Progress of seasonal solar energy storage using supercooled salt hydrate phase change materials

doi:10.16085/j.issn.1000-6613.2017-1564

Abstract

Abstract: Seasonal solar energy storage can be used to alleviate the disadvantages of the solar radiation instability and the mismatch contradiction between the solar energy supply and demands of the building load, and improve the efficiency of solar energy utilization. Based on the comparison among different types of seasonal heat storage methods, the paper mainly reviewed the seasonal thermal storage technology using supercooled salt hydrate phase change materials(PCMs) and corresponding research progress. Firstly, The principle of supercooled thermal storage and key problems in storage system were analyzed, including the selection of salt hydrates, the stable supercooling implementation of salt hydrates, the activation methods of crystallization to release energy, system matching design and performance, phase separation and corrosion of salt hydrates. It was indicated that the calcium chloride hexahydrate, the sodium phosphate dibasic dodecahydrate, the sodium acetate trihydrate and the sodium thiosulfate pentahydrate were suitable PCMs because of appropriate phase transition temperature and the large heat storage density. In addition, corresponding with other key problems of the storage system, the effecting factors and the solution strategies were also analyzed, which could provide theoretical basis and guidance for system design and practical application of seasonal heat storage using supercooled salt hydrates. Finally, the outlook for further research was presented.

Key words: inorganic salt hydrates, seasonal heat storage, stable supercooling, induced crystallization, phase separation

摘要： 跨季节储存太阳能可以缓解太阳辐射不稳定以及与建筑负荷供需不匹配的矛盾，提高太阳能利用效率。本文在比较各类跨季节蓄热方式基础上，着重阐述了过冷水合盐相变材料跨季节蓄热技术及研究进展。分析研究了过冷水合盐跨季节蓄热原理和系统及目前研究的焦点问题，包括水合盐相变材料的选择、稳定过冷的实现、触发释能方法、系统匹配设计和性能、相分离和腐蚀性。结果指出六水氯化钙、十二水磷酸氢二钠、三水合乙酸钠和五水硫代硫酸钠由于相变温度适宜、储热密度较大等优点，是跨季节蓄热材料的研究重点。其次针对系统存在的其他焦点问题，逐一分析其影响因素并总结了目前解决策略，为水合盐过冷跨季节蓄热系统的设计和实际应用提供理论依据和指导，最后指出了进一步研究的方向。

关键词: 无机水合盐, 跨季节蓄热, 稳定过冷, 触发结晶, 相分离

CLC Number:

TU832.17

ZHU Maochuan, ZHOU Guobing, YANG Fei, TIAN Fukuan. Progress of seasonal solar energy storage using supercooled salt hydrate phase change materials[J]. Chemical Industry and Engineering Progress, 2018, 37(06): 2256-2268.

朱茂川, 周国兵, 杨霏, 田富宽. 过冷水合盐相变材料跨季节储存太阳能研究进展[J]. 化工进展, 2018, 37(06): 2256-2268.

References

[1] 叶晓莉,端木琳,齐杰.零能耗建筑中太阳能的应用[J].太阳能学报,2012,33(1):87-89. YE X L,DUAN M L,QI J.The application of solar energy in zero energy consumption buildings[J].Acta Energiae Solaris Sinica,2012,33(1):87-89.
[2] FISCH M N,GUIGAS M,DALENBACK J O.A review of large-scale solar heating systems in Europe[J].Solar Energy,1998,63(6):355-366.
[3] 孟锋,安青松,郭孝峰,等.蓄热过程强化技术的应用研究进展[J].化工进展,2016,35(5):1273-1282. MENG F,AN Q S,GUO X F,et al. Progress in the application of heat storage process reinforcement technology[J].Chemical Industry and Engineering Progress,2016,35(5):1273-1282.
[4] BAUER D,MARX R,OCHS F,et al.German central solar heating plants with seasonal heat storage[J].Solar Energy,2010,84(4):612-623.
