Experimental study on the preparation and stability of water-based carbon black-collagen nanofluids

doi:10.16085/j.issn.1000-6613.2023-0561

Abstract

Abstract:

Due to their excellent photothermal conversion performance, nanofluids have become the research focus of new solar collector media. However, due to its poor stability and complex preparation process, it has not been promoted in practical applications. In this paper, carbon black-collagen nanofluids were prepared by a two-step method using deionized water as the base solution. The effects of material addition order, collagen type, ultrasound time, material ratio and solution pH on the stability of nanofluids were explored. The results showed that the stability could be improved by dispersing carbon black and then adding collagen when preparing water-based carbon black-collagen nanofluids. Porcine skin collagen was more suitable for the preparation of carbon black-collagen nanofluids. The nanofluids prepared by ultrasound for 45min, the carbon black collagen mass ratio of 1/20 and the pH of suspension of 6.5―7.5 had good stability. This research would contribute to the industrial application of water-based carbon black-collagen nanofluids in the field of solar photothermal conversion in the future.

Key words: nanofluids, carbon black, collagen, stability, spectrophotometry, zeta potential

摘要：

纳米流体由于其优异的光热转换性能，已成为新型太阳能集热介质的研究重点；但因其稳定性差、制备工艺复杂，未能在实际应用中得到推广。本文以去离子水为基液，通过两步法制备炭黑-胶原蛋白纳米流体。探究了材料添加顺序、胶原蛋白种类、超声时间、材料配比以及溶液pH等对纳米流体稳定性的影响。结果表明，制备水基炭黑-胶原蛋白纳米流体时，先分散炭黑再加入胶原蛋白可以提高其稳定性；猪皮胶原蛋白更适用于炭黑-胶原蛋白纳米流体的制备；超声45min，炭黑胶原蛋白质量配比为1/20，悬浮液pH在6.5~7.5之间制备得到的纳米流体稳定性较好。本研究有助于今后水基炭黑-胶原蛋白纳米流体产业化应用于太阳能光热转换领域。

关键词: 纳米流体, 炭黑, 胶原蛋白, 稳定性, 分光光度计法, zeta电位

CLC Number:

TK01⁺9

LI Kai, WEI Helin, ZUO Xiahua, YANG Weimin, YAN Hua, AN Ying. Experimental study on the preparation and stability of water-based carbon black-collagen nanofluids[J]. Chemical Industry and Engineering Progress, 2024, 43(4): 1944-1952.

李凯, 魏鹤琳, 左夏华, 杨卫民, 阎华, 安瑛. 水基炭黑-胶原蛋白纳米流体制备及稳定性实验[J]. 化工进展, 2024, 43(4): 1944-1952.

