Review of removal of heavy metal ions from wastewater with agricultural and forestry waste as adsorbent

doi:10.16085/j.issn.1000-6613.2016.04.039

Abstract

Abstract: Industrial wastewater with heavy metals poses a serious threat to the environment, and bio-adsorption can effectively remove heavy metals. This paper firstly introduced current research status of common agricultural and forestry wastes and the modified reagents on absorption of heavy metals, then analyzed the influencing factors on bio-adsorption and the adsorption process optimization, followed by summarizing the mechanism of bio-adsorption and the desorption process and introducing the thermodynamic and kinetic models and related parameters. Finally, we pointed out the existing problems and development prospects of bio-adsorption. Agricultural and forestry waste has the advantages of wide range of sources, low cost and renewable. When used in wastewater treatment, it can achieve the full utilization of resources, so it has a good prospect in industrial application.

Key words: titanium isopropylate, cuprous chloride, dehydrolinalool, citral

摘要： 含重金属的工业废水对环境的危害是相当巨大的,生物吸附法可有效去除废水中的重金属.本文总结了常见的农林废弃物和化学改性剂在吸附重金属方面的研究现状,指出了生物吸附的影响因素及吸附工艺优化,阐述了生物吸附法的吸附机理及解吸处理,介绍了生物吸附的热力学和动力学模型及相关参数,同时指出了生物吸附法存在的问题,并展望其未来的发展前景.农林废弃物具有来源广、成本低、可再生等优点,用于重金属废水处理时,可实现资源的综合利用,具有良好的工业前景.

关键词: 农林废弃物, 重金属, 生物吸附, 废水处理

CLC Number:

X703.1

WEN Yonglin, LIU Pan, TANG Qi. Review of removal of heavy metal ions from wastewater with agricultural and forestry waste as adsorbent[J]. Chemical Industry and Engineering Progree, 2016, 35(04): 1208-1215.

文永林, 刘攀, 汤琪. 农林废弃物吸附脱除废水中重金属研究进展[J]. 化工进展, 2016, 35(04): 1208-1215.

