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Table of Content
05 May 2011, Volume 30 Issue 5
    特约评述
    Development of catalytic cracking to produce low carbon olefins and its commercialization
    WANG Jianming
    2011, 30(5):  911. 
    Abstract ( 2832 )  
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    In recent years,with increasing demand for propylene for polypropylene production worldwide,the ratio of propylene to ethylene on the production side,has not kept pace with the ratio on the demand side. Moreover,the gap between supply and demand of propylene is expanding. To meet increasing demand,significant development of catalytic to produce low carbon olefin,is required. In this paper,commercialization of steam cracking technology to produce low carbon olefins is introduced. Demonstration test of advanced catalytic olefins(ACO)technology from Kellog Brown & Root LLC(KBR)and other 6 commercialized catalytic cracking of VGO/reduced crude are analyzed. It is suggested that based on the current situation in China,we should persist in policies of heavy to light conversion,diversification,integration of refining and petrochemical to increase low carbon olefin production. Large refining and petrochemical companies dealing with paraffin base crude and intermediate base crude are recommended to build several large scale catalytic cracking units to produce more low carbon olefins especially propylene.

    化工过程与装备
    Application of passive acoustic emission measurement in chemical processes
    REN Congjing,CHEN Min,CAO Yijia,HUANG Zhengliang,WANG Jingdai,YANG Yongrong
    2011, 30(5):  918. 
    Abstract ( 2301 )  
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    The applications of acoustic emission(AE)technology in monitoring the state of equipment and the physico-chemical changes in chemical processes are reviewed in this paper,with a brief introduction of the principles of AE,hardware and analysis methods,Furthermore,detail cases in different unit operations and equipment monitoring are presented. AE technology has a broader prospect for industrial application than other detection methods.

    Advances in research on non-thermal plasma reactors of waste gas treatment
    SUN Wanqi1,SONG Hua2,HAN Suling2,BAI Shupei2,MA Tingjun2,SUN Chunbao1
    2011, 30(5):  930. 
    Abstract ( 2511 )  
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    The application of non-thermal plasma technology in waste gas treatment has been paid more attention to and the development of plasma reactors is the key issue. The structural characteristics of corona reactors,dielectric-barrier discharge(DBD)reactors and plasma-catalytic reactors,as well as their discharge characteristics,are introduced. The differences of all kinds of plasma reactors in terms of energy efficiency,by-product selectivity and industrial application are analyzed. Finally,the direction for future research is presented.

    Research on tubular furnace energy efficiency
    CHEN Ying1,ZHANG Jingwei1,LIANG Hongbao2,YANG He1,ZHI Chunsheng3
    2011, 30(5):  936. 
    Abstract ( 2572 )  
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    With the structure of tubular furnace energy saving as a starting point,the research on energy saving of tubular furnace burner,radiation chamber,convection chamber and heat recovery is reviewed including the restructuring of burner and radiation chamber,optimization of soot-blowing development of new decoking  technology, new air preheater,and new radiant tubes. Enhancement of radiation heat transfer and heat recovery can effectivelylower exhaust gas temperature,and improve heating efficiency,contributing to higher furnace energy efficiency. Finally,future research on energy-saving of tubular furnace study is proposed.

    Research progress of dimerization of acetylene to monovinylacetylene
    LIU Jianguo,HAN Minghan,ZUO Yizan,WANG Zhanwen
    2011, 30(5):  942. 
    Abstract ( 2591 )  
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    The research on monovinylacetylene production from dimerization of acetylene is reviewed,including the catalyst,production technology and reaction mechanism. Besides,development of the process,improvement scheme of the production techniques and development of downstream products of monovinylacetylene on the background of current energy and technique are also proposed.

    Advance in kinetics model of diesel hydrodearomatization reaction
    BAO Hongzhou1,2,FANG Xiangchen2,LIU Jihua2,SONG Yongyi2
    2011, 30(5):  948. 
    Abstract ( 2256 )  
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    Due to the lower diesel quality,and harm to health of aromatics,it is necessary to reduce the content of aromatics in diesel. Hydrogenation is an effective way to reduce the content of aromatics in diesel. Thermodynamics and kinetics of hydrodraromatization are introduced. Simple lumping model and complex lumping model of diesel hydrodearomatization reaction are described. Simple lumping model is concise and practical,but its accuracy is not satisfactory. Complex lumping model is accurate,but it is complicated and expensive for general application,which limits its application. For kinetics model,aiming at higher accuracy is necessary,and lowering the cost of development and use are significant in its application.