[5] 韩旭,卢铁江,文正江,等.跨季节蓄热太阳能供热系统的技术进展[J].制冷与空调,2012,26(3):228-233. HAN X,LU T J,WEN Z J,et al.Technical progress of solar energy heating system with seasonal heat storage[J].Refrigeration and Air-conditioning,2012,26(3):228-233.
[6] ZHAO D L,LI Y,DAI Y J,et al.Optimal study of a solar air heating system with pebble bed energy storage[J].Energy Convers,2011,52(6):2392-2400.
[7] MANGOLD D,SCHMIDT T,et al.Seasonal thermal energy storage in Germany[J].Structural Engineering International,2004,14(3):230-232.
[8] 赵璇,赵彦杰,王景刚,等.太阳能跨季节储热技术研究进展[J].新能源进展,2017,5(1):73-80. ZHAO X,ZHAO Y J,WANG J G,et al.Research progress of solar energy seasonal thermal storage technology[J].Advances in New and Renewable Energy,2017,5(1):73-80.
[9] CABEZA L,CASTELL A,BARRENECHE C,et al.Materials used as PCM in thermal energy storage in buildings:a review[J].Renewable and Sustainable Energy Reviews,2011,15(3):1675-1695.
[10] 项宇彤. 水合盐过冷蓄能单元设计与触发释能特性实验研究[D].北京:华北电力大学,2016. XIANG Y T.Experiment study on discharging characteristics of heat storage unit based on supercooling of salt hydrate[D].Beijing:North China Electric Power University,2016.
[11] 张仁元.相变材料与相变储能技术[M].北京:科学出版社,2009. ZHANG R Y.Phase change materials and phase change energy storage technology[M].Beijing:Science Press,2009.
[12] SCHULTZ J M.Phase change material storage with supercooling[C]//STREICHER W.IEA SHC Task 32-Advanced storage concepts for solar and low energy buildings.Austria:Graz University of Technology Austria,2008:68-84.
[13] JANKOWSKI N R,MCCLUSKEY F P. A review of phase change materials for vehicle component thermal buffering[J].Applied Energy,2014,113:1525-1561.
[14] PEREIRA J,EAMES P.Thermal energy storage for low and medium temperature applications using phase change materials-a review[J]. Applied Energy,2016,177:227-238.
[15] 章学来,盛青青,葛轶群.十二水磷酸氢二钠相变性能改进研究[J].化学工程,2009,37(5):53-56. ZHANG X L,SHENG Q Q,GE Y Q.Study on improvement of phase transformation properties of sodium phosphate dibasic dodecahydrate[J]. Chemical Engineering,2009,37(5):53-56.
[16] HAILLOT D,BAUER T,TAMME R.Thermal analysis of phase change materials in the temperature range 120-150℃[J].Thermochimica Acta,2011,513:49-59.
[17] 盛青青,章学来,葛轶群.十二水磷酸氢二钠的相变性能[J].化工进展,2008,27(6):900-903. SHENG Q Q,ZHANG X L,GE Y Q.Phase transformation properties of sodium phosphate dibasic dodecahydrate[J].Chemical Industry and Engineering Progress,2008,27(6):900-903.
[18] 徐建霞,柯秀芳. CH₃COONa·3H₂O相变储能性能研究[J].材料开发与应用,2007,22(6):24-27. XU J X,KE X F.Study on phase change energy storage performance of CH₃COONa·3H₂O[J].Development and Application of Materials,2007,22(6):24-27.
[19] 刘欣,徐涛,高学农,等.十水硫酸钠的过冷和相分离探究[J].化工进展,2011,30(1):755-758. LIU X,XU T,GAO X N,et al.Research on supercooling and phase separation of sodium sulfafe decahydrate[J].Chemical Industry and Engineering Progress,2011,30(1):755-758.
[20] 金星,张小松.三水乙酸钠部分融化时的相变特性分析[C]//2011中国制冷学会学术年会论文集,南京,2011. JIN X,ZHANG X S.Phase change characteristics of sodium acetate trihydrate during partial melting[C]//Proceedings of Annual Conference of Chinese Association of Refrigeration,Nanjing,2011.