References

[1] SHARMA P K,AYUB S, TRIPATHI C N. Agro and horticultural wastes as low cost adsorbents for removal of heavy metals from wastewater:a review[J]. International Refereed Journal of Engineering and Science,2013,2(8):18-27.
[2] 昝逢宇,霍守亮,席北斗,等. 啤酒酵母吸附去除水中Cd²⁺的影响因素[J]. 化工进展,2010,29(2):365-369.
[3] 张帆,李菁,谭建华,等. 吸附法处理重金属废水的研究进展[J]. 化工进展,2013,32(11):2749-2756.
[4] 朱锡锋,陆强. 生物质热裂解原理与技术[M]. 北京:科学出版社,2014:6.
[5] SINGHA B,DAS S K. Biosorption of Cr(Ⅵ) ions from aqueous solutions:kinetics,equilibrium,thermodynamics and desorption studies[J]. Colloids & Surfaces B Biointerfaces,2011,84(1):221-32.
[6] JAISHANKAR M,MATHEW B B,SHAH M S,et al. Biosorption of few heavy metal ions using agricultural wastes[J]. Journal of Environment Pollution and Human Health,2014,2(1):1-6.
[7] ANWAR J,SHAFIQUE U,Waheed-uz-ZAMAN,et al. Removal of Pb(Ⅱ) and Cd(Ⅱ) from water by adsorption on peels of banana[J].
Bioresource Technology,2010,101(6):1752-1755.
[8] FAROOQ F,FAROOQ U,BATOOL M,et al. Use of wheat straw for effective binding of metal ions via a novel modification[J]. Korean Journal of Chemical Engineering,2015,32(9):1818-1826.
[9] SUKSABYE P,THIRAVETYAN P. Cr(Ⅵ) adsorption from electroplating plating wastewater by chemically modified coir pith[J]. Journal of Environmental Management,2012,102(14):1-8.
[10] JÚNIOR O K,GURGEL L V A,FREITAS R P D,et al. Adsorption of Cu(Ⅱ),Cd(Ⅱ),and Pb(Ⅱ) from aqueous single metal solutions by mercerized cellulose and mercerized sugarcane bagasse chemically modified with EDTA dianhydride (EDTAD)[J]. Carbohydrate Polymers,2009,77(3):643-650.
[11] 谭光群,袁红雁,刘勇,等. 麦秆对重金属Pb²⁺和Cr³⁺吸附性能的研究[J]. 化学研究与应用,2011,23(7):840-846.
[12] 王丽艳,余军霞,何正艳,等. 改性甘蔗渣填充柱对铅离子的吸附[J]. 中国有色金属学报,2014,24(7):1921-1926.
[13] VIEIRA M G A,SILVA M G C D,Carneiro C N,et al. Adsorption of lead and copper ions from aqueous effluents on rice husk ash in a dynamic system[J]. Brazilian Journal of Chemical Engineering,2014,31(2):519-529.
[14] 郭磊. 改性稻秸对废水中铅、镉的吸附特征及其机制研究[D]. 沈阳:沈阳农业大学,2014.
[15] BUASRI A,CHAIYUT N,TAPANG K,et al. Equilibrium and kinetic studies of biosorption of Zn(Ⅱ) ions from wastewater using modified corn cob[J]. Apcbee Procedia,2012,3(8):60-64.
[16] VIOLETA Lugo-Lugo,SUSANA Hernández-López,Carlos Barrera-Díaz,et al. A comparative study of natural,formaldehyde-treated and copolymer-grafted orange peel for Pb(Ⅱ) adsorption under batch and continuous mode[J]. Journal of Hazardous Materials,2009,161(2-3):1255-1264.
[17] SALEM Nidá M.,AWWAD Akl M. Biosorption of Ni(Ⅱ) from electroplating wastewater by modified (Eriobotrya japonica) loquat bark[J]. Journal of Saudi Chemical Society,2014,18(5):379-386.
[18] LIU Y,SUN X,LI B. Adsorption of Hg²⁺ and Cd²⁺ by ethylenediamine modified peanut shells[J]. Carbohydrate Polymers,2010,81(2):335-339.
[19] VÁZQUEZ G,CALVO M,SONIA F M,et al. Chestnut shell as heavy metal adsorbent:optimization study of lead,copper and zinc cations removal[J]. Journal of Hazardous Materials,2009,172(2-3):1402-1414.
[20] YE Hengpeng,ZHU Qing,DU Dongyun. Adsorptive removal of Cd(Ⅱ) from aqueous solution using natural and modified rice husk[J]. Bioresource Technology,2010,101(14):5175-5179.
[21] MANSOUR M S,OSSMAN M E,FARAG H A. Removal of Cd(Ⅱ) ion from waste water by adsorption onto polyaniline coated on sawdust[J]. Desalination,2011,272(1):301-305.
[22] 万顺利,马钊钊,薛瑶,等. 氧化锰改性的茶叶渣吸附水体中Pb(Ⅱ)[J]. 环境化学,2014,33(12):2198-2205.
