Chemical Industry and Engineering Progress ›› 2021, Vol. 40 ›› Issue (4): 2048-2059.DOI: 10.16085/j.issn.1000-6613.2020-1411
• Special column:Industrial catalysis • Previous Articles Next Articles
SHI Yanqiang(), XIA Yuetong, WEN Langyou, GAO Liang, XU Guangtong, ZONG Baoning()
Received:
2020-07-22
Online:
2021-04-14
Published:
2021-04-05
Contact:
ZONG Baoning
史延强(), 夏玥穜, 温朗友, 郜亮, 徐广通, 宗保宁()
通讯作者:
宗保宁
作者简介:
史延强(1988—),男,博士研究生,研究方向为催化材料与有机化学品合成。E-mail:基金资助:
CLC Number:
SHI Yanqiang, XIA Yuetong, WEN Langyou, GAO Liang, XU Guangtong, ZONG Baoning. Hydrogen peroxide and its green synthesis of basic organic chemicals[J]. Chemical Industry and Engineering Progress, 2021, 40(4): 2048-2059.
史延强, 夏玥穜, 温朗友, 郜亮, 徐广通, 宗保宁. 过氧化氢及其基本有机化学品绿色合成技术[J]. 化工进展, 2021, 40(4): 2048-2059.
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聚合物 | 能耗 /MJ·(kg产品)-1 | 碳排放 /MJ·(kg产品)-1 |
---|---|---|
尼龙-6 | 129.1 | 6.7 |
尼龙-66 | 139.5 | 6.4 |
聚碳酸酯(PC) | 104.3 | 3.4 |
高抗冲聚苯乙烯(HIPS) | 86.4 | 2.4 |
通用聚苯乙烯(GPPS) | 82.3 | 2.3 |
涤纶树脂(PET) | 69.6 | 2.2 |
低密度聚乙烯(LDPE) | 81.5 | 1.9 |
高密度聚乙烯(HDPE) | 79.4 | 1.8 |
线型低密度聚乙烯(LLDPE) | 78.3 | 1.8 |
聚丙烯(PP) | 77.1 | 1.6 |
聚合物 | 能耗 /MJ·(kg产品)-1 | 碳排放 /MJ·(kg产品)-1 |
---|---|---|
尼龙-6 | 129.1 | 6.7 |
尼龙-66 | 139.5 | 6.4 |
聚碳酸酯(PC) | 104.3 | 3.4 |
高抗冲聚苯乙烯(HIPS) | 86.4 | 2.4 |
通用聚苯乙烯(GPPS) | 82.3 | 2.3 |
涤纶树脂(PET) | 69.6 | 2.2 |
低密度聚乙烯(LDPE) | 81.5 | 1.9 |
高密度聚乙烯(HDPE) | 79.4 | 1.8 |
线型低密度聚乙烯(LLDPE) | 78.3 | 1.8 |
聚丙烯(PP) | 77.1 | 1.6 |
项目 | 工作液组成 | 蒽醌溶解度/g·L-1 | Pd质量分数/% | 催化剂 | 氢化反应器 | 氢化效率/g·L-1 | 萃取液H2O2质量分数/% |
---|---|---|---|---|---|---|---|
国内技术 | AR+TOP+EAQ | 125~140 | 0.3 | Pd/Al2O3 | 固定床 | 7~8 | 27.5~35 |
FMC | AR+TOP+EAQ | 160~180 | 0.3 | — | 固定床 | 10~12 | 27.5~35 |
MGC | AR+TBU+AAQ | 250~300 | 1~2 | Pd/SiO2 | 浆态床 | 15~18 | 45~48 |
Solvay | AR+TBU+EAQ | 160~180 | 1~2 | Pd/Al2O3-ZrO2 | 浆态床 | 12~15 | 43~46 |
Degussa | AR+TOP+EAQ | 160~180 | 1~2 | Pd | 浆态床 | 11~15 | 40~45 |
Arkema | AR+2-MCHA+EAQ | 160~180 | 1~2 | — | 浆态床 | 11~14 | 40~45 |
项目 | 工作液组成 | 蒽醌溶解度/g·L-1 | Pd质量分数/% | 催化剂 | 氢化反应器 | 氢化效率/g·L-1 | 萃取液H2O2质量分数/% |
---|---|---|---|---|---|---|---|
国内技术 | AR+TOP+EAQ | 125~140 | 0.3 | Pd/Al2O3 | 固定床 | 7~8 | 27.5~35 |
FMC | AR+TOP+EAQ | 160~180 | 0.3 | — | 固定床 | 10~12 | 27.5~35 |
MGC | AR+TBU+AAQ | 250~300 | 1~2 | Pd/SiO2 | 浆态床 | 15~18 | 45~48 |
Solvay | AR+TBU+EAQ | 160~180 | 1~2 | Pd/Al2O3-ZrO2 | 浆态床 | 12~15 | 43~46 |
Degussa | AR+TOP+EAQ | 160~180 | 1~2 | Pd | 浆态床 | 11~15 | 40~45 |
Arkema | AR+2-MCHA+EAQ | 160~180 | 1~2 | — | 浆态床 | 11~14 | 40~45 |