[21] FAN J H,FURBO S,ANDERSEN E,et al.Thermal behavior of a heat exchanger module for seasonal heat storage[J].Energy Procedia,2012,30(1):244-254.
[22] FURBO S,FAN J H,ANDERSEN E,et al.Development of seasonal heat storage based on stable supercooling of a sodium acetate water mixture[J].Energy Procedia,2012,30(1):260-269.
[23] ZHOU G B,HAN Y W.Numerical simulation on thermal characteristics of supercooled salt hydrate PCM for energy storage:multiphase model[J]. Applied Thermal Engineering,2017,125:145-152.
[24] DANNEMAND M,DRAGSTED J,FAN J H,et al.Experimental investigations on prototype heat storage units utilizing stable supercooling of sodium acetate trihydrate mixtures[J].Applied Energy,2016,169:72-80.
[25] 周国兵,韩玉维,王雪皎.一种利用水合盐相变材料稳定过冷蓄能装置及方法与应用:CN201410025949.7[P].2014-04-23. ZHOU G B,HAN Y W,WANG X J. Application and method for stable supercooling storage device by using salt hydrates phase change materials:CN201410025949.7[P].2014-04-23.
[26] 韩玉维. 过冷水合盐相变材料释热特性模拟研究[D]. 北京:华北电力大学,2015. HAN Y W.Simulation on discharging characteristics of supercooled salt hydrate phase change materials[D].Beijing:North China Electric Power University,2015.
[27] 刘圣春,姜婷婷,董紫腾. 纯水和氯化钠溶液凝固过程的实验研究[J]. 化工进展,2016,35(2):68-74. LIU S C,JIANG T T,DONG Z T.Experimental study on water and sodium chloride solution solidification[J].Chemical Industry and Engineering Progress,2016,35(2):68-74.
[28] 茅靳丰,李金田,刁孝发,等. 融化和凝固温度对三水乙酸钠相变储热性能的影响[J]. 制冷学报,2011,32(2):50-53. MAO J F,LI J T,DIAO X F,et al.Impact of melting and solidification temperature on the phase change heat storage properties of sodium acetate trihydrate[J].Journal of Refrigeration,2011,32(2):50-53.
[29] WEI L L,KENICHI O.Supercooling and solidification behavior of phase change[J]. ISIJ International,2010,50(9):1265-1269.
[30] CHEN S L,LEE T S.A study of supercooling phenomenon and freezing probability of water inside horizontal cylinders[J]. International Journal of Heat and Mass Transfer,1998,41:769-783.
[31] ARNOLD D.Laboratory performance of an encapsulated iced-ice store[J].ASHRAE Transactions,1991,97(2):1170-1178.
[32] 仝兆丰.储热材料AlNH₄(SO₄)₂·12H₂O的过冷性实验研究[J].太阳能学报,1997,18(3):346-348. TONG Z F.Experimental study for supercooling of AlNH₄(SO₄)₂·12H₂O[J].Acta Energiae Solaris Sinica,1997,18(3):346-348.
[33] SANDNES B,REKSTAD J.Supercooling salt hydrates:stored enthalpy as a function of temperature[J].Solar Energy,2006,80(5):616-625.
[34] 朱冬生,剧霏,刘超,等.相变材料CH₃COONa·3H₂O的研究进展[J].中国材料科技与设备,2007(1):30-34. ZHU D S,JU F,LIU C,et al.Research progress of phase change material CH₃COONa·3H₂O[J].Chinese Materials Science Technology and Equipment,2007(1):30-34.
[35] 徐伟亮.水合乙酸钠相变蓄热研究[J].科技通报,1999,15(4):288-291. XU W L.Study on the hydrated sodium acetate as the materials of phase changing storage heat[J].Bulletin of Science and Technology,1999,15(4):288-291.
