刘敏, 杨铮. 金属双极板表面改性涂层的评价方法研究进展[J]. 化工进展, 2020, 39(S2): 276-284.
[3]	李鹏章, 李爱民, 陈博之, 戴建军, 唐敏. 基于活性污泥呼吸速率的化工废水水质评价方法[J]. 化工进展, 2020, 39(6): 2472-2478.
[4]	马腾, 丛宏斌, 王敬茹, 赵立欣, 姚宗路, 孟海波, 霍丽丽. 生物质热解油/柴油乳化效果评价方法及影响因素[J]. 化工进展, 2018, 37(10): 4098-4108.
[5]	曾维才，石碧. 天然产物抗氧化活性的常见评价方法[J]. 化工进展, 2013, 32(06): 1205-1213.