Chemical Industry and Engineering Progress ›› 2021, Vol. 40 ›› Issue (3): 1681-1688.DOI: 10.16085/j.issn.1000-6613.2020-0757
• Resources and environmental engineering • Previous Articles Next Articles
ZHANG Fuyuan(), ZHANG Jinchi, ZHANG Guang’an, ZHAO Zhuo
Received:
2020-05-06
Online:
2021-03-17
Published:
2021-03-05
Contact:
ZHANG Fuyuan
通讯作者:
张福元
作者简介:
张福元(1979—),男,博士,教授,研究方向为稀贵金属分离富集。E-mail:基金资助:
CLC Number:
ZHANG Fuyuan, ZHANG Jinchi, ZHANG Guang’an, ZHAO Zhuo. Comprehensive recovery of rare and precious metals from copper-rich solution of copper anode slime[J]. Chemical Industry and Engineering Progress, 2021, 40(3): 1681-1688.
张福元, 张金池, 张广安, 赵卓. 铜阳极泥分铜液综合回收稀贵金属[J]. 化工进展, 2021, 40(3): 1681-1688.
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URL: https://hgjz.cip.com.cn/EN/10.16085/j.issn.1000-6613.2020-0757
Cu含量 /g·L-1 | As含量 /g·L-1 | As??含量 /g·L-1 | As??含量 /g·L-1 | Te含量 /g·L-1 | Fe含量 /g·L-1 | Se含量 /g·L-1 | Au含量 /mg·L-1 | Ag含量 /g·L-1 | Pt含量 /mg·L-1 | Pd含量 /mg·L-1 |
---|---|---|---|---|---|---|---|---|---|---|
64.88 | 1.12 | 0.71 | 0.41 | 1.01 | 0.38 | 0.15 | 0.37 | 0.17 | 1.24 | 2.12 |
Cu含量 /g·L-1 | As含量 /g·L-1 | As??含量 /g·L-1 | As??含量 /g·L-1 | Te含量 /g·L-1 | Fe含量 /g·L-1 | Se含量 /g·L-1 | Au含量 /mg·L-1 | Ag含量 /g·L-1 | Pt含量 /mg·L-1 | Pd含量 /mg·L-1 |
---|---|---|---|---|---|---|---|---|---|---|
64.88 | 1.12 | 0.71 | 0.41 | 1.01 | 0.38 | 0.15 | 0.37 | 0.17 | 1.24 | 2.12 |
[Fe3+]/[Fe2+] | 实际电位/V | [Fe3+]/[Fe2+] | 实际电位/V |
---|---|---|---|
1/100000 | 0.416 | 1/10 | 0.700 |
1/10000 | 0.487 | 1 | 0.771 |
1/1000 | 0.558 | 10/1 | 0.842 |
1/100 | 0.629 | 100/1 | 0.913 |
[Fe3+]/[Fe2+] | 实际电位/V | [Fe3+]/[Fe2+] | 实际电位/V |
---|---|---|---|
1/100000 | 0.416 | 1/10 | 0.700 |
1/10000 | 0.487 | 1 | 0.771 |
1/1000 | 0.558 | 10/1 | 0.842 |
1/100 | 0.629 | 100/1 | 0.913 |
电极 | 电极反应 | 标准电极电位φ?/V |
---|---|---|
Fe3+/Fe2+ | Fe3++eFe2+ | 0.771 |
Cu2+/Cu | Cu2++2eCu | 0.342 |
HTeO | HTeO | 0.551 |
[PdCl4]2-/Pd | [PdCl4]2-+2ePd+4Cl- | 0.591 |
[PtCl6]2-/Pt | [PtCl6]2-+4ePt+6Cl- | 0.718 |
[AuCl2]-/Au | [AuCl2]-+eAu+2Cl- | 1.154 |
电极 | 电极反应 | 标准电极电位φ?/V |
---|---|---|
Fe3+/Fe2+ | Fe3++eFe2+ | 0.771 |
Cu2+/Cu | Cu2++2eCu | 0.342 |
HTeO | HTeO | 0.551 |
[PdCl4]2-/Pd | [PdCl4]2-+2ePd+4Cl- | 0.591 |
[PtCl6]2-/Pt | [PtCl6]2-+4ePt+6Cl- | 0.718 |
[AuCl2]-/Au | [AuCl2]-+eAu+2Cl- | 1.154 |
样品 | 浓度/g·L-1 | ||||||||
---|---|---|---|---|---|---|---|---|---|
Cu | Se | As | Te | Fe | Au① | Ag | Pt① | Pd① | |
沉淀率/% | — | 33.3 | 16.8 | 36.1 | — | 100 | 100 | 99.2 | 99.6 |
分铜液 | 84.13 | 0.15 | 3.28 | 1.55 | 0.22 | 0.35 | 0.21 | 1.33 | 2.42 |
沉淀后液1 | 83.17 | 0.11 | 2.70 | 0.96 | 5.97 | 0 | 0 | 0.02 | 0.01 |
沉淀后液2 | 79.66 | 0.10 | 2.78 | 0.99 | 5.88 | 0 | 0 | 0.01 | 0.02 |
沉淀后液 3 | 83.22 | 0.09 | 2.72 | 1.02 | 6.05 | 0 | 0 | 0 | 0 |
平均值 | 82.02 | 0.10 | 2.73 | 0.99 | 5.97 | 0 | 0 | 0.01 | 0.01 |
样品 | 浓度/g·L-1 | ||||||||
---|---|---|---|---|---|---|---|---|---|
Cu | Se | As | Te | Fe | Au① | Ag | Pt① | Pd① | |
沉淀率/% | — | 33.3 | 16.8 | 36.1 | — | 100 | 100 | 99.2 | 99.6 |
分铜液 | 84.13 | 0.15 | 3.28 | 1.55 | 0.22 | 0.35 | 0.21 | 1.33 | 2.42 |
沉淀后液1 | 83.17 | 0.11 | 2.70 | 0.96 | 5.97 | 0 | 0 | 0.02 | 0.01 |
沉淀后液2 | 79.66 | 0.10 | 2.78 | 0.99 | 5.88 | 0 | 0 | 0.01 | 0.02 |
沉淀后液 3 | 83.22 | 0.09 | 2.72 | 1.02 | 6.05 | 0 | 0 | 0 | 0 |
平均值 | 82.02 | 0.10 | 2.73 | 0.99 | 5.97 | 0 | 0 | 0.01 | 0.01 |
成分 | 质量分数/% | 成分 | 质量分数/% |
---|---|---|---|
Te | 18.24 | S | 0.538 |
As | 15.53 | Se | 0.894 |
Fe | 8.74 | Sb | 0.342 |
Ag | 10.54 | Pt① | 1010 |
Bi | 8.22 | Pd① | 320 |
Ti | 4.27 | Au① | 124 |
Cl | 3.38 |
成分 | 质量分数/% | 成分 | 质量分数/% |
---|---|---|---|
Te | 18.24 | S | 0.538 |
As | 15.53 | Se | 0.894 |
Fe | 8.74 | Sb | 0.342 |
Ag | 10.54 | Pt① | 1010 |
Bi | 8.22 | Pd① | 320 |
Ti | 4.27 | Au① | 124 |
Cl | 3.38 |
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