Abstract: The study and application of microwave technique in bulk polymerization，solution polymerization，emulsion polymerization and functional polymer polymerization are reviewed. As a new and effective way of heating，microwave technology can reduce reaction time and energy consumptions，increase reaction rates，yields and selectivities for various chemical reactions. It shows a picture of the future development in green synthesis of polymer.

摘要： 综述了微波技术在高分子本体聚合、溶液聚合、乳液聚合和功能高分子聚合中的应用。指出微波技术具有大大降低聚合反应的时间和能耗，提高聚合反应速率、收率和选择性的特性，将在高分子的绿色化学合成方面发挥重要作用。