Abstract: The developments of heteropolyacid (salt) catalysts and their applications in organic synthesis are reviewed with focuses on the corelation between molecular structure and catalytic characteristics. Heteropolyacids (salts) can be considered as excellent green catalysts and have great potentials in organic synthesis.

摘要： 综述了近年来杂多酸（盐）催化剂的研究进展及其在催化有机合成中的应用，着重介绍了几种类型杂多酸（盐）的分子结构与催化特性。认为杂多酸（盐）是性能优异的环境友好型催化剂，通过分子水平上研究其组成、结构与性能的关系，可以设计出多种新型结构的催化剂，在催化有机合成反应中表现出潜在的巨大应用价值。