Figures/Tables 17

References 35

1	李艳, 洪文鹏, 牛晓娟, 等. 水基Ag@TiO₂纳米流体液滴光热蒸发特性研究[J]. 工程热物理学报, 2022, 43(6): 1467-1472.
	LI Yan, HONG Wenpeng, NIU Xiaojuan, et al. Investigation on photothermal evaporation characteristics of water-based Ag@TiO₂ nanofluid droplets[J]. Journal of Engineering Thermophysics, 2022, 43(6): 1467-1472.
2	HAZRA S K, GHOSH S, NANDI T K. Photo-thermal conversion characteristics of carbon black-ethylene glycol nanofluids for applications in direct absorption solar collectors[J]. Applied Thermal Engineering, 2019, 163: 114402.
3	张俊, 李苏巧, 彭林明, 等. 纳米流体强化气液传质研究进展[J]. 化工进展, 2013, 32(4): 732-739.
	ZHANG Jun, LI Suqiao, PENG Linming, et al. Progress in research on gas-liquid mass transfer enhancement of nanofluids[J]. Chemical Industry and Engineering Progress, 2013, 32(4): 732-739.
4	王亚辉, 罗延旭, 刘耀, 等. 纳米流体研究进展[J]. 能源工程, 2022, 42(2): 7-16.
	WANG Yahui, LUO Yanxu, LIU Yao, et al. Review of research progress of nanofluids[J]. Energy Engineering, 2022, 42(2): 7-16.
5	刘宇龙, 佘跃惠. 纳米粒子的分散稳定机制及影响因素研究[J]. 化工新型材料, 2022, 50(S1): 298-302, 311.
	LIU Yulong, SHE Yuehui. Study on dispersion stability mechanism and influencing factors of nanoparticles[J]. New Chemical Materials, 2022, 50(S1): 298-302, 311.
6	洪欢喜, 武卫东, 盛伟, 等. 纳米流体制备的研究进展[J]. 化工进展, 2008, 27(12): 1923-1928.
	HONG Huanxi, WU Weidong, SHENG Wei, et al. Research progress of preparation of nanofluids[J]. Chemical Industry and Engineering Progress, 2008, 27(12): 1923-1928.
7	马明琰, 翟玉玲, 轩梓灏, 等. 三元混合纳米流体稳定性及热性能[J]. 化工进展, 2021, 40(8): 4179-4186.
	MA Mingyan, ZHAI Yuling, XUAN Zihao, et al. Stability and thermal performance of ternary hybrid nanofluids[J]. Chemical Industry and Engineering Progress, 2021, 40(8): 4179-4186.
8	KIM Hyun Jin, LEE Seung-Hyun, LEE Ji-Hwan, et al. Effect of particle shape on suspension stability and thermal conductivities of water-based bohemite alumina nanofluids[J]. Energy, 2015, 90: 1290-1297.
9	SUSEEL Jai Krishnan S, NAGARAJAN P K. Influence of stability and particle shape effects for an entropy generation based optimized selection of magnesia nanofluid for convective heat flow applications[J]. Applied Surface Science, 2019, 489: 560-575.
10	沈向阳, 李国铭, 陈嘉澍, 等. Al₂O₃/丙二醇纳米流体的稳定性研究及热物性测量[J]. 低温与超导, 2021, 49(9): 88-94.
	SHEN Xiangyang, LI Guoming, CHEN Jiashu, et al. Study on stability of Al₂O₃/propylene glycol nanofluids and its thermophysical property measurement[J]. Cryogenics & Superconductivity, 2021, 49(9): 88-94.
11	恭飞, 吴张永, 王雪婷, 等. SiC纳米流体制备及属性仿真实验研究[J]. 硅酸盐通报, 2020, 39(3): 986-994, 1001.
	GONG Fei, WU Zhangyong, WANG Xueting, et al. Experimental study on preparation and property simulation of SiC nanofluids[J]. Bulletin of the Chinese Ceramic Society, 2020, 39(3): 986-994, 1001.
12	王晗. 管式太阳能集热器高效集热介质及综合利用方法研究[D]. 北京: 北京化工大学, 2018.
	WANG Han. Study on efficient working fluids and comprehensive utilization methods of tubular solar collector[D]. Beijing: Beijing University of Chemical Technology, 2018.
13	熊亚选, 宋超宇, 药晨华, 等. 纳米流体稳定性研究综述[J]. 华电技术, 2021, 43(7): 68-74.
	XIONG Yaxuan, SONG Chaoyu, YAO Chenhua, et al. Review on the stability of nanofluids[J]. Huadian Technology, 2021, 43(7): 68-74.
14	CHUNG S J, LEONARD J P, NETTLESHIP I, et al. Characterization of ZnO nanoparticle suspension in water: Effectiveness of ultrasonic dispersion[J]. Powder Technology, 2009, 194(1/2): 75-80.
15	丁洁, 王平, 张本国, 等. 混合基纳米流体在汽车散热器中的稳定性及传热特性[J]. 科学技术与工程, 2019, 19(1): 196-206.
	DING Jie, WANG Ping, ZHANG Benguo, et al. Stability and heat transfer characteristics in automotive radiators of mixed-based nanofluids[J]. Science Technology and Engineering, 2019, 19(1): 196-206.
16	ISMAIL H, SULAIMAN M Z, AIZZAT M H. Qualitative investigations on the stability of Al₂O₃-SiO₂ hybrid water-based nanofluids[J]. IOP Conference Series: Materials Science and Engineering, 2020, 788(1): 012091.
17	毛凌波. 太阳能吸收与热输运纳米黑液材料的制备与性能研究[D]. 广州: 广东工业大学, 2008.
	MAO Lingbo. Study on preparation and properties of black nanofluids for solar radiation absorbing and heat transporting[D]. Guangzhou: Guangdong University of Technology, 2008.
