Preparation and properties of CS/SA composite gel membrane based on blueberry anthocyanins

doi:10.16085/j.issn.1000-6613.2024-0663

Chemical Industry and Engineering Progress ›› 2025, Vol. 44 ›› Issue (6): 3550-3560.DOI: 10.16085/j.issn.1000-6613.2024-0663

• Materials science and technology • Previous Articles

Preparation and properties of CS/SA composite gel membrane based on blueberry anthocyanins

ZHANG Min¹^,²^,³^,⁴(), ZHAO Yamin¹^,²^,³^,⁴(), ZHANG Peichun¹^,²^,³^,⁴, ZHANG Bin¹^,²^,³^,⁴, QI Yanjiao¹^,²^,³^,⁴, ZHANG Hong¹^,²^,³^,⁴, CHEN Lihua¹^,²^,³^,⁴

^1.School of Chemical Engineering, Northwest Minzu University, Lanzhou 730124, Gansu, China
^2.Key Laboratory of Environment-Friendly Composites of the State Ethnic Affairs Commission, Northwest Minzu University, Lanzhou 730124, Gansu, China
^3.Gansu Provincial Biomass Function Composites Engineering Research Center, Northwest Minzu University, Lanzhou 730124, Gansu, China
^4.Key Laboratory for Utility of Environment-Friendly Composites and Biomass in Universities of Gansu Province, Northwest Minzu University, Lanzhou 730124, Gansu, China

Received:2024-04-19 Revised:2024-06-17 Online:2025-07-08 Published:2025-06-25
Contact: ZHAO Yamin

基于蓝莓花青素的CS/SA智能指示复合凝胶膜的制备及性能

张敏¹^,²^,³^,⁴(), 赵娅敏¹^,²^,³^,⁴(), 张沛春¹^,²^,³^,⁴, 张斌¹^,²^,³^,⁴, 齐燕姣¹^,²^,³^,⁴, 张宏¹^,²^,³^,⁴, 陈丽华¹^,²^,³^,⁴

^1.西北民族大学化工学院，甘肃兰州 730124
^2.西北民族大学环境友好复合材料国家民委重点实验室，甘肃兰州 730124
^3.西北民族大学甘肃省生物质功能复合材料工程研究中心，甘肃兰州 730124
^4.西北民族大学甘肃省高校环境友好复合材料及生物质利用重点实验室，甘肃兰州 730124

通讯作者: 赵娅敏
作者简介:张敏（1998—），女，硕士研究生，研究方向为复合材料的制备。E-mail：2550614342@qq.com。
基金资助:
中央高校基本科研业务费项目(31920240115);中央高校基本科研业务费项目(31920190079)

Abstract

Abstract:

Blueberry anthocyanins were utilized to prepare into freshness indicator films, which were made of chitosan and sodium alginate by solution casting method. The color changes of anthocyanins under different pH buffer solutions were analyzed, and the effects of different anthocyanin additions on the chitosan/sodium alginate composite film in terms of thickness, mechanical property, water content, solubility, water solubility, infrared spectroscopy, surface microstructure, light transmittance, contact angle and antioxidant activity. The experimental results showed that the indicator film exhibited the strongest antioxidant performance when the content of anthocyanin was 10mg, while its water content was the lowest. The best sensitivity was found when the added amount of anthocyanin was 50mg. It indicated from the experiments that the data of Fourier infrared spectroscopy and scanning electron microscopy showed that there was a good compatibility between the blueberry anthocyanin and the two membrane materials it was coupled with, and that it could enhance the affinity between the components. The performance and feasibility were analyzed under ambient conditions, and the color of the indicated membranes changed from red to dark green. The results of the study were aimed to provide reference for the application of anthocyanin smart indicator film in the specialty pork in Gansu region.