    Experimental research on vapor-liquid equilibrium of gasoline modeling thiophene/isooctane
    ZHANG Jiaojing1,SONG Hua1,LI Xueyuan2
    2011, 30(5):  953. 
    Abstract ( 2096 )  
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    Using thiophene/isooctane to model gasoline,the effects of extractant and solvent/oil ratio on vapor-liquid equilibrium were researched on a self-made small vapor-liquid equilibrium apparatus and the relative volatility of thiophene/isooctane system was determined. Two chemical process flow simulation softwares of PRO/II and Aspen were used in simulation of the system. Good agreement between the measured results by this work and those of computer simulation was obtained. The relative volatility of thiophene/isooctane is 1.466 by using N,N-dimethylformamide as extractant at solvent/oil ratio of 4∶1.

    Extraction of polyols from bio-based polyols residue
    BAO Nina,WU Hongfa,WANG Jingyi,XUE Donghua
    2011, 30(5):  957. 
    Abstract ( 2178 )  
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    By using the method of complexation extraction and molecular distillation,the polyols in bio-based polyols distillation residues were extracted and separated. The ratio between complexing and extracting agent,and the impact of temperature and time on the outcome of extraction were investigated. The results showed that complexation extraction and molecular distillation could effectively separate polyols.

    Operation characteristics of returning ash heat exchanger for small CFB boilers
    JI Hui,LU Xiaofeng,LI Wenjie,KANG Yinhu
    2011, 30(5):  962. 
    Abstract ( 2653 )  
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    In the circulating fluidized bed(CFB)cold model test system,a study on the relationship between operating conditions and gas-solids flow characteristics were carried out in a new returning ash heat exchanger. By changing the air flowrates of air-equalizing chamber and back-feed chamber,supplying air in radial direction in standpipe,the gas-solid flow characteristics of back-feed system under different operating conditions were analyzed. Cold test study results showed the relationship between different operating conditions and gas-solids flow characteristics in the returning ash heat exchanger,obtained from the air flowrates of each air chamber and the parameters of radial air supply for standpipe.

    能源加工与技术
    Research progress in H2 production from steam reforming of bioglycerol:A review
    DOU Binlin1,CHEN Haisheng 2
    2011, 30(5):  967. 
    Abstract ( 2631 )  
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    With ever-increasing production of biodiesel through the building of new bio-refineries worldwide,the crude glycerol by-product from biodiesel production becomes a surplus. In this paper,the recent advance in catalytic steam reforming of bioglycerol is reviewed. The composition and pyrolysis of bioglycerol are introduced. H2 production by steam reforming of bioglycerol and sorption-enhanced steam reforming process(SERP)with in-situ CO2 removal are introduced. The review shows the feasibility of high purity hydrogen production at a low temperature by the SERP technology,and further work is needed to optimize the system. The key technologies and potential challenges for steam reforming of bioglycerol are discussed,and the developing prospect is forecasted.

    Storage stability of bio-oil
    ZHANG Wei1,2,ZHAO Zengli1,ZHENG Anqing1,CHANG Sheng1,LI Haibin1
    2011, 30(5):  973. 
    Abstract ( 2457 )  
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    Good storage stability of bio-oils is the key to entering the market as an alternative energy. The basic characteristics of bio-oil,current research of storage stability,measurement methods and evaluation parameters of bio-oil storage stability are reviewed. Upgrading methods of bio-oil are discussed. Advantages and disadvantages of different methods,as well as the present status of upgrading technologies are analyzed.Making in-depth studies on the mechanism of pyrolysis,and development standards for bio-oil storage stability and application will help to accelerate the commercial utilization of bio-oils.

    Progress of Bunsen reaction study in iodine-sulfur thermochemical cycle
    XUE Lulu,ZHANG Ping,CHEN Songzhe,WANG Laijun
    2011, 30(5):  983. 
    Abstract ( 2601 )  
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    The iodine-sulfur(IS)thermochemical cycle is an extensively studied and prospective approach to nuclear hydrogen production. Among the three reactions of IS process,the Bunsen reaction,which connects the sulfuric acid and HI acid decomposition reactions,plays a key role in the closing of the cycle. Many researchers studied the Bunsen reaction,including operating conditions,products separation characteristics,side reactions and purification method,and new approaches were proposed. In this paper,the progress of the Bunsen reaction study is reviewed. The Bunsen reaction conditions and separation characteristics presented by various institutions are compared,the purification methods and results are summarized,and the optimal operating windows are recommended. In addition,the new approaches differing from conventional ones are introduced. These results may offer theoretical guide and basis for the smooth implementation of the Bunsen reaction,to achieve continuous and stable operation of the whole process.