[36] 刘栋,徐云龙.成核剂对CaCl₂·6H₂O相变材料储热性能的影响[J].太阳能学报,2007,28(7):732-738. LIU D,XU Y L.Effects of nucleators on the thermal storage properties of CaCl₂·6H₂O phase change materials[J].Acta Energiae Solaris Sinica,2007,28(7):732-738.
[37] ROGERSON M A,CARDOSO S S S.Solidification in heat packs:I. nucleation rate[J].AIChE Journal,2010,49(2):505-515.
[38] 潘利红,黄立维,岳桥,等.振动对无机盐相变材料过冷度的影响[J].浙江工业大学学报,2008,36(6):655-658. PAN L H,HUANG L W,YUE Q,et al.Influence of vibration on the supercooling relex of inorganic salt solution as a phase change material[J]. Journal of Zhejiang University of Technology,2008,36(6):655-658.
[39] SEO K,SUZUKI S,KINOSHITA T,et al.Effect of ultrasonic irradiation on the crystallization of sodium acetate trihydrate utilized as heat storage material[J].Chemical Engineering and Technology,2012,35(6):1013-1016.
[40] LYCZKO N,ESPITALIER F,LOUISNARD O,et al.Effect of ultrasound on the induction time and the metastable zone widths of potassium sulphate[J]. Chemical Engineering Journal,2002,86(3):233-241.
[41] 王葳,张绍志,陈光明,等.超声波对水的过冷度影响的实验研究[J].制冷学报,2003,24(1):6-8. WANG W,ZHANG S Z,CHEN G M,et al.Experimental study of the effects of ultrasound on the supercooling of water[J].Journal of Refrigeration,2003,24(1):6-8.
[42] 王伟宁,吕秉玲.超声波在碱式氯化镁结晶中的应用研究[J].无机盐工业,1990(3):22-23. WANG W N,LV B L.Study on the application of ultrasonic wave in the crystallization of basic magnesium chloride[J].Inorganic Chemicals Industry,1990(3):22-23.
[43] 孟磊.超声对硫酸铜结晶过程的影响[D]. 扬州:扬州大学,2007. MENG L.Effect of ultrasound on crystallization process of copper sulfate[D]. Yangzhou:Yangzhou University,2007.
[44] HOZUMI T,SAITO A,OKAWA S. Freezing phenomena of supercooled water under impacts of ultrasonic waves[J].International Journal of Refrigeration,2002,25(7):948-953.
[45] 方金升. 磁场对低温相变蓄冷材料过冷度和结晶过程影响的实验研究[D]. 济南:山东大学,2011. FANG J S.Experimental research on effects of magnetic field on supercooling degree and crystallization process of low temperature cool storage materials[D].Jinan:Shandong University,2011.
[46] 柴诚敬,贾绍义,李宗堂,等.磁化技术在化工分离领域中的应用[J].化学工业与工程,1999,16(4):245-247. CHAI C J,JIA S Y,LI Z T,et al.Application of magnetization technology in the field of chemical separation[J].Chemical Industry and Engineering,1999,16(4):245-247.
[47] WANG Y,BABCHIN J,CHERNYI L T,et al.Rapid onset of calcium carbonate crystallization under the influence of a magnetic field[J].Water Research,1997,31(2):346-350.
[48] 杨筠,杨祖荣,史季芬,等.磁场对碳酸氢钠结晶动力学的影响[J].北京化工大学学报,1997,24(2):l-7. YANG Y,YANG Z R,SHI J F,et al.The effection of magnetic field on the crystalline dynamics with a new type of carbonating column[J].Journal of Beijing University of Chemical Technology,1997,24(2):1-7.
[49] 陈照章,王恒海,黄永红,等.交变磁场对含盐溶液冰晶形成的影响[J].应用科学学报,2008,26(2):l45-149. CHEN Z Z,WANG H H,HUANG Y H,et al.Influence of alternated magnetic field on ice crystal formation process in aqueous solution[J].Journal of Applied Sciences,2008,26(2):145-149.
