Research progress of MOFs-based materials in electrochemical energy storage

doi:10.16085/j.issn.1000-6613.2017-0926

Abstract

Abstract: Metal organic frameworks(MOFs) have attracted great attention because of their high specific surface area, adjustable pore structure and diverse composition, and the applications of MOFs have great prospects in various fields, especially for electrochemical energy storage in which great progress has made. This article summarizes the application of MOFs based materials in the field of electrochemical energy storage for lithium-sulfur batteries, lithium-ion batteries and supercapacitors in recent years. The mechanism of MOFs and their composites as host of lithium-sulfur battery cathode was introduced in detail. The physical encapsulation and chemical coordination of MOFs on active substances were discussed. In addition, it described the improved battery performance when the MOFs derived carbon material with unique pore structure, strong conductivity and rich active sites was used as the electrode material. Finally, the MOFs based materials in electrochemical energy storage is prospected and the control of heteroatoms and the design of the channels in the MOFs-based materials are thought as the focus of future research.

Key words: metal organic frameworks, complexes, composite, electrochemistry, electrode material

摘要： 金属有机骨架材料（MOFs）由于其高比表面积、可调孔结构以及多样的组成等引起了学者们的极大关注，尤其在电化学储能领域取得了较大的研究进展。本文综述了近几年MOFs基材料在锂硫电池、锂离子电池和超级电容器等电化学储能领域中的应用。详细介绍了MOFs及其复合材料作为锂硫电池正极载体时与活性物质的作用机理，探讨了MOFs对活性物质硫的物理封装和化学配位作用。此外，阐述了MOFs衍生碳材料因独特孔结构、较强导电性和丰富活性位点等作为电极材料时对电池性能的提升。最后对MOFs基材料在电化学储能中的研究前景作出了展望，指出MOFs基材料中杂原子比例的控制和孔道设计是未来研究的重点。

关键词: 金属有机骨架, 配合物, 复合材料, 电化学, 电极材料

CLC Number:

CHEN Dan, YANG Rong, ZHANG Weihua, LI Runqiu, ZHU Xuyang, LU Leilei. Research progress of MOFs-based materials in electrochemical energy storage[J]. Chemical Industry and Engineering Progress, 2018, 37(02): 628-636.

陈丹, 杨蓉, 张卫华, 李润秋, 朱序阳, 路蕾蕾. 有机金属骨架材料在电化学储能领域中的研究进展[J]. 化工进展, 2018, 37(02): 628-636.