    Advance in improvement of cycle life of lithium-sulfur batteries
    XIONG Shizhao1,HONG Xiaobin1,XIE Kai1,RONG Lixia2
    2011, 30(5):  991. 
    Abstract ( 2785 )  
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    The factors limiting the cycle life of lithium-sulfur batteries and effect of cathode,anode and electrolyte on the cycle life are reviewed. The factors limiting the cycle life are introduced as follows:formation of irreversible Li2S,failure of porous structure of the cathode and parasitic reaction between species of electrolyte and lithium anode. The approaches to improving cycle life of lithium sulfur batteries are introduced as follows:appropriate binder,carbon materials and preparation method of cathode,protective technology of lithium anode,appropriate species of electrolyte,structure and design of battery. Future development of the research is also prospected.

    工业催化
    Research progress of catalyst in catalytic hydrogenolysis of glycerol to propanediols
    CHEN Zhong1,LI Jianxiu2
    2011, 30(5):  997. 
    Abstract ( 2161 )  
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    The recent progress of catalysts used in hydrogenolysis of glycerol to propanediols is reviewed. Catalyst is the key factor in the hydrogenolysis of glycerol to propanediols,such as Cu,Ru,Rh,Pt,Ni,Co-based catalysts. The catalyst properties,product separation and environment pollution are influenced by the catalyst type,composition,vector,preparation and process condition. There is still a lack of fundamental understanding of high activity and selectivity catalyst in hydrogenolysis of glycerol to 1,3-propanediol,Optimization of preparation technologies of catalysts used in hydrogenolysis of glycerol to 1,2-propanediol will be needed in order to achieve commercialization.

    Structures and properties of diphosphinoamine ligands in ethylene tetramerization catalyst system
    NING Yingnan,XUE Qiumei,MAO Guoliang,JIANG Tao
    2011, 30(5):  1003. 
    Abstract ( 1664 )  
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    Recently progress of the catalytic system for ethylene tetramerization toward 1-octene is summarized. The structure and electronic property of PNP ligand are the mainly factors affecting the catalytic activity and the selectivity of the catalytic system. The bulk and electronic properties of N-substituented and P-substituented groups in PNP ligand have important effect on catalytic activity and selectivity to 1-octene. The substituent with bulkier and richer electronegativity will result in hindering further ethylene insertion,which induces lower catalytic activity and lower selectivity to 1-octene. The design and synthesis of a novel ligand is crucial to higher catalytic activity and higher selectivity to 1-octene.

    Effect of organic ligands on hydrotreating catalysts
    YANG Yi1,2,ZHOU Yong2,YANG Chengmin2,ZHOU Yukun1,2
    2011, 30(5):  1008. 
    Abstract ( 1771 )  
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    The effect of organic ligands on hydrotreating catalysts and catalysis are reviewed. The organic ligands enhance the activity of hydrotreating catalysts. The mechanisms of organic ligands are discussed from two points of the preparation of catalyst and the sulfidation step. Organic ligands will interact more strongly with the metal species and the support. They prevent the strong metal-support interactions,and impact the dispersion and sulfidation of the metal species. Therefore,the more active type CoMoS phases can be formed.

    Research on catalysts loaded with Cu for amination of ethanol to acetonitrile
    CAO Jinpeng1,HU Yunfeng 1,XU Peng2,CUI Baoyu 3,DONG Qun 1
    2011, 30(5):  1013. 
    Abstract ( 2387 )  
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    The catalytic performance of SAPO-11,montmorillonite-K10,γ-Al2O3,ZnO and MgO loaded with Cu were studied for amination of ethanol to acetonitrile. The results showed that reduced copper metal had the function of dehydrogenation,and carriers not only played a role in the dispersion of copper metal but also had a synergistic effect. The acid-base property of carriers was closely related to catalytic results. Among these catalysts,the ideal catalytic results were obtained over the Cu/γ-Al2O3 catalyst. The influence of reaction conditions was investigated,and the favorable conditions of amination of ethanol to acetonitrile over Cu/γ-Al2O3 were as follows:reaction temperature of 290 ℃,reaction pressure of 0.1 MPa,ethanol WHSV of 1.0 h-1 and ammonia/ethanol molar ratio of 7.0. The conversion of ethanol and the selectivity to acetonitrile were 99.7% and 92.6% respectively under the reaction conditions.

