Abstract: The new development and current of supercritical fluids in non-catalytic reaction， which include supercritical water, methanol, carbon dioxide, is summarized and analyzed from a new point of view according to the characteristic of supercritical fluids—solvent and catalyst. Meanwhile, they are compared with traditional catalytic reaction. The prospect and research progress are presented.

摘要： 依据超临界流体自身的特点，在反应中既作为溶剂又作为催化剂，从一个全新的角度介绍了超临界流体在非催化反应中的新成果、新动向。主要阐述了包括超临界水、甲醇、二氧化碳在有机反应中的应用，并与传统催化反应进行了比较，同时探讨了国内外研究现状、应用前景和发展趋势。