References

[1] LU W, WEI Z, GU Z Y, et al. Tuning the structure and function of metal-organic frameworks via linker design[J]. Chemical Society Reviews, 2014, 43(16):5561-5593.
[2] SHIMIZU G K. Metal-organic frameworks:model, make, measure[J]. Nature Chemistry, 2010, 2(11):909-911.
[3] ROSSEINSKY M J. Metal-organic frameworks:enlightened pores[J]. Nature Material, 2010, 9(8):609-610.
[4] JANIAK C, VIETH J K. MOFs, MILs and more:concepts, properties and applications for porous coordination networks(PCNs)[J]. New Journal of Chemistry, 2010, 42(3):2366-2388.
[5] 刘淑芝,赵福临,郭齐,等.金属有机骨架MIL-101的合成、改性及在催化反应中的应用进展[J].化工进展, 2017, 36(3):918-925. LIU S Z, ZHAO F L, GUO Q, et al. Progress in synthesis, modification and catalytic application of metal-organic frameworks MIL-101[J]. Chemical Industry and Engineering Progress, 2017, 36(3):918-925.
[6] DEY C, KUNDU T, BISWAL B P, et al. Cheminform abstract:crystalline metal-organic frameworks(MOFs):synthesis, structure and function[J]. Acta Crystallographica, 2014, 70(1):3-10.
[7] 李小娟,何长发,黄斌,等.金属有机骨架材料吸附去除环境污染物的进展[J].化工进展, 2016, 35(2):586-594. LI X J, HE C F, HUANG B, et al. Progress in the applications of metal-organic frameworks in adsorption removal of hazardous materials[J]. Chemical Industry and Engineering Progress, 2016, 35(2):586-594.
[8] 杨江峰,欧阳坤,陈杨,等.柔性MOFs材料Cu(BDC)的氨气吸附及可逆转化性能[J].化工学报, 2017, 68(1):418-423. YANG J F, OUYANG K, CHEN Y, et al. NH₃ adsorption on flexy reversible metal-organic frameworks Cu(BDC)[J]. CIESC Journal, 2017, 68(1):418-423.
[9] WANG Z, SEZEN H, LIU J, et al. Tunable coordinative defects in UHM-3 surface-mounted MOFs for gas adsorption and separation:a combined experimental and theoretical study[J]. Microporous & Mesoporous Materials, 2015, 207:53-60.
[10] KE F, QIU L G, ZHU J. Fe₃O₄@MOF core-shell magnetic microspheres as excellent catalysts for the Claisen-Schmidt condensation reaction[J]. Nanoscale, 2014, 6(3):1596-1601.
[11] CHOWDHURY M A. Metal-organic frameworks for biomedical applications in drug delivery, and as MRI contrast agents[J]. Journal of Biomedical Materials Research Part A, 2017, 105A:1184-1194.
[12] 周健,谢林华,豆义波,等. MOFs基材料在超级电容器中的应用[J].化工进展, 2016, 35(9):2830-2838. ZHOU J, XIE L H, DOU Y B, et al. MOFs-based materials for supercapacitor[J]. Chemical Industry and Engineering Progress, 2016, 35(9):2830-2838.
[13] 杨蓉, 邓坤发, 刘晓艳, 等. 锂硫电池正极复合材料研究现状[J]. 化工进展, 2015, 34(5):1340-1344. YANG R, DENG K F, LIU X Y, et al. Recent progress of sulfur composites as cathode materials for lithium sulfur batteries[J]. Chemical Industry and Engineering Progress, 2015, 34(5):1340-1344.
[14] ZHANG S S. Liquid electrolyte lithium-sulfur battery:fundamental chemistry, problems, and solutions[J]. Journal of Power Sources, 2013, 231(2):153-162.
[15] SON Y, LEE J, SON Y, et al. Recent advances in lithium-sulfide cathode materials and their use in lithium-sulfur batteries[J]. Advanced Energy Materials, 2015, 5(16):1-14.
[16] ZHENG J, TIAN J, WU D, et al. Lewis acid-base interactions between polysulfides and metal organic framework in lithium sulfur batteries[J]. Nano Letters, 2014, 14(5):2345-2352.
[17] WANG Z, DOU Z, CUI Y, et al. Sulfur encapsulated ZIF-8 as cathode material for lithium-sulfur battery with improved cyclability[J]. Microporous & Mesoporous Materials, 2014, 185(2):92-96.
[18] WANG Z, WANG B, YANG Y, et al. Mixed-metal-organic framework with effective lewis acidic sites for sulfur confinement in high-performance lithium-sulfur batteries[J]. ACS Applied Materials & Interfaces, 2015, 7(37):20999-21021.
[19] LIU F, FAN F T, LU Y C, et al. Research progress on photocatalytic degradation of organic pollutants by graphene/TiO₂ composite materials[J]. CIESC Journal, 2016, 67(5):1635-1643.
[20] 肖淑娟,于守武,谭小耀.石墨烯类材料的应用及研究进展[J].化工进展, 2015, 34(5):1345-1348. XIAO S J, YU S W, TAN X Y. Research progress of graphene-based composite electrodes in asymmetric supercapacitors[J]. Chemical Industry and Engineering Progress, 2015, 34(5):1345-1348.
[21] BAO W, ZHANG Z, QU Y, et al. Confine sulfur in mesoporous metal-organic framework@reduced graphene oxide for lithium sulfur battery[J]. Journal of Alloys & Compounds, 2014, 582(2):334-340.
[22] LI Z, LI C, GE X, et al. Reduced graphene oxide wrapped MOFs-derived cobalt-doped porous carbon polyhedrons as sulfur immobilizers as cathodes for high performance lithium sulfur batteries[J]. Nano Energy, 2016, 23:15-26.
[23] CHEN R, ZHAO T, TINA T, et al. Graphene-wrapped sulfur/metal organic framework-derived microporous carbon composite for lithium sulfur batteries[J]. APL Materials, 2014, 2(12).DOI:10.1063/1. 4901751.
[24] NAGARATHINAM M, SARAVANAN K, PHUA E J, et al. Redox-active metal-centered oxalato phosphate open framework cathode materials for lithium-ion batteries[J]. Angewandte Chemie International Edition, 2012, 51(24):5866-5870.
[25] SHAHYLHAMEED A, NAGARATHINAM M, SCHREYER M, et al. A layered oxalatophosphate framework as a cathode material for lithium-ion batteries[J]. Journal of Materials Chemistry A, 2013, 1(18):5721-5726.