[50] 杨琥,严晓虎,王治流,等.静电场诱导十二烷基硫酸钠结晶行为的研究[J].高等学校化学学报,2001,22(4):666-668. YANG H,YAN X H,WANG Z L,et al.The crystallizing behavior of sodium dodecyl sulfate under a electro-static field[J].Chemical Journal of Chinese Universities,2001,22(4):666-668.
[51] GARETZ B A,MYERSON A S,ARNOLD S,et al.Method for using a static electric field to induce crystallization and to control crystal form:US7879115[P].2011-02-01.
[52] MARAND H,STEIN R S.Isothermal crystallization of poly(vinylidene fluoride) in the presence of high static electric fields. Ⅱ. Effect of crystallization temperature and electric field strength on the crystal phase content and morphology[J].Journal of Polymer Science Part B:Polymer Physics,1989,27(5):1089-1106.
[53] 赵胜利,宣英男,黄勇.乙基氰乙基纤维素溶液的高压静电场纺丝[J].高分子材料科学与工程,2004,20(2):151-154. ZHAO S L,XUAN Y N,HUANG Y.Fiber of ethyl-cyanoethyl cellulose produced by electrospinning[J].Polymeric Materials Science and Engineering,2004,20(2):151-154.
[54] 李海花,刘振法,高玉华,等.静电场对CaCO₃结晶过程的影响及与绿色阻垢剂的协同阻垢性能[J].化工学报,2013,64(5):1736-1742. LI H H,LIU Z F,GAO Y H,et al.Influence of electrostatic water treatment on crystallization behavior of CaCO₃ and synergistic scale inhibition with a green scale inhibitor[J].Journal of Chemical Industry and Engineering,2013,64(5):1736-1742.
[55] DANNEMAND M,KONG W,FAN J H,et al.Laboratory test of a prototype heat storage module based on stable supercooling of sodium acetate trihydrate[J].Energy Procedia,2015,70:172-181.
[56] 张纲,王静康,熊晖.沉淀结晶过程中的添加晶种技术[J].化学世界,2002,43(6):326-328. ZHANG G,WANG J K,XIONG H.Seeding technology on the precipitation crystallization process[J].Chemical World,2002,43(6):326-328.
[57] 许妍妍,刘振,徐本静,等.晶种诱导高结晶度Beta沸石的合成[C]//中国化学会第30届学术年会摘要集--第三十二分会:多孔功能材料. 大连,2016. XU Y Y,LIU Z,XU B J,et al.Synthesis of high-crystallinity Beta zeolite with seeds[C]//Proceedings of the 30th annual academic meeting of China Chemical Society-32th chapters:porous functional material.Dalian,2016.
[58] BENLI H,DURMUS A.Performance analysis of a latent heat storage system with phase change material for new designed solar collectors in greenhouse heating[J].Solar Energy,2009,83(12):2109-2119.
[59] 周国兵,王雪皎,韩玉维.一种跨季节太阳能-相变蓄能分级释能采暖系统及方法:201410025925.1[P].2014-04-09. ZHOU G B,WANG X J,HAN Y W. Seasonal solar energy-phase change energy storage type graded energy release heating system and method:CN201410025925.1[P].2014-04-09.
[60] 王雪皎.相变材料过冷跨季节蓄能地板采暖系统模拟[D].北京:华北电力大学,2015. WANG X J. Simulation of floor heating system using seasonal thermal storage by PCM with stable supercooling[D].Beijing:North China Electric Power University,2015.
[61] SHARIF M K A,AL-ABIDI A A,MAT S,et al.Review of the application of phase change material for heating and domestic hot water systems[J]. Renewable and Sustainable Energy Reviews,2015,42:557-568.
[62] AL-ABIDI A A,MAT S B,SOPIAN K,et al.Review of thermal energy storage for air conditioning systems[J].Renewable and Sustainable Energy Reviews,2012,16(8):5802-5819.
[63] ESEN M.Thermal performance of a solar-aided latent heat store used for space heating by heat pump[J].Solar Energy,2000,69(1):15-25.
[64] HELM M,HAGEL K,PFEFFERL W,et al.Solar heating and cooling system with absorption chiller and latent heat storage-A research project summary[J].Energy Procedia,2014,48:837-849.
