Chemical Industry and Engineering Progress ›› 2019, Vol. 38 ›› Issue (02): 921-932.DOI: 10.16085/j.issn.1000-6613.2018-0359
• Materials science and technology • Previous Articles Next Articles
Hualing LI1,2,3(),Yongzhen CHEN1,2,3,Wenji SONG1,2,3(),Ziping FENG1,2,3
Received:
2018-02-23
Revised:
2018-06-19
Online:
2019-02-05
Published:
2019-02-05
Contact:
Wenji SONG
黎华玲1,2,3(),陈永珍1,2,3,宋文吉1,2,3(),冯自平1,2,3
通讯作者:
宋文吉
作者简介:
<named-content content-type="corresp-name">黎华玲</named-content>(1987—),女,硕士研究生,研究方向为锂离子电池材料。E-mail:<email>lihl1@ms.giec.ac.cn</email>。|宋文吉,博士,研究员,研究方向为大规模储电及控制技术。E-mail:<email>songwj@ms.giec.ac.cn</email>。
基金资助:
CLC Number:
Hualing LI, Yongzhen CHEN, Wenji SONG, Ziping FENG. Research progress on the recovery of valuable metals in retired LiNi x Co y Mn z O2 batteries by wet process[J]. Chemical Industry and Engineering Progress, 2019, 38(02): 921-932.
黎华玲, 陈永珍, 宋文吉, 冯自平. 湿法回收退役三元锂离子电池有价金属的研究进展[J]. 化工进展, 2019, 38(02): 921-932.
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产品名称 | 2017年产量/万吨 | 2016年产量/万吨 | 同比增长/% |
---|---|---|---|
三元材料 | 12.6 | 6.5 | 93.85 |
磷酸铁锂 | 10.1 | 7.4 | 36.49 |
钴酸锂 | 6.0 | 5.1 | 17.65 |
锰酸锂 | 3.6 | 2.6 | 38.46 |
合计 | 32.3 | 21.6 | 49.54 |
消耗碳酸锂量 | 11.0 | 7.3 | 52.14 |
产品名称 | 2017年产量/万吨 | 2016年产量/万吨 | 同比增长/% |
---|---|---|---|
三元材料 | 12.6 | 6.5 | 93.85 |
磷酸铁锂 | 10.1 | 7.4 | 36.49 |
钴酸锂 | 6.0 | 5.1 | 17.65 |
锰酸锂 | 3.6 | 2.6 | 38.46 |
合计 | 32.3 | 21.6 | 49.54 |
消耗碳酸锂量 | 11.0 | 7.3 | 52.14 |
电池材料 | 金属含量(当量)/% | 金属价值/万元 | ||||
---|---|---|---|---|---|---|
Co | Ni | Li2CO3当量 | Co | Ni | Li2CO3 | |
LiFePO4 | 0 | 0 | 23.24 | 0 | 0 | 2.89 |
LiMn2O4 | 0 | 0 | 20.28 | 0 | 0 | 2.52 |
LiCoO2 | 60.21 | 0 | 37.47 | 23.03 | 0 | 4.66 |
LiNi0.33Co0.33Mn0.33O2 | 20.28 | 20.20 | 38.26 | 7.75 | 1.65 | 4.76 |
LiNi0.8Co0.15Al0.05O2 | 9.20 | 48.87 | 38.21 | 3.52 | 3.99 | 4.76 |
LiNi0.8Co0.1Mn0.1O2 | 6.06 | 48.26 | 38.00 | 2.32 | 3.94 | 4.73 |
电池材料 | 金属含量(当量)/% | 金属价值/万元 | ||||
---|---|---|---|---|---|---|
Co | Ni | Li2CO3当量 | Co | Ni | Li2CO3 | |
LiFePO4 | 0 | 0 | 23.24 | 0 | 0 | 2.89 |
LiMn2O4 | 0 | 0 | 20.28 | 0 | 0 | 2.52 |
LiCoO2 | 60.21 | 0 | 37.47 | 23.03 | 0 | 4.66 |
LiNi0.33Co0.33Mn0.33O2 | 20.28 | 20.20 | 38.26 | 7.75 | 1.65 | 4.76 |
LiNi0.8Co0.15Al0.05O2 | 9.20 | 48.87 | 38.21 | 3.52 | 3.99 | 4.76 |
LiNi0.8Co0.1Mn0.1O2 | 6.06 | 48.26 | 38.00 | 2.32 | 3.94 | 4.73 |
项目名称 | 具体内容 | 成本/元·吨-1 |
---|---|---|
原料 | 退役三元电池、碱、酸等化学试剂 | 20000 |
燃料动力 | 水、电等 | 700 |
设备维护 | 设备维修费、折旧费 | 600 |
环境处理 | 废气、废水、废渣等处理 | 700 |
人工 | 工资 | 600 |
其他费用 | 场地费、公摊费、税费等 | 6000 |
合计 | 28600 |
项目名称 | 具体内容 | 成本/元·吨-1 |
---|---|---|
原料 | 退役三元电池、碱、酸等化学试剂 | 20000 |
燃料动力 | 水、电等 | 700 |
设备维护 | 设备维修费、折旧费 | 600 |
环境处理 | 废气、废水、废渣等处理 | 700 |
人工 | 工资 | 600 |
其他费用 | 场地费、公摊费、税费等 | 6000 |
合计 | 28600 |
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