Key words: anthocyanin, chitosan, sodium alginate, composite gel membrane

摘要：

利用蓝莓花青素制备成食品新鲜度智能指示复合凝胶膜，本文以壳聚糖和海藻酸钠为材料，通过溶液浇铸法完成。通过分析花青素在不同pH缓冲溶液下的颜色变化，不同花青素添加量对壳聚糖/海藻酸钠复合凝胶膜在厚度、力学性能、含水量、溶胀度、水溶性、红外光谱、表面微观结构、透光率、接触角以及抗氧化活性等方面的影响，证实当花青素的含量为10mg时，复合凝胶膜表现出最强的抗氧化性能，同时其含水量最低；当花青素的添加量为50mg时，复合凝胶膜具有最佳的食品新鲜度指示的灵敏度。傅里叶红外光谱和扫描电镜的数据显示，蓝莓花青素与两种膜基质之间有很好的相容性，并且能够相互提升各组成部分之间的亲和力。在环境条件下，分析智能指示复合凝胶膜的性能和可行性，猪肉经过24h的储存，膜的颜色会从红色变成深绿色。研究结果旨在为花青素智能指示复合凝胶膜在甘肃地区特色猪肉中的应用提供参考。

关键词: 花青素, 壳聚糖, 海藻酸钠, 复合凝胶膜

CLC Number:

O636.9

ZHANG Min, ZHAO Yamin, ZHANG Peichun, ZHANG Bin, QI Yanjiao, ZHANG Hong, CHEN Lihua. Preparation and properties of CS/SA composite gel membrane based on blueberry anthocyanins[J]. Chemical Industry and Engineering Progress, 2025, 44(6): 3550-3560.

张敏, 赵娅敏, 张沛春, 张斌, 齐燕姣, 张宏, 陈丽华. 基于蓝莓花青素的CS/SA智能指示复合凝胶膜的制备及性能[J]. 化工进展, 2025, 44(6): 3550-3560.

