Research progress on preparation technology of phase-change bidirectional temperature-regulating textile materials

doi:10.16085/j.issn.1000-6613.2021-1652

Abstract

Abstract:

Phase-change bidirectional temperature-regulating textile materials are the product of the combination of the energy field and the textile industry, and has the advantage of automatic bidirectional temperature-regulation. From the perspective of preparation technology, this article introduces two major approaches: phase-change fiber preparation method and post-finishing method. Around the phase change fiber preparation method, the principle and application of microcapsule melt spinning method, microcapsule solution spinning method, electrostatic spinning method, PCMs composite spinning method and fiber hollow filling method are explained in detail. For the finishing method, the principle and application of filling method, coating method, printing method, pad-dry-cure method and grafting method are introduced in detail. The advantages and disadvantages of various preparation technologies are analyzed in order to deepen the knowledge and understanding of phase-change bidirectional temperature-regulating textile materials from the preparation technology. The advancement of preparation technology can improve the comprehensive performance of the phase-change bidirectional temperature-regulating textile material. How to prepare the phase-change bidirectional temperature-regulating textile material that to meet the requirements of wearing with excellent comprehensive performance is the key to its application. Finally, suggestions and prospects for the future research directions of phase-change bidirectional temperature-regulating textile materials are put forward in the hope of providing reference for the research of preparation technology of phase-change bidirectional temperature-regulating textile materials.

Key words: phase change material, microcapsule, temperature-regulating textile, spinning method, composite material

摘要：

相变双向调温纺织材料是能源领域与纺织行业结合的产物，具有自动双向调温的优点。本文从制备技术的角度出发，分别介绍了相变纤维制备法和后整理法两大途径。围绕相变纤维制备法，详细阐述了微胶囊熔融纺丝法、微胶囊溶液纺丝法、静电纺丝法、PCMs复合纺丝法和纤维中空填充法的原理及应用。针对后整理法，详细介绍了填充法、涂层法、印花法、浸轧法和接枝法的原理及应用。分析了各种制备技术的优缺点，以期从制备技术上加深对相变双向调温纺织材料的认知和理解。制备技术的进步可提高相变双向调温纺织材料的综合性能，如何制备出满足服用要求、综合性能优异的相变双向调温纺织材料是其实现应用的关键。最后，对相变双向调温纺织材料未来的研究方向提出了建议和展望，以期为相变双向调温纺织材料制备技术的研究提供参考和借鉴。

关键词: 相变材料, 微胶囊, 调温纺织, 纺丝法, 复合材料

CLC Number:

TS195.6

GUO Zhi’an, SUI Zhihui, LI Yaping, XU Yikun, SUN Fang, ZHAO Xin. Research progress on preparation technology of phase-change bidirectional temperature-regulating textile materials[J]. Chemical Industry and Engineering Progress, 2022, 41(7): 3648-3659.

郭制安, 隋智慧, 李亚萍, 徐逸坤, 孙芳, 赵欣. 相变双向调温纺织材料制备技术研究进展[J]. 化工进展, 2022, 41(7): 3648-3659.