[23] CHAND P,PAKADE Y B. Utilization of chemically modified apple juice industrial waste for removal of Ni²⁺ ions from aqueous solution[J]. Journal of Material Cycles & Waste Management,2014,17(1):163-173.
[24] RAZA M H,SADIQ A,FAROOQ U,et al. Phragmites karka as a biosorbent for the removal of mercury metal Ions from aqueous solution:effect of modification[J]. Journal of Chemistry,2015,2015:1-12.
[25] GUO H,ZHANG S,KOU Z,et al. Removal of cadmium(Ⅱ) from
aqueous solutions by chemically modified maize straw[J].
Polymers,2015,115(115):177-185.
[26] LIU J,XIE T H,DENG C et al. Welan gum-modified cellulose bead as an effective adsorbent of heavy metal ions (Pb²⁺,Cu²⁺,and Cd²⁺) in aqueous solution[J]. Separation Science & Technology,2014,49(7):1096-1103.
[27] JIANG X,MA Z,JIANG Y,et al. Optimization of adsorption conditions of Cr(Ⅵ) by PEI modified bsg using response surface methodology[J]. Advance Journal of Food Science & Technology,2015,7(3):159-163.
[28] 杨玉山,董发勤,罗顺忠,等. 固定化啤酒酵母对锶离子的吸附[J]. 化工进展,2012,31(3):639-642.
[29] CHEN L,YANG F,MA P,et al. Adsorption performance of heavy metal Zn²⁺ by modified cabbage[J]. Chinese Journal of Environmental Engineering,2014,8(4):1526-1532.
[30] DENG K,PING Y,LIU X,et al. Modeling,analysis and optimization of adsorption parameters of Au(Ⅲ) using low-cost agricultural residuals buckwheat hulls[J]. Journal of Industrial & Engineering Chemistry,2014,20(4):2428-2438.
[31] JAYA S V C,DAS D,DAS N. Optimization of parameters for praseodymium(Ⅲ) biosorption onto biowaste materials using response surface methodology:equilibrium,kinetic and regeneration studies[J]. Ecological Engineering,2015,81:321-327.
[32] SUD D,MAHAJAN G,KAUR M P. Agricultural waste material as potential adsorbent for sequestering heavy metal ions from aqueous solutions:a review[J]. Bioresource Technology,2008,99(14):6017-6027.
[33] BOŽIĆ D,GORGIEVSKI M,STANKOVIĆ V,et al. Adsorption of heavy metal ions by beech sawdust——kinetics,mechanism and equilibrium of the process[J]. Ecological Engineering,2013,58:202-206.
[34] .KRISHNANI K,MENG X,CHRISTODOULATOS C,et al. Biosorption mechanism of nine different heavy metals onto biomatrix from rice husk[J]. Journal of Hazardous Materials,2008,153(3):1222-1234.
[35] LIANG S,GUO X,TIAN Q. Adsorption of Pb²⁺,Cu²⁺ and Ni²⁺ from aqueous solutions by novel garlic peel adsorbent[J]. Desalination & Water Treatment,2013,51(37):7166-7171.
[36] 李青竹,覃文庆,柴立元,等. 酯化改性麦糟对Pb(Ⅱ)的吸附特性[J]. 中国有色金属学报,2013,23(4):1152-1159.
[37] SITI N M Y,KAMARI A,PUTRA W P,et al. Removal of Cu(Ⅱ),Pb(Ⅱ) and Zn(Ⅱ) ions from aqueous solutions using selected agricultural wastes:adsorption and characterisation studies[J]. Journal of Environmental Protection,2014,5(4):289-300.
[38] KALAIVANI S S,VIDHYADEVI T,MURUGESAN A,et al. Equilibrium and kinetic studies on the adsorption of Ni(Ⅱ) ion from an aqueous solution using activated carbon prepared from Theobroma cacao (cocoa) shell[J]. Desalination & Water Treatment,2014,54(6):1629-1641.
[39] RUBCUMINTARA T. Adsorptive recovery of Au(Ⅲ) from aqueous solution using modified bagasse biosorbent[J]. International Journal of Chemical Engineering & Applications,2015,6(2):95-100.
[40] 李克斌,王勤勤,党艳,等. 荞麦皮生物吸附去除水中Cr(Ⅵ)的吸附特性和机理[J]. 化学学报,2012,70(7):929-937.
[41] LIAN A I,LUO X,WANG Y,et al. Selective adsorption of U(Ⅵ) and Cu(Ⅱ) ions by sunflower straw[J].Ciesc Journal,2014,65(4):1450-1461.
[42] 万顺利,徐圣友,张庆瑞,等. 废弃茶叶渣净化水体中重金属的
研究进展[J]. 水处理技术,2013,39(8):5-9.
[43] MONDAL M K. Removal of Pb(Ⅱ) ions from aqueous solution using activated tea waste: adsorption on a fixed bed column[J].Journal of Environmental Management,2009,90(11):3266-3271.