18	KEKLIKCIOGLU CAKMAK Nese. The impact of surfactants on the stability and thermal conductivity of graphene oxide de-ionized water nanofluids[J]. Journal of Thermal Analysis and Calorimetry, 2020, 139(3): 1895-1902.
19	宋景东, 孙娟, 孙斌. 太阳集热管纳米流体的光热性能实验[J]. 化工进展, 2016, 35(5): 1314-1320.
	SONG Jingdong, SUN Juan, SUN Bin. Experimental investigation on photo-thermal properties of nanofluid for the solar tube[J]. Chemical Industry and Engineering Progress, 2016, 35(5): 1314-1320.
20	Alexandra GIMENO-FURIO, NAVARRETE Nuria, MONDRAGON Rosa, et al. Stabilization and characterization of a nanofluid based on a eutectic mixture of diphenyl and diphenyl oxide and carbon nanoparticles under high temperature conditions[J]. International Journal of Heat and Mass Transfer, 2017, 113: 908-913.
21	Pritam Kumar DAS, ISLAM Nurul, SANTRA Apurba Kumar, et al. Experimental investigation of thermophysical properties of Al₂O₃-water nanofluid: Role of surfactants[J]. Journal of Molecular Liquids, 2017, 237: 304-312.
22	程波，杜垲, 张小松, 等. 氨水-纳米炭黑纳米流体的稳定性研究[C]//第五届全国制冷空调新技术研讨会论文集. 厦门, 2008: 326-330.
23	ZHANG Hao, QING Shan, ZHAI Yuling, et al. The changes induced by pH in TiO₂/water nanofluids: Stability, thermophysical properties and thermal performance[J]. Powder Technology, 2021, 377: 748-759.
24	HUANG Jin, WANG Xianju, LONG Qiong, et al. Influence of pH on the stability characteristics of nanofluids[C]//2009 Symposium on Photonics and Optoelectronics. Wuhan： IEEE, 2009: 1-4.
25	ZAREEI Maliheh, YOOZBASHIZADEH Hossein, MADAAH HOSSEINI Hamid Reza. The effect of pH and ionic strength on the transport of alumina nanofluids in water-saturated porous media[J]. Journal of Thermal Analysis and Calorimetry, 2019, 137(4): 1169-1179.
26	代浩. 基于炭黑纳米颗粒的太阳能蒸馏器样机制作及实验研究[D]. 武汉: 华中科技大学, 2020.
	DAI Hao. The prototype fabrication and experimental study on solar still with carbon black nanoparticles[D]. Wuhan: Huazhong University of Science and Technology, 2020.
27	龚碧瑶. 面向海水淡化的碳基纳米光热蒸发结构及其界面能质传输特性研究[D]. 杭州: 浙江大学, 2022.
	GONG Biyao. Study on carbon-based nano-photothermal evaporation structure and its interface energy and mass transfer characteristics for seawater desalination[D]. Hangzhou: Zhejiang University, 2022.
28	李金宝, 谢竺航, 杨雪, 等. 炭黑/CNF复合光热转化材料的制备及性能研究[J]. 中国造纸, 2020, 39(7): 9-14.
	LI Jinbao, XIE Zhuhang, YANG Xue, et al. Study on preparation and properties of carbon black/CNF composite photothermal conversion materials[J]. China Pulp & Paper, 2020, 39(7): 9-14.
29	王迅. 炭黑组件气液界面加热海水蒸馏淡化及其抗盐析性能研究[D]. 杭州: 浙江大学, 2020.
	WANG Xun. Carbon black-based salt-ressisting solar evaporator for efficient and durable seawater evaporation based on interfacial solar heating[D]. Hangzhou: Zhejiang University, 2020.
30	WANG Han, YANG Weimin, CHENG Lisheng, et al. Chinese ink: High performance nanofluids for solar energy[J]. Solar Energy Materials and Solar Cells, 2018, 176: 374-380.
31	高玲玲, 侯成立, 高远, 等. 胶原蛋白热稳定性研究进展[J]. 中国食品学报, 2018, 18(5): 195-207.
	GAO Lingling, HOU Chengli, GAO Yuan, et al. Research advances of thermal stability of collagen[J]. Journal of Chinese Institute of Food Science and Technology, 2018, 18(5): 195-207.
32	肖倩影. PNIPAm水凝胶复合膜制备及高效吸附蛋白质研究[D]. 大连: 大连理工大学, 2022.
	XIAO Qianying. Preparation of PNIPAm hydrogel composite membrane and its high-efficiency adsorption of protein[D].Dalian: Dalian University of Technology, 2022.
33	张亚楠, 刘妮, 由龙涛, 等. 表面活性剂对水基纳米流体特性影响的研究进展[J]. 化工进展, 2015, 34(4): 903-910, 920.
	ZHANG Yanan, LIU Ni, YOU Longtao, et al. Research progress in the effect of surfactants on the characteristics of H₂O-based nanofluids[J]. Chemical Industry and Engineering Progress, 2015, 34(4): 903-910, 920.
34	解矛盾, 闫瑾. 疏水性Fe₃O₄磁性纳米粒子的表面改性修饰[J]. 焦作大学学报, 2015, 29(4): 77-79.
	XIE Maodun, YAN Jin. Surface modification of hydrophobic Fe₃O₄ magnetic nanoparticles[J]. Journal of Jiaozuo University, 2015, 29(4): 77-79.
35	宋晓岚, 邱冠周, 史训达, 等. 混合表面活性剂分散纳米CeO₂颗粒的协同效应[J]. 湖南大学学报(自然科学版), 2005, 32(5): 95-99.
	SONG Xiaolan, QIU Guanzhou, SHI Xunda, et al. Synergistic effect of mixed surfactants on the dispersion stability of CeO₂ nanoparticles[J]. Journal of Hunan University (Natural Science), 2005, 32(5): 95-99.