Figures/Tables 9

References 66

1	TYURIN I N, GETMANTSEVA V V, ANDREEVA E G. Analysis of innovative technologies of thermoregulating textile materials[J]. Fibre Chemistry, 2018, 50(1): 1-9.
2	IQBAL K, KHAN A, SUN D M, et al. Phase change materials, their synthesis and application in textiles—A review[J]. The Journal of the Textile Institute, 2019, 110(4): 625-638.
3	申天伟, 陆少锋, 张晶, 等. 低黄变聚脲微胶囊相变材料的制备及性能表征[J]. 化工进展, 2017, 36(12): 4547-4553.
	SHEN Tianwei, LU Shaofeng, ZHANG Jing, et al. Preparation and performance characterization of low-yellowing polyurea microcapsule phase change materials[J]. Chemical Industry and Engineering Progress, 2017, 36(12): 4547-4553.
4	ALVA G, LIN Y X, LIU L K, et al. Synthesis, characterization and applications of microencapsulated phase change materials in thermal energy storage: a review[J]. Energy and Buildings, 2017, 144: 276-294.
5	ZHAO C Y, ZHANG G H. Review on microencapsulated phase change materials (MEPCMs): fabrication, characterization and applications[J]. Renewable and Sustainable Energy Reviews, 2011, 15(8): 3813-3832.
6	JAMEKHORSHID A, SADRAMELI S M, FARID M. A review of microencapsulation methods of phase change materials (PCMs) as a thermal energy storage (TES) medium[J]. Renewable and Sustainable Energy Reviews, 2014, 31: 531-542.
7	王鑫, 方建华, 吴江, 等.改性SiO₂杂化层相变微胶囊的制备与表征[J].化工进展, 2020, 39(4): 1431-1438.
	WANG Xin, FANG Jianhua, WU Jiang, et al. Preparation and characterization of SiO₂hybrid phase change microcapsules[J]. Chemical Industry and Engineering Progress, 2020, 39(4): 1431-1438.
8	ZHOU Y C, WU S Q, MA Y, et al. Recent advances in organic/composite phase change materials for energy storage[J]. ES Energy & Environment, 2020, 9: 28-40.
9	PRAJAPATI D G, KANDASUBRAMANIAN B. A review on polymeric-based phase change material for thermo-regulating fabric application[J]. Polymer Reviews, 2020, 60(3): 389-419.
10	BRYANT Y G, COLVIN D P. Fiber with reversible enhanced thermal storage properties and fabrics made therefrom: US4756958[P]. 1988-07-12.
11	IQBAL K, SUN D M. Development of thermo-regulating polypropylene fibre containing microencapsulated phase change materials[J]. Renewable Energy, 2014, 71: 473-479.
12	IQBAL K, SUN D M. Development of thermal stable multifilament yarn containing micro-encapsulated phase change materials[J]. Fibers and Polymers, 2015, 16(5): 1156-1162.
13	LI W, MA Y J, TANG X F, et al. Composition and characterization of thermoregulated fiber containing acrylic-based copolymer microencapsulated phase-change materials (MicroPCMs)[J]. Industrial & Engineering Chemistry Research, 2014, 53(13): 5413-5420.
14	HARTMANN M H, WORLEY J B. Cellulosic fibers having enhanced reversible thermal properties and methods of forming thereof: US7244497[P]. 2007-07-17.
15	ZHANG X X, WANG X C, TAO X M, et al. Structures and properties of wet spun thermo-regulated polyacrylonitrile-vinylidene chloride fibers[J]. Textile Research Journal, 2006, 76(5): 351-359.
16	AHN Y H, DEWITT S J A, MCGUIRE S, et al. Incorporation of phase change materials into fibers for sustainable thermal energy storage[J]. Industrial & Engineering Chemistry Research, 2021, 60(8): 3374-3384.
17	LI J J, WANG B, YE G D, et al. Study of synthesizing energy storage microcapsules in PVA spinning solution and thermal regulating fibers prepared by this solution[J]. Fibers and Polymers, 2013, 14(4): 537-541.
18	SARIER N, ONDER E. Organic phase change materials and their textile applications: an overview[J]. Thermochimica Acta, 2012, 540: 7-60.
19	WU Y, CHEN C Z, JIA Y F, et al. Review on electrospun ultrafine phase change fibers (PCFs) for thermal energy storage[J]. Applied Energy, 2018, 210: 167-181.
20	MCCANN J T, MARQUEZ M, XIA Y N. Melt coaxial electrospinning: a versatile method for the encapsulation of solid materials and fabrication of phase change nanofibers[J]. Nano Letters, 2006, 6(12): 2868-2872.
21	LING Z Y, CHEN J J, XU T, et al. Thermal conductivity of an organic phase change material/expanded graphite composite across the phase change temperature range and a novel thermal conductivity model[J]. Energy Conversion and Management, 2015, 102: 202-208.
22	NOMURA T, TABUCHI K, ZHU C Y, et al. High thermal conductivity phase change composite with percolating carbon fiber network[J]. Applied Energy, 2015, 154: 678-685.
