Research progress on the preparation method and application of zinc stannate nanomaterials

doi:10.16085/j.issn.1000-6613.2021-1595

Abstract

Abstract:

Zinc stannate has gradually attracted the attention of scientific researchers in recent years due to its high electron mobility, stability, high electrical conductivity, excellent adsorption properties, optical properties, and flame and smoke suppression properties. This paper presentes the research progress on the preparation methods of zinc stannate nanoparticles (hydrothermal, chemical precipitation, solid-phase chemical synthesis, microwave synthesis, sol-gel method, template method, etc.), morphology and structure (granular, cubic, spherical, octahedral, nano-rod, flake, nano-flower, etc.), particle sizes and their applications in different fields (lithium battery anode materials, gas-sensitive materials, electrical contact materials, DSSC anodes, photocatalysis, flame retardant, etc.). The principles, preparation conditions and product properties of Zn₂SnO₄ nanoparticles using different tin compounds and different methods are analyzed, and the advantages and disadvantages of each preparation method and the formation mechanism of different structures in each preparation method are pointed out, as well as how the different structures affected the relevant properties of Zn₂SnO₄. The article indicates that how efficient and controllable preparation of zinc stannate with specific morphology and grain size is a future direction for zinc stannate nanomaterials.

Key words: zinc stannate, nanomaterial, preparation method, application, topography

摘要：

锡酸锌由于具有较高的电子迁移率、稳定性、高电导率，优异的吸附性能、光学性能和阻燃抑烟性能等特性，近年来逐渐受到科研人员的关注。本文介绍了锡酸锌纳米颗粒的制备方法（水热法、化学沉淀法、固相化学合成法、微波合成法、溶胶-凝胶法、模板法等）、形貌结构（颗粒状、立方体、球形、八面体、纳米棒、片状、纳米花状等）、粒径及其在不同领域（锂电负极材料、气敏材料、电触头材料、DSSC阳极、光催化、阻燃等）的应用研究进展，分析了利用不同锡化合物原料、不同方法制备锡酸锌纳米颗粒的原理、制备条件和产品特性，指出了每种制备方法的优缺点及每种制备方法中不同结构的形成机理，以及不同结构是如何对Zn₂SnO₄相关性能产生影响的。文章指出如何高效可控制备特定形貌和晶粒尺寸的锡酸锌是锡酸锌纳米材料未来的发展方向。

关键词: 锡酸锌, 纳米材料, 制备方法, 应用, 形貌结构

CLC Number:

TQ115

MA Dianpu, LI Jun, QIN Deqing, YUAN Yingjie, PAN Fei, FU Zewei. Research progress on the preparation method and application of zinc stannate nanomaterials[J]. Chemical Industry and Engineering Progress, 2022, 41(6): 3113-3126.

马殿普, 李俊, 覃德清, 袁英杰, 潘飞, 符泽卫. 锡酸锌纳米材料的制备方法及应用研究进展[J]. 化工进展, 2022, 41(6): 3113-3126.

Figures/Tables 18

References 61

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形貌	气体	工作温度/℃	气体浓度/10^-6	灵敏度	响应恢复时间/s	检测限/10^-6	文献
空心八面体	H₂S	260	50	46.0	—	1	［38］
纳米立方体	正丁胺	350	400	102.2	—	30	［39］
纳米薄膜	NO₂	200	200	2.66	25/326（200×10^-6）	50	［40］
纳米花状	LPG	室温	5000	2.5	180/240（5000×10^-6）	—	［41］
齿状纳米线	乙醇	—	200	27	7/8	1	［42］
纳米粒子	乙醇	180	100	46.5	—	5	［43］
纳米球	乙醇	180	50	23.4	—	5	［44］
八面体	TEA	200	100	37	2/17（100×10^-6）	5	［45］
空心立方体	丙酮	260	200	141.7	—	10	［46］
空心球	丙酮	200	200	153	7/9（200×10^-6）	20	［47］

形貌	气体	工作温度/℃	气体浓度/10^-6	灵敏度	响应恢复时间/s	检测限/10^-6	文献
空心八面体	H₂S	260	50	46.0	—	1	［38］
纳米立方体	正丁胺	350	400	102.2	—	30	［39］
纳米薄膜	NO₂	200	200	2.66	25/326（200×10^-6）	50	［40］
纳米花状	LPG	室温	5000	2.5	180/240（5000×10^-6）	—	［41］
齿状纳米线	乙醇	—	200	27	7/8	1	［42］
纳米粒子	乙醇	180	100	46.5	—	5	［43］
纳米球	乙醇	180	50	23.4	—	5	［44］
八面体	TEA	200	100	37	2/17（100×10^-6）	5	［45］
空心立方体	丙酮	260	200	141.7	—	10	［46］
空心球	丙酮	200	200	153	7/9（200×10^-6）	20	［47］