[65] BENLI H.Energetic performance analysis of a ground-source heat pump system with latent heat storage for a greenhouse heating[J].Energy Conversion and Management,2011,52(1):581-589.
[66] ANDERSEN E,FURBO S. Theoretical comparison of solar combi systems and stratification design options[J]. Journal of Solar Energy Engineering,2007,129:439-448.
[67] LELE A F,TAMBAB J G.A review on the use of SrBr₂·6H₂O as a potential material for low temperature energy storage systems and building applications[J].Solar Energy Materials and Solar Cells,2017,164:175-187.
[68] LELE A F, KUZNIK F,OPEL O,et al.Performance analysis of a thermochemical based heat storage as an addition to cogeneration systems[J].Energy Conversion and Management,2015,106:1327-1344.
[69] N'TSOUKPOEA K E,MAZETB N,NEVEUB P.The concept of cascade thermochemical storage based on multimaterial system for household applications[J]. Energy and Buildings,2016,129:138-149.
[70] HU P,LU D J,FAN X Y,et al.Phase change performance of sodium acetate trihydrate with AlN nanoparticles and CMC[J].Solar Energy Materials and Solar Cells,2011,95(9):2645-2649.
[71] RAMIREZ B M L G,GLORIEUX C,MARTINEZ E S M,et al.Tuning of thermal properties of sodium acetate trihydrate by blending with polymer and silver nanoparticles[J].Applied Thermal Engineering,2014,62(2):838-844.
[72] RYU H W,WOO S W,SHIN B C,et al.Prevention of supercooling and stabilization of inorganic salt hydrates as latent heat storage materials[J].Solar Energy Materials and Solar Cells,1992,27(2):161-172.
[73] CABEZA L F,SVENSSON G,HIEBLER S,et al.Thermal performance of sodium acetate trihydrate thickened with different materials as phase change energy storage material[J].Applied Thermal Engineering,2003,23(13):1697-1704.
[74] 石海民,梁德青,李栋梁,等. CH₃COONa·3H₂O相变蓄热性能研究[J].制冷学报,2009,30(2):8-11. SHI H M,LIANG D Q,LI D L,et al.Study on phase change property of heat storage material-CH₃COONa·3H₂O[J].Journal of Refrigeration,2009,30(2):8-11.
[75] 丁红雨,李慧星,冯国会.基于相变材料三水乙酸钠蓄热性能实验研究[J].建筑节能,2014(10):42-45. DING H Y,LI H X,FENG G H.Experimental study on thermal storage performance of sodium acetate trihydrate based on phase change material[J]. Building Energy Conservation,2014(10):42-45.
[76] 李海丽,季旭,冷从斌,等.膨胀石墨/五水硫代硫酸钠相变储能复合材料热性能[J].复合材料学报,2016,33(12):2941-2951. LI H L,JI X,LENG C B,et al.Thermal performance of expanded graphite/Na₂S₂O₃·5H₂O phase change energy storage composite[J]. Acta Materiae Compositae Sinica,2016,33(12):2941-2951.
[77] 张雪梅,蔡路茵,苏忠杰,等. 超声波对三水乙酸钠相分离及结晶的影响[J]. 化工学报,2010,61(1):104-108. ZHANG X M,CAI L Y,SU Z J,et al.Effects of ultrasound on phase separation and crystallization of sodium acetate trihydrate[J]. CIESC Journal,2010,61(1):104-108.
[78] KIMURA H,KAI J.Mixtures of calcium chloride hexahydrate with some salt hydrates or anhydrous salts as latent heat storage materials[J].Energy Conversion and Management,1988,28(3):197-200.
[79] 王智平,田禾青,王克振,等.钾明矾基低共熔相变储热材料的制备与研究[J]. 人工晶体学报,2013,42(3):491-496. WANG Z P,TIAN H Q,WANG K Z,et al.Preparation and study on the matrix of aluminum potassium sulfate eutectic phase change heat storage materials[J].Journal of Synthetic Crystals,2013,42(3):491-496.