    Ortho-selective alkylation of phenol with diethyl carbonate over Cr2O3/SiO2 catalyst
    JIA Quan,XUE Bing,XU Jie,LI Yongxin
    2011, 30(5):  1019. 
    Abstract ( 3221 )  
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    Cr2O3/SiO2 catalysts with different Cr2O3 loadings were prepared by impregnation with Cr(NO3)3?9H2O as precursor.Ortho-selective alkylation of phenol with diethyl carbonate was performed in a continuous flow fixed-bed reactor filled with Cr2O3/SiO2 catalysts.The Cr2O3/SiO2 catalysts were characterized by means of XRD,NH3-TPD,CO2-TPD and FT-IR with pyridine adsorption.The results indicated that with increasing Cr2O3 loading,conversion of phenol and selectivity to o-ethylphenol increased;when Cr2O3 loading reached 7.5%,conversion of phenol and selectivity for o-ethylphenol reached a maximum of 48% and 67%,respectively.The catalyst characterization results showed that the Lewis acid sites were the active centers of ortho-selective alkylation of phenol;and the variations in phenol conversion and selectivity to o-ethylphenol could be mainly ascribed to the change in the number of acid sites and base sites.

    材料科学与技术
    Research progress of cathode materials for rechargeable magnesium batteries
    ZHENG Yupei,NULI Yanna,YANG Jun,CHEN Qiang,WANG Jiulin
    2011, 30(5):  1024. 
    Abstract ( 2129 )  
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    Rechargeable magnesium batteries may be a potential candidate for heavy load application due to high energy density,low cost,safety of handling and environmentally friendly nature of metallic magnesium. In this paper,the recent research progress of cathode materials is reviewed,especially MgxMo3S4,V2O5 aerogels,V2O5 gel/carbon composites,graphene-like MoS2,polyanion-type materials with good cyclability,high specific capacity or high discharge plateau. Furthermore,the current problems and the corresponding research directions are proposed.

    Advance in surface molecularly imprinted carriers
    XU Feifei1,DUAN Yuqing1,ZHANG Haihui1,QIN Yu1,MA Haile1,YAN Yongsheng2
    2011, 30(5):  1033. 
    Abstract ( 2769 )  
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    The advance in surface molecularly imprinted polymer carriers is reviewed. In this paper,the surface molecularly imprinting technique with inorganic material and chitosan as the carriers is introduced respectively according to different types of carriers and surface modification methods,and the development prospect of the carriers is also presented. The surface modification of inorganic materials is mainly achieved by introduction of the functional groups(such as the amino group,the benzyl group,etc)of the alkylating agents. Then,the polymers are prepared by the surface molecularly imprinted technique. However,the modification of chitosan is completed by a variety of cross-linking methods in order to obtain a single matrix or a hybrid material as the carrier. Compared with traditional methods,the novel material has an excellent performance of good adsorption ability,high recycling rate and uniform particles. Nevertheless,further research is needed to study the micro behavior patterns during the preparation of polymers as well as the bonding rules between the functional monomer and the target molecule.

    Research progress of modification of lignosulfonate water-reducer
    WANG Wanlin1,WANG Haibin2,HUO Jichuan1,LEI Yonglin1,Lü Shuzhen1
    2011, 30(5):  1039. 
    Abstract ( 2707 )  
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    The recent development in modification methods and performance studies of lignosulfonate,a type of water-reducers,is reviewed. Physical modification methods include separation,purification and molecular weight classification of lignosulfonate. Chemical modification methods include oxidation,sulfonation,phenolation,hydroxymethylation,Mannich reaction and graft copolymerization. The main aspects of performance studies of lignosulfonate are its influences on setting time,strength,hydration process of cement and adsorption behavior on cement particles. Further studies and optimization of modification methods to lower cost on the basis of performance enhancement,along with basic studies of application of modified products through modern analysis methods are research directions for this green water-reducer.

