Chemical Industry and Engineering Progree

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Progress of fixation and utilization of CO2 using ionic liquids

YAO Shumei,WANG Xiaogang,ZHANG Hui,LIU Zongyao   

  1. Institute of Environmental Protection,Scivic Engineering Corporation; Sichuan Nuclear Industry Geology Institute
  • Online:2008-05-05 Published:2008-05-05

离子液体固定化利用CO2研究进展

姚淑梅,王晓刚,张 辉,刘宗耀   

  1. 机械工业第四设计研究院环保所; 四川省核工业地质调查院

Abstract: The development and characteristics of ionic liquids (ILs) in recent decades are reviewed. The mechanism for remarkable solubility of CO2 in ionic liquids and the monte carlo simulations for predicting the atomic force fields of absorptions in ILs are also summarized. The significant advantages of fixation and utilization of CO2 with ILs as absorbent,catalyst or promoter used in organic reaction,catalyzed reaction,electrochemical reaction,supported ionic liquid membranes over the conventional absorbents and the catalytic systems without ILs are discussed. Furthermore,the proposal for solving existing problems and the prospect of its application are presented.

摘要: 介绍了近几十年来离子液体的发展历程及其特点。阐述了CO2在离子液体中高溶度机制,对CO2 在离子液体中吸收的原子力场进行了计算机模拟预测。评述分析了离子液体作为吸收剂或助剂或催化剂,在有机反应、催化反应、电化学反应、支撑液膜中固定化利用CO2时,与传统吸收剂和没有离子液体的催化体系相比具有诸多优点,并对尚存在的问题提出了建议,并对前景做了展望。

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