项目 | 工作液组成 | 氢化效率 /g·L-1 | 工作液损失 /kg·(tH2O2)-1 | 能耗 /kW·h·(tH2O2)-1 | 废气 /m3·(tH2O2)-1 | 废水 /m3·(tH2O2)-1 | 后处理程序 | 单套装置最高产能/104t·a-1 |
---|---|---|---|---|---|---|---|---|
浆态床 | AR+TOP+EAQ | 12~13 | 2.03 | 600 | 0 | 0.105 | 全酸性环境,本质安全 | 12 |
固定床 | AR+TOP+EAQ | 7~8 | 2.54 | 742 | 1000 | 0.15 | 酸碱切换,易爆炸 | 5 |
项目 | 工作液组成 | 氢化效率 /g·L-1 | 工作液损失 /kg·(tH2O2)-1 | 能耗 /kW·h·(tH2O2)-1 | 废气 /m3·(tH2O2)-1 | 废水 /m3·(tH2O2)-1 | 后处理程序 | 单套装置最高产能/104t·a-1 |
---|---|---|---|---|---|---|---|---|
浆态床 | AR+TOP+EAQ | 12~13 | 2.03 | 600 | 0 | 0.105 | 全酸性环境,本质安全 | 12 |
固定床 | AR+TOP+EAQ | 7~8 | 2.54 | 742 | 1000 | 0.15 | 酸碱切换,易爆炸 | 5 |
技术 | 反应器 | 环己酮转化率 /% | 环己酮肟选择性 /% | H2O2利用率 /% | 催化剂微反评价寿命 /h | 单位催化剂产能 /g酮·(g催化剂)-1 |
---|---|---|---|---|---|---|
中国石化技术 | 单釜 | 99.5 | 99.5 | 92.0 | 132 | 936 |
国外对比技术 | 双釜串联 | 99.4 | 98.2 | 89.0 | 70 | 424 |
技术 | 反应器 | 环己酮转化率 /% | 环己酮肟选择性 /% | H2O2利用率 /% | 催化剂微反评价寿命 /h | 单位催化剂产能 /g酮·(g催化剂)-1 |
---|---|---|---|---|---|---|
中国石化技术 | 单釜 | 99.5 | 99.5 | 92.0 | 132 | 936 |
国外对比技术 | 双釜串联 | 99.4 | 98.2 | 89.0 | 70 | 424 |
技术商 | 甲醇/双氧水(摩尔比) | 丙烯/双氧水(摩尔比) | 反应温度/℃ | 反应压力/MPa | H2O2转化率/% | 环氧丙烷选择性/% |
---|---|---|---|---|---|---|
中国石化 | 7.0 | 2.0 | 40 | 2.0 | 98.8 | 96.0 |
国外技术1 | 9.6 | 2.0 | 40 | 2.1 | 96.0 | 95.0 |
国外技术2 | 15.6 | 2.0 | 65 | 1.6 | 96.8 | 94.5 |
技术商 | 甲醇/双氧水(摩尔比) | 丙烯/双氧水(摩尔比) | 反应温度/℃ | 反应压力/MPa | H2O2转化率/% | 环氧丙烷选择性/% |
---|---|---|---|---|---|---|
中国石化 | 7.0 | 2.0 | 40 | 2.0 | 98.8 | 96.0 |
国外技术1 | 9.6 | 2.0 | 40 | 2.1 | 96.0 | 95.0 |
国外技术2 | 15.6 | 2.0 | 65 | 1.6 | 96.8 | 94.5 |
生产方法 | 原材料 | ECH 收率/% | 催化剂 | 剂耗 /t·(tECH)-1 | 能耗 | 废渣量 /t·(tECH)-1 | 废水 排放量 /t·(tECH)-1 | 预计 投资 /亿元 | 预计环保 投资 /亿元 | 环保费用 占总投资 比例/% |
---|---|---|---|---|---|---|---|---|---|---|
丙烯高温氯化法 | 丙烯,Cl2,Ca(OH)2 | 70~75 | — | — | 高 | 0.8~1.2 | 40 | 1.67 | 0.7 | 20 |
甘油法 | 甘油,干燥HCl,Ca(OH)2 | 85~90 | ZnCl2 | 0.0005 | 较低 | 0.4~0.6 | 15~17 | 1.62 | 0.5 | 10 |
氯丙烯直接环氧化法 | 氯丙烯,H2O2 | 95 | 钛硅分子筛 | 0.00016 | 较低 | 0 | 2-3 | 0.57 | 0.062 | 3 |
生产方法 | 原材料 | ECH 收率/% | 催化剂 | 剂耗 /t·(tECH)-1 | 能耗 | 废渣量 /t·(tECH)-1 | 废水 排放量 /t·(tECH)-1 | 预计 投资 /亿元 | 预计环保 投资 /亿元 | 环保费用 占总投资 比例/% |
---|---|---|---|---|---|---|---|---|---|---|
丙烯高温氯化法 | 丙烯,Cl2,Ca(OH)2 | 70~75 | — | — | 高 | 0.8~1.2 | 40 | 1.67 | 0.7 | 20 |
甘油法 | 甘油,干燥HCl,Ca(OH)2 | 85~90 | ZnCl2 | 0.0005 | 较低 | 0.4~0.6 | 15~17 | 1.62 | 0.5 | 10 |
氯丙烯直接环氧化法 | 氯丙烯,H2O2 | 95 | 钛硅分子筛 | 0.00016 | 较低 | 0 | 2-3 | 0.57 | 0.062 | 3 |
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