    Preparation and characterization of polybutylene terephthalate/polymethyl methacrylate ammonium salts modified montmorillonite nanocomposites
    HUANG Xiaoling,WANG Xiaoli,ZHANG Bingbing,SU Haiquan
    2011, 30(5):  1045. 
    Abstract ( 2976 )  
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    Two polymethyl methacrylate ammonium salts(MAPS-B and MAPS-O)were used to modify montmorillonite. Such thermally stable oligomerically modified montmorillonites were further melt-compounded with polybutylene terephthalate(PBT)at a high temperature and six kinds of nanocomposites(PBT/MAPS-B-1,PBT/MAPS-B-2,PBT/MAPS-B-3,PBT/MAPS-O-1,PBT/MAPS- O-2 and PBT/MAPS-O-3)were obtained. The influence of the structure and content of oligomerically modified montmorillonite on the morphology and properties of the nanocomposites were evaluated. The results of X-ray diffraction(XRD)and transmission electrical microscopy(TEM)indicated that the PBT/MMT nanocomposites had intercalated structures. Increased clay loading was a disadvantage for clay dispersion in the polymer matrix. Thermogravimetric analysis(TGA)showed that thermal stabilities of the PBT/MAPS-B and PBT/MAPS-O nanocomposites were improved remarkably. The onset temperature of thermal degradation(Tonset)of PBT/MAPS-O-2 was 20 ℃ higher than that of the pristine material. The thermal stability of the composites was influenced by the dispersity of clay. The poor dispersity with clay loading higher than 2% resulted in decreased Tonset of PBT/MMT. The effects of modified clays on the crystallization behavior of PBT were characterized by differential scanning calorimeter(DSC). The results showed that the nanocomposites of polyester/MMT had higher crystallization rate and a little lower melting temperature than the pristine polyester. The crystallization rate increased with increasing MMT content.

    Thermal properties of diallyl biphenol A modified bismaleimide-triazine
    ZENG Xiaoliang1,YU Shuhui1,SUN Rong1,DU Ruxu2
    2011, 30(5):  1050. 
    Abstract ( 2886 )  
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    2,2-diallyl biphenol A was used to modify the bismaleimide-triazine(BT resin)which composed of bisphenol A dicyanate ester(BCE),4,4′-bismaleimidodipphenylmethane(BMI). The effects of 2,2-diallyl biphenol A on curing reaction,solubility and thermal property of BT resin were investigated. The results showed that 2,2-diallyl biphenol A could reduce the temperature of curing reaction and improve the solubility of BT resin. When the amount of the 2,2-diallyl biphenol A amount was 20%,The temperature of curing reaction was lowered to 233.1 ℃. Furthermore,glass transition temperature(Tg)and the temperature at which 5% of the mass volatilized of the modified BT were 239.4 ℃ and 372.9 ℃,respectively,showing that excellent thermal properties of the modified BT.

    Synthesis,characterization and thermal stability of resorcinol bis[di(pentaerythritol phosphate)] phosphate
    SU Haixiao1,3,HOU Xufeng2,ZHONG Liu 1,LIU Zhiguo1,3
    2011, 30(5):  1054. 
    Abstract ( 4364 )  
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    A novel phosphorus-containing flame retardant,resorcinol bis[di(2,6,7-trioxa-1- phosphabicyclo [2.2.2]-octane-1-oxo-4-hydroxymethyl)] phosphate(RBPP)was synthesized from pentaerythritol,phosphorus oxychloride and resorcinol. The title compound was characterized by elemental analysis,FTIR,and 1H NMR. The results showed that the structure of the title compound was consistent with expectation. Thermogravimetry(Tg)investigation on thermal stability of RBPP showed that mass loss of 5% was at about 350 ℃ and residue at 600 ℃ was as high as 57.4%. The limiting oxygen index(LOI)value coulds reach 31.8% and flame retardancy was UL-94 V-0 when mass fraction in E-51 epoxy resin was 15.2%.

    Fabrication of polycaprolactone nanofibrous scaffolds by thermally induced phase separation
    LIU Shuqiong,XIAO Xiufeng,LIU Rongfang,ZHONG Zhangyu,JIAO Jianjin
    2011, 30(5):  1059. 
    Abstract ( 2603 )  
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    Polycaprolactone(PCL)three-dimensional(3D)scaffold with spherulite and nanofibrous was first fabricated by thermally induced phase separation from a ternary PCL/dioxane/water system. The effects of aging temperature,ratio of dioxane and water on the morphology of nanofibrous scaffolds were investigated. The results showed that aging temperature played a crucial role in forming the unique nanofibrous structure. A higher gelation temperature or a higher content of water in the mixed solvent system was not favorable for the spherulite -like  morphology of scaffold. Coalescence of nanofibers occurred,even spherulite -like structure disappeared at a gelation temperatures higher than 8℃ or lower than -40℃ and at a proportion of water exceeding 12%.