原材料	生产厂家	规格/尺度
炭黑	美国CABOT公司	15nm
胶原蛋白	尚宏生物科技有限公司	500g/袋
去离子水	来源LD-UPW-20超纯水机	电导率<5μS/cm

原材料	生产厂家	规格/尺度
炭黑	美国CABOT公司	15nm
胶原蛋白	尚宏生物科技有限公司	500g/袋
去离子水	来源LD-UPW-20超纯水机	电导率<5μS/cm

仪器名称	生产厂家	仪器型号
电子天平	上海海康电子仪器厂	FA214
超声波细胞破碎机	宁波新芝生物科技股份有限公司	Scientz IID
紫外-可见分光光度计	南京菲勒仪器有限公司	G-9PC，PHILES
超声波清洗机	深圳福洋科技集团有限公司	F-030S
磁力搅拌仪	常州金坛良友仪器有限公司	HJ-2A
zeta 电位及粒度分析仪	美国布鲁克海文仪器公司	ZetaPALS

仪器名称	生产厂家	仪器型号
电子天平	上海海康电子仪器厂	FA214
超声波细胞破碎机	宁波新芝生物科技股份有限公司	Scientz IID
紫外-可见分光光度计	南京菲勒仪器有限公司	G-9PC，PHILES
超声波清洗机	深圳福洋科技集团有限公司	F-030S
磁力搅拌仪	常州金坛良友仪器有限公司	HJ-2A
zeta 电位及粒度分析仪	美国布鲁克海文仪器公司	ZetaPALS

