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Research progress of inverse CeO2/CuO catalyst on low-temperature oxidation of CO in H2 rich gas

WANG Yan,ZHANG Wenli,WANG Qi,WANG Pengzhan,SU Haiquan,ZENG Shanghong   

  1. Inner Mongolia Key Laboratory of Chemistry and Physics of Rare Earth Materials,School of Chemistry and Chemical Engineering,Inner Mongolia University,Hohhot 010021,Inner Mongolia,China
  • Online:2011-06-05 Published:2011-06-05

富H2中优先氧化CO的CeO2/CuO催化剂的研究进展

王 艳,张文丽,王 奇,王鹏展,苏海全,曾尚红   

  1. 内蒙古大学化学化工学院,内蒙古自治区稀土材料化学与物理重点实验室,内蒙古 呼和浩特 010021

Abstract:

An inverse CeO2/CuO catalyst is a novel catalyst for low-temperature oxidation of CO in H2 rich gaswith higher activity than traditional CuO/CeO2 catalysts. This paper summarizes the preparation methods of CeO2/CuO catalystsincluding inverse microemulsion and impregnation methodsand speculates the influence of size effect and interfacial effect on the performance of CeO2/CuO catalysts. Moreoverit presents the development of CeO2/CuO catalysts in the futurein order to look for the appropriate size of CuO and CeO2 particles and improve selectivity and stability of CeO2/CuO catalysts for CO preferential oxidation.

摘要:

逆负载型CeO2/CuO催化剂是富H2中优先氧化CO的一种新型催化剂,其活性较传统CuO - CeO2催化剂高。本文综述了CeO2/CuO催化剂的制备方法,着重介绍了逆微乳液法和浸渍法,CeO2/CuO催化剂的尺寸效应和界面效应对催化剂性能的影响作了大胆的猜测,对未来CeO2/CuO催化剂的研究趋势提出了建议,旨在找到CuOCeO2颗粒的最优组合,提高催化剂的选择性和稳定性。

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