    Effects of Sr doping on high temperature electric properties of CaMnO3+δ - based compounds
    JIA Kun,WEI Changping,XU Jie,Lü Zhijun,YU Minna
    2011, 30(5):  1065. 
    Abstract ( 2784 )  
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    Ca1-xSrxMnO3(x=0,0.05,0.1)ceramic samples were prepared by using the sol-gel method and sintering in air with nitrales as starting materials. The phase composition,microstructure and electric properties of Sr doped samples were investigated. The results showed that the Ca1-xSrxMnO3 ceramic samples was single phase and had condensed microstructure. Sr doped samples had better electric properties. The substitution of Sr for Ca had no significant effect on Seabeek coefficient but decreased its electrical resistivity,the highest power factor was 24.03×10-5 W/(m·K2)at 600℃ for the sample of Ca0.9Sr0.1MnO3.

    生物化工
    Fermentation of bio-based product 2,3-butanediol
    SONG Yuanquan,XU Yunzhen,LI Qiang,LIU Dehua
    2011, 30(5):  1069. 
    Abstract ( 2712 )  
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    The development of chemical industry is hindered by energy crisis and environment pollution,and a new model of development is urgently to be exploited. Biorefining technology with renewable resources as feedstock is proposed as one possible solution,in which 2,3-butanediol fermentation is one important issue. 2,3-Butanediol,a bulk chemical product,has extensive applications,especially in chemical processes,food,fuel and medicine. The metabolic pathway of 2,3-butanediol is briefly described,and the progress of biotechnological production of 2,3-butanediol is reviewed,including microbial strains,strains mutagenization,genetic modifications and operating conditions (substrates,pH value,aeration,temperature and fermentation mode). Finally,2,3-butanediol fermentation research directions are proposed.

    精细化工
    Modified spinel-cobalt blue pigments and research progress
    CHENG Aiju,ZHAO Yanzhao,GUO Wenji
    2011, 30(5):  1078. 
    Abstract ( 1874 )  
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    The structure and preparation methods of spinel cobalt blue pigments,including solide phase,liquid phase and gaseous phase processes were introduced. The effects of different iron-doping methods on the structure and properties of modified cobalt blue pigments were investigated with XRD,SEM techniques. Bivalent cation-doping influenced the lattice constant of the pigments in agreement with the law of Vegard. Tribalent cation-doping had an obvious influence on the tone of the pigments. Finally the development of cobalt blue pigments in terms of preparation methods and iron-doping was forecasted.

    Application of rosin–based polyamide in isotopic conductive adhesive
    LIN Guifu,NIE Xiaoan,MI Zhen
    2011, 30(5):  1082. 
    Abstract ( 2663 )  
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    Rosin-based polyamide used as curing agent for conductive adhesive,was prepared from maleopimaric acid anhydride by amidation with diethylenetriamine,with epoxy resin 618 as matrix,silver-coated copper powder as conductive filler,KH560 and PEG(200)as accelerant,and silver-coated copper powder conductive adhesive was prepared. The influences of various factors on the shear strength,conductivity of the conductive adhesive were discussed,and its glass transition and heat-resistance were evaluated. The result showed that the resin epoxy/rosin-based polyamide system was cured completely when the mass ratio of resin epoxy:rosin-based polyamide was 100∶50.8 at  120 ℃ for 60 min,and the addition of silver-coated copper powder was 60% to resin epoxy,KH560 and PEG(200)were 3% and 5% to silver-coated copper powder respectively.Under such conditions the comprehensive performance of the conductive adhesive was optimal. Thermal decomposition temperature was 342.1 ℃,and glass transition was 144.7 ℃.

    Catalytic synthesis process of 2-hydroxy-4,6-dimethoxydeoxybenzoin
    WU Chunxin1,WU Qiuping1,LI Yangyang1,ZHAO Deming1,CHEN Yingqi2
    2011, 30(5):  1089. 
    Abstract ( 2176 )  
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    2-Hydroxy-4,6-dimethoxydeoxybenzoin was synthesized from 1,3,5- trimethoxybenzene,via the Houben-Hoesch reaction or Friedel-Crafts reaction and demethylation of 2,4,6- trimethoxydeoxybenzoin. Because of the protection of methyl group,the reactivity of hydroxy groups was reduced and the yields of Houben-Hoesch and Friedel-Crafts reaction reached to 81.3% and 94.5% respectively. The yield of demethylation was 93.8%. The effects of catalyst amount and reaction temperature were investigated,and the optimal process parameters were as follows:(1)in Friedel-Crafts reaction,the ratio of catalyst(aluminum chloride)and 1,3,5-trimethoxybenzene 1.1∶1,reaction temperature 25 ℃,(2)in demethylation,the ratio of demethylation reagent and 2,4,6- trimethoxydeoxybenzoin 1.2∶1,reaction temperature 82 ℃. The product was characterized with 1H NMR and MS.

