Research progress in the application of dehydroabietic amine and its derivatives

doi:10.16085/j.issn.1000-6613.2015.11.029

Chemical Industry and Engineering Progree ›› 2015, Vol. 34 ›› Issue (11): 4006-4013.DOI: 10.16085/j.issn.1000-6613.2015.11.029

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Research progress in the application of dehydroabietic amine and its derivatives

YANG Yanping¹, SHEN Minggui^1,2, SHANG Shibin^1,2, SONG Zhanqian¹

1 Institute of Chemical Industry of Forest Products, CAF;National Engineering Lab for Biomass Chemical Utilization;Key and Open Lab of Forest Chemical Engineering, SFA;Key Lab of Biomass Energy and Material, Jiangsu Province, Nanjing 210042, Jiangsu, China;
2 Institute of New Technology of Forestry, CAF, Beijing 100091, China

Received:2015-02-06 Revised:2015-03-19 Online:2015-11-05 Published:2015-11-05

脱氢枞胺及其衍生物的应用研究进展

杨艳平¹, 沈明贵^1,2, 商士斌^1,2, 宋湛谦¹

1 中国林业科学研究院林产化学工业研究所, 生物质化学利用国家工程实验室, 国家林业局林产化学工程重点开放性实验室, 江苏省生物质能源与材料重点实验室, 江苏南京 210042;
2 中国林业科学研究院林业新技术研究所, 北京 100091

通讯作者: 商士斌,研究员,博士生导师,从事生物质资源的化学研究与利用。E-mailshangsb@hotmail.com。
作者简介:杨艳平(1992—),女,硕士研究生。
基金资助:
国家自然科学基金项目(31470597)。

Abstract

Abstract: As the main component of disproportionated rosin amine, dehydroabietylamine with the tricyclic diterpene skeleton is one of the important modified products of rosin. The research progress in the application of dehydroabietylamine and its derivatives is reviewed, including the application of dehydroabietylamine in chiral compound separation and the application of dehydroabietylamine derivatives in antibacterial, anticorrosion, corrosion inhibition, metal ion flotation, catalysis, anticancer, antioxidation, antiulcer and combining with testosterone. At present, the study of dehydroabietylamine derivatives modified on B ring and C ring is still needed to be strengthened although dehydroabietic amine salts and N—C derivatives are widely studied. And furthermore, the in-depth study of dehydroabietylamine derivatives modified on B ring and C ring will further promote the application of dehydroabietylamine derivatives in biological activity. The future research and application of dehydroabietic amine derivatives on biomedical engineering are previewed.

Key words: disproportionated rosin amine, dehydroabietylamine, dehydroabietylamine derivatives, anticorrosion, antioxidation, biomedical engineering

摘要： 脱氢枞胺是歧化松香胺的主要成分,具有三环菲骨架结构,是松香重要的改性产品之一。本文综述了脱氢枞胺及其衍生物的应用研究进展,包括脱氢枞胺在手性化合物分离方面的应用和脱氢枞胺衍生物在抑菌、防腐、缓蚀、金属离子浮选、催化、抗癌、抗氧化、抗溃疡、可与雄性激素结合等方面的应用。指出目前脱氢枞胺成盐衍生物及脱氢枞胺N—C衍生物的研究较为广泛,脱氢枞胺B环和C环改性衍生物的研究仍需加强,而且对于B环和C环改性衍生物的深入研究,将进一步促进脱氢枞胺衍生物在生物活性方面的应用。最后对脱氢枞胺衍生物在生物医学工程上的应用前景进行了展望。

关键词: 歧化松香胺, 脱氢枞胺, 脱氢枞胺衍生物, 防腐, 抗氧化, 生物医学工程

CLC Number:

TQ351.471

YANG Yanping, SHEN Minggui, SHANG Shibin, SONG Zhanqian. Research progress in the application of dehydroabietic amine and its derivatives[J]. Chemical Industry and Engineering Progree, 2015, 34(11): 4006-4013.

杨艳平, 沈明贵, 商士斌, 宋湛谦. 脱氢枞胺及其衍生物的应用研究进展[J]. 化工进展, 2015, 34(11): 4006-4013.

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Research progress in the application of dehydroabietic amine and its derivatives

脱氢枞胺及其衍生物的应用研究进展

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