23	MEHRALI M, LATIBARI S T, MEHRALI M, et al. Preparation and characterization of palmitic acid/graphene nanoplatelets composite with remarkable thermal conductivity as a novel shape-stabilized phase change material[J]. Applied Thermal Engineering, 2013, 61(2): 633-640.
24	XIAO X, ZHANG P, LI M. Effective thermal conductivity of open-cell metal foams impregnated with pure paraffin for latent heat storage[J]. International Journal of Thermal Sciences, 2014, 81: 94-105.
25	NOURANI M, HAMDAMI N, KERAMAT J, et al. Thermal behavior of paraffin-nano-Al₂O₃ stabilized by sodium stearoyl lactylate as a stable phase change material with high thermal conductivity[J]. Renewable Energy, 2016, 88: 474-482.
26	BABAPOOR A, KARIMI G, KHORRAM M. Fabrication and characterization of nanofiber-nanoparticle-composites with phase change materials by electrospinning[J]. Applied Thermal Engineering, 2016, 99: 1225-1235.
27	GOLESTANEH S I, KARIMI G, BABAPOOR A, et al. Thermal performance of co-electrospun fatty acid nanofiber composites in the presence of nanoparticles[J]. Applied Energy, 2018, 212: 552-564.
28	LU Y, XIAO X D, FU J, et al. Novel smart textile with phase change materials encapsulated core-sheath structure fabricated by coaxial electrospinning[J]. Chemical Engineering Journal, 2019, 355: 532-539.
29	XIANG H X, ZHOU J L, ZHANG Y K, et al. Polyethylene glycol infused acid-etched halloysite nanotubes for melt-spun polyamide-based composite phase change fibers[J]. Applied Clay Science, 2019, 182: 105249.
30	ZHANG X W, LU Y. Centrifugal spinning: an alternative approach to fabricate nanofibers at high speed and low cost[J]. Polymer Reviews, 2014, 54(4): 677-701.
31	ZHANG X G, QIAO J X, ZHAO H, et al. Preparation and performance of novel polyvinylpyrrolidone/polyethylene glycol phase change materials composite fibers by centrifugal spinning[J]. Chemical Physics Letters, 2018, 691: 314-318.
32	CHEN G, SHI T T, ZHANG X G, et al. Polyacrylonitrile/polyethylene glycol phase-change material fibres prepared with hybrid polymer blends and nano-SiC fillers via centrifugal spinning[J]. Polymer, 2020, 186: 122012.
33	HANSEN R H. Temperature adaptable fabrics: US3607591[P]. 1971-09-21.
34	VIGO T L, FROST C E. Temperature-sensitive hollow fibers containing phase change salts[J]. Textile Research Journal, 1982, 52(10): 633-637.
35	SONG S K, ZHAO T T, ZHU W T, et al. Natural microtubule-encapsulated phase-change material with simultaneously high latent heat capacity and enhanced thermal conductivity[J]. ACS Applied Materials & Interfaces, 2019, 11(23): 20828-20837.
36	DONG T, JIANG W, LIU Y, et al. A phase change material embedded composite consisting of kapok and hollow PET fibers for dynamic thermal comfort regulation[J]. Industrial Crops and Products, 2020, 158: 112945.
37	KAMON E, KENNEY W L, DENO N S, et al. Readdressing personal cooling with ice[J]. American Industrial Hygiene Association Journal, 1986, 47(5): 293-298.
38	COLEMAN S R. Heat storage capacity of gelled coolants in ice vests[J]. American Industrial Hygiene Association Journal, 1989, 50(6): 325-329.
39	KENNY G P, SCHISSLER A R, STAPLETON J, et al. Ice cooling vest on tolerance for exercise under uncompensable heat stress[J]. Journal of Occupational and Environmental Hygiene, 2011, 8(8): 484-491.
40	GAO C S, KUKLANE K, HOLMÉR I. Cooling vests with phase change materials: the effects of melting temperature on heat strain alleviation in an extremely hot environment[J]. European Journal of Applied Physiology, 2011, 111(6): 1207-1216.
41	REINERTSEN R E, FÆREVIK H, HOLBØ K, et al. Optimizing the performance of phase-change materials in personal protective clothing systems[J]. International Journal of Occupational Safety and Ergonomics, 2008, 14(1): 43-53.
42	BENDKOWSKA W, KŁONOWSKA M, KOPIAS K, et al. Thermal manikin evaluation of PCM cooling vests[J]. Fibres & Textiles in Eastern Europe, 2010, 1 (78): 70-74.
43	ZHAO M M, GAO C S, WANG F M, et al. The torso cooling of vests incorporated with phase change materials: a sweat evaporation perspective[J]. Textile Research Journal, 2013, 83(4): 418-425.
44	HOUSHYAR S, PADHYE R, TROYNIKOV O, et al. Evaluation and improvement of thermo-physiological comfort properties of firefighters’ protective clothing containing super absorbent materials[J]. The Journal of the Textile Institute, 2015, 106(12): 1394-1402.
45	ITANI M, GHADDAR N, GHALI K. Innovative PCM-desiccant packet to provide dry microclimate and improve performance of cooling vest in hot environment[J]. Energy Conversion and Management, 2017, 140: 218-227.