    Cationic reaction of hydroxyethyl cellulose in mixed media
    LI Wei1,2,CHEN Yufang1,MA Yanfang3,CHEN Wenning1,HOU Chengmin1,2
    2011, 30(5):  1093. 
    Abstract ( 2395 )  
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    In the mixed solvents of ethanol and isopropanol,3-chloro-2-hydroxypropyl trimethyl ammonium chloride(CTA)was used as etherifying agent to achieve the cationic reaction of hydroxyethyl cellulose(HEC). The factors affecting the degree of substitution(Cds)and reaction efficiency(Cre)were investigated,and the structure of the product was identified by 1H NMR. Cds of the product was 0.50 and the Cre reached 75%,with mass ratio m(HEC)∶m(Et.)∶m(iPA)∶ m(25%NaOH)∶m(69%CTA)∶m(Ea)= 20∶20∶70∶13∶15∶8,at 25 ℃ for 30 min activation with amine,and reaction at 60 ℃ for 4 h.

    资源与环境工程
    Application progress of flue gas dry purification technology by activated coke(carbon)
    GAO Jixian,LIU Jing,ZHAI Shangpeng,FU Yuemei,TANG Xishan,ZENG Yan
    2011, 30(5):  1097. 
    Abstract ( 2423 )  
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    To control air pollution,develop cycling economy and promote the technology with the characteristics of resource reutilization,water-saving and wide spectrum purification,the progress of industrial application of flue gas dry purification by dry activated coke(carbon)methods is reviewed. Through a comprehensive analysis of the new development of industrial applications,such a technology can promote the development of domestic flue gas purification industry,development of cycling economy and building a sustainable ecologically civilized society.

    Research and applications of magnetic immobilization technology in environmental engineering
    ZHOU Jin,ZHOU Zuoming,JING Guohua
    2011, 30(5):  1106. 
    Abstract ( 2269 )  
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    The magnetic immobilized technology with unique magnetism advantages has wide application prospect in environmental engineering. In this paper,the research progress of the magnetic immobilized carriers and the magnetic immobilized technology used in environmental monitoring,waste water and gas treatment in recent years is reviewed and its development orientations,such as preparation of magnetic carriers,exploring new immobilized methods and developing industrial applications in the future are presented.

    Research progress of non-hydrogenation desulfurization technology for liquid hydrocarbons
    ZHANG Junhua1,WANG Zhijie2,WANG Dongfei2,CAO Qing1
    2011, 30(5):  1112. 
    Abstract ( 2296 )  
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    Compared with the catalytic hydrogenation desulfurization technology,non-hydrogenation desulfurization technology can be used under atmospheric pressure and at a low temperature with the advantages of small investment,safe operation and lower cost. The principles and techniques of non-hydrogenation desulfurization technology,including acid-base purification,adsorption,catalysis,extraction,oxidation,microbiological method,radiation and other ionic liquid method were compared,and their respective advantages and disadvantages were discussed to provide guidance for the development of desulfurization technology. The prospect of desulfurization process is a combination  of the above desulfurization processes.

    Progress of corrosion and fouling prevention in utilization of
    LIU Mingyan1,ZHU Jialing2
    2011, 30(5):  1120. 
    Abstract ( 2530 )  
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    Equipment corrosion and fouling problems are analyzed in the utilization of geothermal energy and new technologies to inhibit geothermal corrosion and fouling are reviewed. Anti-corrosion methods include coating an anti-corrosion layer,selecting anti-corrosion materials for the equipment and pipes,increasing the corrosion allowance in the design of pipelines and other structures,injecting nitrogen or sealing off oxygen,adding sulfur(corrosion inhibitors)into the system etc. Fouling prevention techniques include adding chemical inhibitors,cleaning scale by installing fouling trapping tank or groove before geothermal utilization,imposing electric,magnetic,sound or other physical fields,coating an antiscaling layer,etc. The research directions of the corrosion and fouling prevention technologies are proposed.