[26] LI X, CHENG F, ZHANG S, et al. Shape-controlled synthesis and lithium-storage study of metal-organic frameworks Zn₄O (1,3,5-benzenetribenzoate) 2[J]. Journal of Power Sources, 2006, 160(1):542-547.
[27] SARAVANAN K, NAGARATHINAM M, BALAYA P, et al. Lithium storage in a metal organic framework with diamondoid topology a case study on metal formates[J]. Journal of Materials Chemistry, 2010, 20:8329-8335.
[28] JIN Y, ZHAO C, SUN Z, et al. Facile synthesis of Fe-MOF/RGO and its application as a high performance anode in lithium-ion batteries[J]. RSC Advances, 2016, 6(36):30763-30768.
[29] YANG X, LIU L, YUAN R, et al. Self-assembly of metal-organic frameworks and graphene oxide as precursors for lithium-ion battery applications[J]. Journal of Nanoparticle Research, 2016, 18(313):1-8.
[30] KE F S, WU Y S, DENG H. Metal-organic frameworks for lithium-ion batteries and supercapacitors[J]. Journal of Solid State Chemistry, 2014, 223:109-121.
[31] YU A, CHEN Z, MARIC R, et al. Electrochemical supercapacitors for energy storage and delivery:advanced materials, technologies and applications[J]. Applied Energy, 2015, 153:1-2.
[32] WANG G, ZHANG L, ZHANG J. A review of electrode materials for electrochemical supercapacitors[J].Chemical Society Reviews,2012, 41(2):797-828.
[33] DÍAZ R, ORCAJO M G, BOTAS J A, et al. Co8-MOF-5 as electrode for supercapacitors[J]. Materials Letters, 2012, 68:126-128.
[34] LEE D Y, SHINDE D V, KIM E K, et al. Supercapacitive property of metal-organic-frameworks with different pore dimensions and morphology[J]. Microporous & Mesoporous Materials, 2013, 171(10):53-57.
[35] LIAO C M, ZUO Y K, ZHANG W, et al. Electrochemical performance of metal-organic frameworks synthesized by a solvothermal method for supercapacitors[J]. Russ. J. Electrochem., 2012, 49(10):983-986.
[36] LI W H, DING K, TIAN H R, et al. Supercapacitors:conductive metal organic framework nanowire array electrodes for high performance solid-state supercapacitors[J]. Advanced Functional Materials, 2017, 27(27).
[37] GUO Z P, ZHANG C F, WU H B, et al. Confining sulfur in double-shelled hollow carbon spheres for lithium-sulfur batteries[J]. Angewandte Chemie, 2012, 124(38):9730-9733.
[38] GENG X Y, RAO M M, LI X P, et al. Highly dispersed sulfur in multi-walled carbon nanotubes for lithium-sulfur battery[J]. Journal of Solid State Electrochemistry, 2013, 17(4):987-992.
[39] HUANG J Q, LIU X F, ZHANG Q, et al. Entrapment of sulfur in hierarchical porous graphene for lithium-sulfur batteries with high rate performance from-40 to 60℃[J]. Nano Energy, 2013, 2(2):314-321.
[40] 孟宪斌,高秋明.由含铝金属有机骨架材料制备的多孔碳在锂硫电池中的应用[J].高等学校化学学报, 2014, 35(8):1715-1719. MENG X B, GAO Q M. Porous carbon from carbonized metal-organic frameworks for lithium-sulfur batteries[J]. Chemical Journal of Chinese Universities, 2014, 35(8):1715-1719.
[41] LI X, SUN Q, LIU J, et al. Tunable porous structure of metal organic framework derived carbon and the application in lithium-sulfur batteries[J]. Journal of Power Sources, 2016, 302:174-179.
[42] HE J, CHEN Y, LV W, et al. From metal-organic framework to Li₂S@C-Co-N nanoporous architecture:a high-capacity cathode for lithium-sulfur batteries[J]. ACS Nano, 2016, 10(12):10981-10987.
[43] WANG M, YANG H, ZHOU X, et al. Rational design of SnO₂@C nanocomposites for lithium ion batteries by utilizing adsorption properties of MOFs[J]. Chemical Communications, 2015, 52(4):717-720.
[44] YANG D-H, ZHOU X L, ZHONG M, et al. A robust hybrid of SnO₂ nanoparticles sheathed by N-doped carbon derived from ZIF-8 as anodes for Li-ion batteries[J]. ChemNanoMat, 2017, 3(4):252-258.
[45] CHEN Y, ZHENG L, FU Y, et al. MOF-derived Fe₃O₄/carbon octahedral nanostructures with enhanced performance as anode materials for lithium-ion batteries[J]. RSC Advances, 2016, 6(89):85917-85923.
[46] LIU J, WU C, XIAO D, et al. MOF-derived hollow Co₉S₈ nanoparticles embedded in graphitic carbon nanocages with superior Li-ion storage[J]. Small, 2016, 12(17):2354-2366.
[47] YIN D, HUANG G, SUN Q, et al. RGO/Co₃O₄ composites prepared using GO-MOFs as precursor for advanced lithium-ion batteries and supercapacitors electrodes[J]. Electrochimica Acta, 2016, 215:410-419.
[48] BAO W, MONDAL A K, XU J, et al. 3D hybrid-porous carbon derived from carbonization of metal organic frameworks for high performance supercapacitors[J]. Journal of Power Sources, 2016, 325:286-291.
[49] YANG J Q, DUAN X C, GUO W, et al. Electrochemical performances investigation of NiS/rGO composite as electrode material for supercapacitors[J]. Nano Energy, 2014, 5(2):74-81.
[50] LANG X, HIRATA A, FUJITA T, et al. Nanoporous metal/oxide hybrid electrodes for electrochemical supercapacitors[J]. Nature Nanotechnology, 2011, 6(4):232-236.
[51] LIU Y, XU J, LIU S. Porous carbon nanosheets derived from Al-based MOFs for supercapacitors[J]. Microporous & Mesoporous Materials, 2016, 236:94-99.
[52] YI H, WANG H, JING Y, et al. Asymmetric supercapacitors based on carbon nanotubes@NiO ultrathin nanosheets core-shell composites and MOF-derived porous carbon polyhedrons with super-long cycle life[J]. Journal of Power Sources, 2015, 285:281-290.