Abstract: Chlorotoluene was synthesised by anodic oxidation using netted titanium as the anode，netted nickel as the cathode，saturated NaCl solution as the anode electrolyte and an ion exchange membrane as a separator．The selections of reactive condition such as mass fraction of electrolyte，current density，electrolyte temperature and reaction time are discussed．The optimized reaction conditions were found to be 25％ NaCl as the anode electrolyte，10％ NaOH as the cathode electrolyte，10—15A／dm2 of current density and the reaction temperature as 25 ℃，under which chlorotoluene yield reached to 55.5％ with a current efficiancy of 51.5％.

摘要： 以钛网为阳极，镍网为阴极，饱和的NaCl溶液为阳极电解质，应用离子交换膜通过阳极氧化甲苯的方法合成氯甲苯。讨论了阳极电解质质量分数、电流密度、电解液温度、反应时间等反应条件的选择。结果表明：在反应温度25 ℃，阳极、阴极电解液分别为25％NaCl和10％NaOH溶液，电流密度为10～15 A/dm2条件下电解，并在4.5 h左右结束反应，氯甲苯的产率最高，可达55.5％，电流效率为51.5％。