    Study on activated carbon made from sewage sludge
    LIANG Xin,MENG Liyan,CHEN Xiaoshan,SHI Jiaming,MENG Mianwu,HUANG Ying
    2011, 30(5):  1124. 
    Abstract ( 2892 )  
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    Activated carbon was made from sewage sludge with H3PO4  as a sludge activation agent during the pyrolytic process. The carbonization temperature,carbonization time,acid concentration,activation temperature,activation time were optimized. The effects of such factors on the sludge activated carbon were investigated. The optimal conditions were carbonization temperature 623K,carbonization time 50min,concentration of washing acid 25%,activation temperature 653K,activation time 50min. Under such conditions,the yield of the activated carbon was 48%,and the iodine adsorption value was 585.1mg/g. The activated carbon was used to purify dyeing waste water,and the adsorption efficiency could reach 99.97% with 0.5g activated carbon per 100 mL waste water.

    Effect of dissolved oxygen on DMBR treatment efficiency and characteristics of membrane fouling
    HONG Junming,YIN Juan
    2011, 30(5):  1130. 
    Abstract ( 2555 )  
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    Polyester filter cloth with mean pore size of 37 μm was used as the separation medium to develop a submerged dynamic membrane bioreactor(DMBR)for treating model household wastewater. The treatment efficiency and extracellular polymeric substances(EPS)were investigated at different dissolved oxygen(DO)concentrations,the characteristics of membrane fouling were dicussed. The results showed that when the concentration of DO was more than 0.5 mg/L,the concentration of effluent COD was stable at 16.67 mg/L. The concentration of DO had a significant effect on the effluent of ammonia nitrogen,nitrate and total nitrogen. When the concentration of DO was 3.0~3.5 mg/L,the effluent concentration of ammonia nitrogen was the lowest,and the removal of total nitrogen was the maximum. When the concentration of DO was more than 2.0 mg/L,the concentration of EPS was almost unchanged. Under such circumstances,the concentration of EPS was 20 mg/g MLSS,and the polysaccharide concentration was more than the protein concentration in the DMBR. The resistance values of cloth and dynamic membrane was 2×106 m-1 and 4.32×107 m-1,respectively. The latter was the main resistance in the DMBR. At a constant influent flow of 3.0 L/h,the flux of the dynamic membrane could reach 25 L/(m2·h),with its backwashing period of about 33d and 100% recovery of the membrane flux.

    应用技术
    Feasibility of oxidation of inert ingredients in coking wastewater tailrace by H2O2/UV fluidized bed
    XIA Fang,WEI Chaohai,WU Chaofei,HU Yun,LUO Hanjin
    2011, 30(5):  1135. 
    Abstract ( 2365 )  
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    The tailrace of coking wastewater still have a variety of inert ingredients,which is an environmental risk and further limits its discharge or reuse safety,so it is necessary to study the feasibility of an advanced in-depth treatment technology. The actual wastewater was treated with a designed H2O2/UV fluidized bed reactor,and  COD removal and UV254 conversion were investigated under different dosages of H2O2,pH,aeration and light conditions,with TOC as an indicator to evaluate the degree of mineralization,and the oxidation of inert ingredients was analyzed by UV scanning,HPLC,GC/MS,IC. The results showed that under the conditions that the initial molar ratio of H2O2 to the COD was about 0.22,with slightly acidic and proper aeration,and high light reflection effective conversion of pollutants could be achieved,COD and TOC concentration could be decreased to about 20 mg/L and 10 mg/L respectively. During the process,the long-chain hydrocarbons,nitrogen-containing heterocyclic compounds,benzene and polycyclic aromatic hydrocarbons and other components were effectively transformed and mineralized,some were transformed into small molecule intermediate products,such as acetic acid and others,the toxicity of wastewater was greatly reduced and the effluent could serve as a source of reuse water.

    Characteristics of cyanide degradation in A/O/H/O coking wastewater treatment
    HUANG Huijing1,WEI ChaoHai1,WU Chaofei1,FENG Chunhua1,WU Haizhen2,LU Bin3
    2011, 30(5):  1141. 
    Abstract ( 2989 )  
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    Few studies have been devoted to the real-time analysis of the variation in cyanide concentration in a coking wastewater treatment plant,although this is important for the design of such a plant. This work presented a method to allow high-efficiency removal of cyanide,based on the analysis of the data collected from a real A/O1/H/O2 coking wastewater treatment plant(Shaogang,Guangdong). The results showed that the biodegradation rate of cyanide was much slower than that of phenols present in the biological system,and the degradation rate of metal-complexed cyanide was much slower than that associated with uncomplexed cyanide. The effective removal of carbon and nitrogen in the A/O1/H/O2 biological system was responsible for achieving high-efficiency biodegradation of cyanide. In addition,this work demonstrated that the high-efficiency treatment of coking wastewater could be realized by taking into account the synergetic effect of biodegradation kinetics for different components and the optimization of operating conditions.

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