[80] LING Z Y,LIU J W,WANG Q H,et al.MgCl₂·6H₂O-Mg(NO₃)₂·6H₂O eutectic/SiO₂ composite phase change material with improved thermal reliability and enhanced thermal conductivity[J]. Solar Energy Materials and Solar Cells,2017,172:195-201.
[81] LIU Y S,YANG Y Z.Preparation and thermal properties of Na₂CO₃·10H₂O-Na₂HPO₄·12H₂O eutectic hydrate salt as a novel phase change material for energy storage[J].Applied Thermal Engineering,2017,112:606-609.
[82] 令闰强.太阳能跨季节储热单元及相变材料KAl(SO₄)₂·12H₂O的研究[D].兰州:兰州理工大学,2012. LING R Q.Study on seasonal solar energy storage unit and phase change material KAl(SO₄)₂·12H₂O[D].Lanzhou:Lanzhou University of Technology,2012.
[83] CABEZA L F,ROCA J,NOGUES M,et al.Immersion corrosion tests on metal-salt hydrate pairs used for latent heat storage in the 48 to 58℃ temperature range[J].Materials and Corrosion,2002,53(12):902-907.
[84] LV Y J,ZHOU W B,YANG Z J,et al.Characterization and numerical simulation on heat transfer performance of inorganic phase change thermal storage devices[J].Applied Thermal Engineering,2016,93:788-796.
[85] 盛强,邢玉明,王泽. 八水氢氧化钡相变材料的强化传热实验[J].航空动力学报,2013,28(9):1927-1932. SHENG Q,XING Y M,WANG Z.Experiment on heat transfer enhancement of barium hydroxide octahydrate phase change material[J].Journal of Aerospace Power,2013,28(9):1927-1932.
[86] EL-SEBAⅡ A A,AL-AMIR S,AL-MARZOUKI F M,et al.Fast thermal cycling of acetanilide and magnesium chloride hexahydrate for indoor solar cooking[J].Energy Conversion and Management,2009,50(12):3104-3111.
[87] 苑坤杰,张正国,方晓明,等. 水合无机盐及其复合相变储热材料的研究进展[J]. 化工进展,2016,35(6):1820-1826. YUAN K J,ZHANG Z G,FANG X M,et al.Research progress of inorganic hydrated salts and their phase change heat storage composites[J]. Chemical Industry and Engineering Progress,2016,35(6):1820-1826.
[88] 于永生,井强山,孙雅倩. 低温相变储能材料研究进展[J]. 化工进展,2010,29(5):896-900. YU Y S,JING Q S,SUN Y Q.Progress in studies of low temperature phase-change energy storage materials[J].Chemical Industry and Engineering Progress,2010,29(5):896-900.
[89] DUAN Z J,ZHANG H Z,SUN L X.CaCl₂·6H₂O/Expanded graphite composite as form-stable phase change materials for thermal energy storage[J]. Journal of Thermal Analysis and Calorimetry,2014,115(1):111-117.
[90] 陈娇,张焕芝,孙立贤,等.CaCl₂·6H₂O/多孔Al₂O₃复合相变材料的制备与热性能[J].应用化工,2014,43(4):590-593. CHEN J,ZHANG H Z,SUN L X,et al.Preparation and thermal properties of calcium chloride hexahydrate/multiporous alumina composites as phase change materials[J].Applied Chemical Industry,2014,43(4):590-593.
[91] 刘太奇,操彬彬,张成,等.物理法制备微胶囊无机芯相变材料及其表征[J].新技术新工艺,2010(3):81-84. LIU T Q,CAO B B,ZHANG C,et al.Preparation and characterization of phase change materials in microencapsulated inorganic-core by physical method[J].New Technology and New Process,2010(3):81-84.
[92] HASSABO A G,MOHAMED A L,WANG H L,et al.Metal salts rented in silica microcapsules as inorganic phase change materials for textile usage[J]. Indian Journal of Chemistry A,2015,10(2):59-65.