Abstract: The telomerization reaction kinetics of 1,1,1,3- tetrachloropropane synthesis using tetrachloromethane and ethylene as raw materials was studied. The influence of catalyst concentration，pressure，temperature and other factors on the reaction was investigated by，using phosphate ester，powdered iron and FeCl3 as catalysts. It was found that the telomerization reaction was of first order and activation energy was 59.6 kJ/mol. A reaction kinetic equation was presented as follows：－rA= 6.566×107exp(－5.96×104／RT)CA0(1－xA)。

摘要： 研究了以四氯化碳和乙烯为原料合成1,1,1,3-四氯丙烷的调聚反应动力学。考察了以烷基磷酸酯、氯化铁、铁粉为催化剂时，催化剂浓度、压力、温度对反应的影响，结果表明该反应在1.0 MPa、100～115 ℃下为一级反应，表观活化能为59.6 kJ/mol，对四氯化碳消耗速率的动力学方程为：－rA= 6.566×107exp(－5.96×104/RT)CA0(1－xA)。