[44] 齐亚凤,何正艳,余军霞,等. 改性甘蔗渣对Cu²⁺和Zn²⁺的吸附机理[J]. 环境工程学报,2013,7(2):585-590.
[45] KILIÇ M,ÇISEM Kırbıyık,ÖZGE Çepelioğullar,et al. Adsorption of heavy metal ions from aqueous solutions by bio-char,a by-product of pyrolysis[J]. Applied Surface Science,2013,283(14):856-862.
[46] 聂小琴,董发勤,刘明学,等. 生物吸附剂梧桐树叶对铀的吸附行为研究[J]. 光谱学与光谱分析,2013,32(5):1290-1294.
[47] JAYA S V C,DAS D,DAS N. Optimization of parameters for cerium(Ⅲ) biosorption onto biowaste materials of animal and plant origin using 5-level Box-Behnken design:equilibrium,kinetic,thermodynamic and regeneration studies[J]. Journal of Rare Earths,2014,32(14):745-758.
[48] MORENO-PIRAJÁN J C,GIRALDO L. Heavy metal ions adsorption from wastewater using activated carbon from orange peel[J]. Journal of Chemistry,2012,9(2):926-937.
[49] MURITHI G,ONINDO C O,WAMBU E W,et al. Removal of cadmium(Ⅱ) ions from water by adsorption using water hyacinth (eichhornia crassipes) biomass[J]. Bioresources,2014,9(2):3613-3631.
[50] KONG W,REN J,WANG S,et al. Removal of heavy metals from aqueous solutions using acrylic-modified sugarcane bagasse-based adsorbents:equilibrium and kinetic studies[J]. Bioresources,2014,9(2):3184-3196.
[51] BEGUM Shaik Abdul Shahanaz,THARAKESWAR Yadamari,KALYAN Yakkala,et al. Biosorption of Cd(Ⅱ),Cr(Ⅵ) & Pb(Ⅱ) from aqueous solution using mirabilis jalapa as adsorbent[J]. Journal of Encapsulation and Adsorption Sciences,2015,05:93-104.
[52] CHERAGHI E,AMERI E,MOHEB A. Adsorption of cadmium ions from aqueous solutions using sesame as a low-cost biosorbent:kinetics and equilibrium studies[J]. International Journal of Environmental Science & Technology,2015,12(8):2579-2592.
[53] XIA L,YU Y U,ZHANG B H. Kinetics and equilibrium adsorption of copper(Ⅱ) and nickel(Ⅱ) ions from aqueous solution using sawdust xanthate modified with ethanediamine[J]. Transactions of Nonferrous Metals Society of China,2014,24(3):868-875.
[54] 李瑞月,陈德,李恋卿,等. 不同作物秸秆生物炭对溶液中Pb²⁺、Cd²⁺的吸附[J]. 农业环境科学学报,2015,34(5):1001-1008.
[55] GEORGIEVA V G,TAVLIEVA M P,GENIEVA S D,et al. Adsorption kinetics of Cr(Ⅵ) ions from aqueous solutions onto black rice husk ash[J]. Journal of Molecular Liquids,2015,208:219-226.
[56] KHALIR W,HANAFIAH M,SO'AD S,et al. Adsorption behavior of Pb(Ⅱ) onto xanthated rubber (hevea brasiliensis) leaf powder[J]. Polish Journal of Chemical Technology,2011,13(4):82-88.
[57] GORGIEVSKI M,BOŽIĆ D,STANKOVIĆ V,et al. Kinetics,equilibrium and mechanism of Cu²⁺,Ni²⁺and Zn²⁺ions biosorption using wheat straw[J]. Ecological Engineering,2013,58(10):113-122.
[58] RUNGRODNIMITCHAI S. Rapid preparation of biosorbents with high ion exchange capacity from rice straw and bagasse for removal of heavy metals[J]. Scientific World Journal,2014,2014(2014):1-9.
[59] FARHAN A M,AL-DUJAILI A H,AWWAD A M. Equilibrium and kinetic studies of cadmium(Ⅱ) and lead(Ⅱ) ions biosorption onto Ficus carcia leaves[J]. International Journal of Industrial Chemistry,2013,4(1):24.
[60] EUGENE Y,AKINOLA A. Kinetics and thermodynamics of Pb(Ⅱ) and Zn(Ⅱ) ions uptake from aqueous phase by tea (Camellia sinensis) seed shell[J]. IOSR Journal of Applied Chemistry,2015,8(4):20-26.
[61] 杨继利,潘新革,孔郑磊,等. 荔枝皮对重金属Ni²⁺的吸附性能[J]. 环境工程学报,2014,8(6):2277-2282.
[62] HAN R,ZHANG L,SONG C,et al. Characterization of modified wheat straw,kinetic and equilibrium study about copper ion and methylene blue adsorption in batch mode[J]. Carbohydrate Polymers,2010,79(4):1140-1149.