46	ZHAO Y J, YI W, CHAN A P, et al. Evaluating the physiological and perceptual responses of wearing a newly designed cooling vest for construction workers[J]. Annals of Work Exposures and Health, 2017, 61(7): 883-901.
47	KOO K, PARK Y, CHOE J, et al. The application of microencapsulated phase-change materials to nylon fabric using direct dual coating method[J]. Journal of Applied Polymer Science, 2008, 108(4): 2337-2344.
48	SHIN Y, YOO D I, SON K. Development of thermoregulating textile materials with microencapsulated phase change materials (PCM). Ⅱ. Preparation and application of PCM microcapsules[J]. Journal of Applied Polymer Science, 2005, 96(6): 2005-2010.
49	KIM J, CHO G. Thermal storage/release, durability, and temperature sensing properties of thermostatic fabrics treated with octadecane-containing microcapsules[J]. Textile Research Journal, 2002, 72(12): 1093-1098.
50	SUN Y L, WANG R, LIU X, et al. Design of a novel multilayer low-temperature protection composite based on phase change microcapsules[J]. Journal of Applied Polymer Science, 2019, 136(20): 47534.
51	EL-KASHOUTI M, ELHADAD S, ABDEL-ZAHER K. Printing technology on textile fibers: review[J]. Journal of Textiles, Coloration and Polymer Science, 2019, 16(2): 129-138.
52	周岚, 刘国金, 张国庆, 等. 一种蓄热调温喷印液及数码喷印制备蓄热调温纺织品的方法: CN110004729A[P]. 2019-07-12.
	ZHOU Lan, LIU Guojin, ZHANG Guoqing, et al. A method for preparing temperature-regulating printing fluid and temperature-regulating textiles by digital printing: CN110004729A[P]. 2019-07-12.
53	CHOI K, CHO G, KIM P, et al. Thermal storage/release and mechanical properties of phase change materials on polyester fabrics[J]. Textile Research Journal, 2004, 74(4): 292-296.
54	NEJMAN A, CIEŚLAK M, GAJDZICKI B, et al. Methods of PCM microcapsules application and the thermal properties of modified knitted fabric[J]. Thermochimica Acta, 2014, 589: 158-163.
55	CHOI K, CHO G. Development of phase change materials treated thermostatic fabric by screen printing method[J]. Research Journal of Textile and Apparel, 2006, 10(2): 19-24.
56	SHIN Y, SON K, YOO D I. Development of natural dyed textiles with thermo-regulating properties[J]. Thermochimica Acta, 2010, 511(1/2): 1-7.
57	DEMIRBAĞ S, AKSOY S A. Encapsulation of phase change materials by complex coacervation to improve thermal performances and flame retardant properties of the cotton fabrics[J]. Fibers and Polymers, 2016, 17(3): 408-417.
58	SHIN Y, YOO D I, SON K. Development of thermoregulating textile materials with microencapsulated phase change materials (PCM). Ⅳ. Performance properties and hand of fabrics treated with PCM microcapsules[J]. Journal of Applied Polymer Science, 2005, 97(3): 910-915.
59	KARTHIKEYAN M, RAMACHANDRAN T, SUNDARAM O S. Nanoencapsulated phase change materials based on polyethylene glycol for creating thermoregulating cotton[J]. Journal of Industrial Textiles, 2014, 44(1): 130-146.
60	SALAÜN F, DEVAUX E, BOURBIGOT S, et al. Thermoregulating response of cotton fabric containing microencapsulated phase change materials[J]. Thermochimica Acta, 2010, 506(1/2): 82-93.
61	SHAHID A, MIAH S, RAHIM A. Thermal and breathability management of microencapsulated phase change material (MPCM) incorporated jute fabric[J]. Journal of Engineered Fibers and Fabrics, 2021, 16: 155892502110295.
62	SHI H F, LI J H, JIN Y M, et al. Preparation and properties of poly(vinyl alcohol)-g-octadecanol copolymers based solid-solid phase change materials[J]. Materials Chemistry and Physics, 2011, 131(1/2): 108-112.
63	KUMAR A, KULKARNI P S, SAMUI A B. Polyethylene glycol grafted cotton as phase change polymer[J]. Cellulose, 2014, 21(1): 685-696.
64	BENMOUSSA D, MOLNAR K, HANNACHE H, et al. Novel thermo-regulating comfort textile based on poly(allyl ethylene diamine)/n-hexadecane microcapsules grafted onto cotton fabric[J]. Advances in Polymer Technology, 2018, 37(2): 419-428.
65	XIONG R, GRANT A M, MA R L, et al. Naturally-derived biopolymer nanocomposites: interfacial design, properties and emerging applications[J]. Materials Science and Engineering R: Reports, 2018, 125: 1-41.
66	QIAN Y Q, HAN N, ZHANG Z X, et al. Enhanced thermal-to-flexible phase change materials based on cellulose/modified graphene composites for thermal management of solar energy[J]. ACS Applied Materials & Interfaces, 2019, 11(49): 45832-45843.

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