阻燃剂添加量 /份	极限氧指数 /%	烟密度等级 /%	最大烟密度等级 /%	残炭率 /%
0	28.7	90.5	100.0	20.8
5	33.1	88.3	95.7	23.4
10	34.9	85.8	93.7	26.7
15	36.0	86.2	93.2	29.7
20	36.4	86.4	94.5	29.4

阻燃剂添加量 /份	极限氧指数 /%	烟密度等级 /%	最大烟密度等级 /%	残炭率 /%
0	28.7	90.5	100.0	20.8
5	33.1	88.3	95.7	23.4
10	34.9	85.8	93.7	26.7
15	36.0	86.2	93.2	29.7
20	36.4	86.4	94.5	29.4

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[2]	YIN Xinyu, PI Pihui, WEN Xiufang, QIAN Yu. Application of special wettability materials for anti-hydrate-nucleation and anti-hydrate-adhesion in oil and gas pipelines [J]. Chemical Industry and Engineering Progress, 2023, 42(8): 4076-4092.
[3]	MAO Shanjun, WANG Zhe, WANG Yong. Group recognition hydrogenation: From concept to application [J]. Chemical Industry and Engineering Progress, 2023, 42(8): 3917-3922.
[4]	XU Peiyao, CHEN Biaoqi, KANKALA Ranjith Kumar, WANG Shibin, CHEN Aizheng. Research progress of nanomaterials for synergistic ferroptosis anticancer therapy [J]. Chemical Industry and Engineering Progress, 2023, 42(7): 3684-3694.
[5]	SUN Xudong, ZHAO Yuying, LI Shirui, WANG Qi, LI Xiaojian, ZHANG Bo. Textual quantitative analysis on China’s local hydrogen energy development policies [J]. Chemical Industry and Engineering Progress, 2023, 42(7): 3478-3488.
[6]	XU Chunshu, YAO Qingda, LIANG Yongxian, ZHOU Hualong. Effects of graphene oxide/carbon nanotubes on the properties of several typical polymer materials [J]. Chemical Industry and Engineering Progress, 2023, 42(6): 3012-3028.
[7]	XU Guobin, LIU Honghao, LI Jie, GUO Jiaqi, WANG Qi. Preparation and properties of ZnO QDs water-based inkjet fluorescent ink [J]. Chemical Industry and Engineering Progress, 2023, 42(6): 3114-3122.
[8]	JIN Yong, CHENG Yi, BAI Dingrong, ZHANG Chenxi, WEI Fei. Fluidization research and development in China [J]. Chemical Industry and Engineering Progress, 2023, 42(6): 2761-2780.
[9]	CHEN Yixin, ZHEN Yaoyao, CHEN Ruihao, WU Jiwei, PAN Limei, YAO Chong, LUO Jie, LU Chunshan, FENG Feng, WANG Qingtao, ZHANG Qunfeng, LI Xiaonian. Preparation of platinum based nanocatalysts and their recent progress in hydrogenation [J]. Chemical Industry and Engineering Progress, 2023, 42(6): 2904-2915.
[10]	ZHANG Chenyu, WANG Ning, XU Hongtao, LUO Zhuqing. Performance evaluation of the multiple layer latent heat thermal energy storage unit combined with nanoparticle for heat transfer enhancement [J]. Chemical Industry and Engineering Progress, 2023, 42(5): 2332-2342.
[11]	CHEN Shaohua, WANG Yihua, HU Qiangfei, HU Kun, CHEN Li’ai, LI Jie. Research progress on detection of Cr(Ⅵ) by electrochemically modified electrode [J]. Chemical Industry and Engineering Progress, 2023, 42(5): 2429-2438.
[12]	YIN Ming, GUO Jin, PANG Jifeng, WU Pengfei, ZHENG Mingyuan. Deactivation mechanisms and stabilizing strategies for Cu based catalysts in reactions with hydrogen [J]. Chemical Industry and Engineering Progress, 2023, 42(4): 1860-1868.
[13]	GE Weitong, LIAO Yalong, LI Mingyuan, JI Guangxiong, XI Jiajun. Preparation and dechlorination kinetics of Pd-Fe/MWCNTs bimetallic catalyst [J]. Chemical Industry and Engineering Progress, 2023, 42(4): 1885-1894.
[14]	WAN Maohua, ZHANG Xiaohong, AN Xingye, LONG Yinying, LIU Liqin, GUAN Min, CHENG Zhengbai, CAO Haibing, LIU Hongbin. Research progress on the applications of MXene in the fields of biomass based energy storage nanomaterials [J]. Chemical Industry and Engineering Progress, 2023, 42(4): 1944-1960.
[15]	LI Jianxiong, GENG Shuang, HU Shujian, ZHOU Ming. Research progress on functional structure design and application of liposome delivery system [J]. Chemical Industry and Engineering Progress, 2023, 42(4): 2003-2012.