[1]	LIU Han, QU Minglu, YE Zhendong, YANG Fan, HUANG Beijia, ZHANG Yaning, LIU Hongzhi. Evaluation of the thermal energy storage performance of calcium-magnesium binary composite salt hydrates [J]. Chemical Industry and Engineering Progress, 2024, 43(4): 1764-1773.
[2]	LU Zhiqiang, SHI Yu, CHEN Pengyu, ZHANG Liang, LI Jun, FU Qian, ZHU Xun, LIAO Qiang. Performance of a vertical thermally regenerative ammonia-based battery with a high-concentration ammonia chamber [J]. Chemical Industry and Engineering Progress, 2024, 43(3): 1224-1231.
[3]	LIU Zepeng, ZENG Jijun, TANG Xiaobo, ZHAO Bo, HAN Sheng, LIAO Yuanhao, ZHANG Wei. Thermodynamic properties of four alkyl imidazolium phosphate ionic liquids [J]. Chemical Industry and Engineering Progress, 2024, 43(3): 1484-1491.
[4]	SUN Hongjun, LI Teng, LI Jinxia, DING Hongbing. Disturbance wave height prediction model based on Kelvin-Helmholtz instability and interfacial shear [J]. Chemical Industry and Engineering Progress, 2024, 43(2): 609-618.
[5]	SUN Yue, WANG Sijia, WU Mingxia, SONG Xianyu, XU Shouhong. Synthesis, performance regulation and application of pH/temperature responsive polymer PMAA-b-PDMAEMA [J]. Chemical Industry and Engineering Progress, 2024, 43(1): 480-489.
[6]	ZHANG Dailing, DING Yumei, ZUO Xiahua, LI Haowei, YANG Weimin, YAN Hua, AN Ying. Photothermal characteristics of waste toner nanofluids [J]. Chemical Industry and Engineering Progress, 2023, 42(9): 4791-4798.
[7]	WANG Xin, WANG Bingbing, YANG Wei, XU Zhiming. Anti-scale and anti-corrosion properties of PDA/PTFE superhydrophobic coating on metal surface [J]. Chemical Industry and Engineering Progress, 2023, 42(8): 4315-4321.
[8]	LU Yang, ZHOU Jinsong, ZHOU Qixin, WANG Tang, LIU Zhuang, LI Bohao, ZHOU Lingtao. Leaching mechanism of Hg-absorption products on CeO₂/TiO₂ sorbentsin syngas [J]. Chemical Industry and Engineering Progress, 2023, 42(7): 3875-3883.
[9]	WU Zhanhua, SHENG Min. Pitfalls of accelerating rate calorimeter for reactivity hazard evaluation and risk assessment [J]. Chemical Industry and Engineering Progress, 2023, 42(7): 3374-3382.
[10]	XIE Zhiwei, WU Zhangyong, ZHU Qichen, JIANG Jiajun, LIANG Tianxiang, LIU Zhenyang. Viscosity properties and magnetoviscous effects of Ni_0.5Zn_0.5Fe₂O₄ vegetable oil-based magnetic fluid [J]. Chemical Industry and Engineering Progress, 2023, 42(7): 3623-3633.
[11]	YANG Jingying, SHI Wansheng, HUANG Zhenxing, XIE Lijuan, ZHAO Mingxing, RUAN Wenquan. Research progress on the preparation of modified nano zero-valent iron materials [J]. Chemical Industry and Engineering Progress, 2023, 42(6): 2975-2986.
[12]	YANG Yang, SUN Zhigao, LI Cuimin, LI Juan, HUANG Haifeng. Promotion on the formation of HCFC-141b hydrate under static conditions by surfactant OP-13 [J]. Chemical Industry and Engineering Progress, 2023, 42(6): 2854-2859.
[13]	PANG Nanjiong, WANG Xiaoling, LIAO Xuepin, SHI Bi. Separation of boron isotopes by collagen fibers-immobilized black wattle tannin [J]. Chemical Industry and Engineering Progress, 2023, 42(5): 2616-2625.
[14]	LI Ling, MA Chaofeng, LU Chunshan, YU Wanjin, SHI Nengfu, JIN Jiamin, ZHANG Jianjun, LIU Wucan, LI Xiaonian. Progress on the synthesis of 1,1,2-trifluoroethene and the catalysts [J]. Chemical Industry and Engineering Progress, 2023, 42(4): 1822-1831.
[15]	YIN Ming, GUO Jin, PANG Jifeng, WU Pengfei, ZHENG Mingyuan. Deactivation mechanisms and stabilizing strategies for Cu based catalysts in reactions with hydrogen [J]. Chemical Industry and Engineering Progress, 2023, 42(4): 1860-1868.