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Preparation and evaluation of C2 front-end hydrogenation catalyst

CHE Chunxia,TAN Duping,ZHAO Yurong,JING Xilin,LIANG Kun,CHANG Xiaoxin,XIE Wei,JIA Huiqing   

  1. Lanzhou Center of Petrochemical Research Institute,PetroChina Company Limited
  • Online:2010-01-05 Published:2010-01-05

碳二前加氢催化剂的应用

车春霞,谭都平,赵育榕,景喜林,梁 琨,常晓昕,颉 伟,贾慧青   

  1. 中国石油化工研究院兰州化工研究中心

Abstract: Catalyst for C2 front-end hydrogenation was prepared via equality design methodology,and the composition and preparation technics were optimized. The prepared catalyst was compared with the commercially available catalyst in a simulating industry unit for 1000 h. It was proved that the activity of the prepared catalyst is slightly lower than that of the commercial one,while the prepared catalyst has a better selectivity. XPS analysis revealed that the prepared catalyst has a stronger effect with Pd-Ag alloy,and XRF analysis illustrated that the prepared catalyst has a less active composition on the catalyst surface.

摘要: 采用均匀设计方法,进行了碳二前加氢催化剂的制备,确定了催化剂的最佳配方和制备工艺。1000 h工业侧线对比评价结果表明,自制催化剂活性稍低于市售催化剂,选择性高于市售催化剂,两种催化剂总体性能相当。X光电子能谱分析表明,自制催化剂钯银合金作用更为明显,X荧光光谱分析表明表面活性组分含量低于市售催化剂。

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