Figures/Tables 17

References 31

[1]	DUTTA P K, YADAV Srasti, MEHROTRA G K. Modified chitosan films/coatings for active food packaging[M]//JAYAKUMAR R, PRABAHARAN M. Chitosan for biomaterials III. Cham: Springer International Publishing, 2021: 203-232.
[2]	GIANNAKAS Aris, SALMAS Constantinos, LEONTIOU Areti, et al. Novel LDPE/chitosan rosemary and melissa extract nanostructured active packaging films[J]. Nanomaterials, 2019, 9(8): 1105.
[3]	ASHRAFI Azam, JOKAR Maryam, MOHAMMADI NAFCHI Abdorreza. Preparation and characterization of biocomposite film based on chitosan and Kombucha tea as active food packaging[J]. International Journal of Biological Macromolecules, 2018, 108: 444-454.
[4]	NUNES Cláudia, COIMBRA Manuel A, FERREIRA Paula. Tailoring functional chitosan-based composites for food applications[J]. The Chemical Record, 2018, 18(7/8): 1138-1149.
[5]	Verónica CABAÑAS-ROMERO L, VALLS Cristina, VALENZUELA Susana V, et al. Bacterial cellulose-chitosan paper with antimicrobial and antioxidant activities[J]. Biomacromolecules, 2020, 21(4): 1568-1577.
[6]	SELLIMI Sabrine, YOUNES Islem, AYED Hanen BEN, et al. Structural, physicochemical and antioxidant properties of sodium alginate isolated from a Tunisian brown seaweed[J]. International Journal of Biological Macromolecules, 2015, 72: 1358-1367.
[7]	RAHMANI Bahareh, HOSSEINI Hedayat, KHANI Mohammadreza, et al. Development and characterisation of chitosan or alginate-coated low density polyethylene films containing Satureja hortensis extract[J]. International Journal of Biological Macromolecules, 2017, 105: 121-130.
[8]	Cristina BILBAO-SAINZ, CHIOU Bor-Sen, PUNOTAI Kaylin, et al. Layer-by-layer alginate and fungal chitosan based edible coatings applied to fruit bars[J]. Journal of Food Science, 2018, 83(7): 1880-1887.
[9]	GHOSH Susmita, SARKAR Tanmay, Arpita DAS, et al. Natural colorants from plant pigments and their encapsulation: An emerging window for the food industry[J]. LWT, 2022, 153: 112527.
[10]	冉锐敏, 王璐瑶, 何宾宾, 等. 纳米氧化锌/葡萄皮红改性大豆分离蛋白膜的制备与性能研究[J]. 农业工程学报, 2021, 37(14): 294-301.
	RAN Ruimin, WANG Luyao, HE Binbin, et al. Preparation and characterization of soy protein isolate films modified by ZnO nanoparticles and grape-skin red[J]. Transactions of the Chinese Society of Agricultural Engineering, 2021, 37(14): 294-301.
[11]	蒋光阳, 肖力源, 王章英, 等. 不同基材复配紫薯花青素制备智能指示膜及其应用[J]. 食品科学, 2019, 40(13): 267-273.
	JIANG Guangyang, XIAO Liyuan, WANG Zhangying, et al. Development and application of intelligent indicator films using blended film-forming solutions combined with purple sweet potato anthocyanins[J]. Food Science, 2019, 40(13): 267-273.
[12]	王文娇. 淀粉/琼脂-花青素pH响应型包装膜的制备及其性能研究[D]. 泰安: 山东农业大学, 2023.
	WANG Wenjiao. Preparation and properties of starch/agar-anthocyanin pH responsive packaging films[D]. Taian: Shandong Agricultural University, 2023.
[13]	吴琼. 壳聚糖/海藻酸钠复合保鲜膜的制备与应用研究[D]. 青岛: 中国海洋大学, 2014.
	WU Qiong. Study on preparation and application of edible fresh-keeping films based on chitosan and alginate[D]. Qingdao: Ocean University of China, 2014.
[14]	ZHOU Xi, ZONG Xinxiang, WANG Shanglong, et al. Emulsified blend film based on konjac glucomannan/carrageenan/camellia oil: Physical, structural, and water barrier properties[J]. Carbohydrate Polymers, 2021, 251: 117100.
[15]	ROMAINOR Ain Nadirah, CHIN Suk Fun, LIHAN Samuel. Antimicrobial starch-based film for food packaging application[J]. Starch - Stärke, 2022, 74(3/4): 2100207.
[16]	QU Wenjuan, XIONG Ting, WANG Bo, et al. The modification of pomegranate polyphenol with ultrasound improves mechanical, antioxidant, and antibacterial properties of tuna skin collagen-chitosan film[J]. Ultrasonics Sonochemistry, 2022, 85: 105992.
[17]	邹小波, 张俊俊, 石吉勇, 等. 基于玫瑰茄花青素的猪肉新鲜度智能指示膜研究[J]. 食品科学, 2017, 38(23): 243-248.
	ZOU Xiaobo, ZHANG Junjun, SHI Jiyong, et al. Development of intelligent indicator films based on Roselle anthocyanins for monitoring pork freshness[J]. Food Science, 2017, 38(23): 243-248.
[18]	贾代涛, 卢立新, 潘嘹, 等. 改性花青素涂覆聚丙烯新鲜度指示膜的制备与研究[J]. 功能材料, 2019, 50(6): 6211-6215.
	JIA Daitao, LU Lixin, PAN Liao, et al. Preparation and study of modified Roselle anthocyanin coated polypropylene freshness indicator film[J]. Journal of Functional Materials, 2019, 50(6): 6211-6215.
[19]	PERALTA Juliana, BITENCOURT-CERVI Camila M, MACIEL Vinicius B V, et al. Aqueous hibiscus extract as a potential natural pH indicator incorporated in natural polymeric films[J]. Food Packaging and Shelf Life, 2019, 19: 47-55.
[20]	NOGUEIRA Gislaine Ferreira, FAKHOURI Farayde Matta, DE OLIVEIRA Rafael Augustus. Effect of incorporation of blackberry particles on the physicochemical properties of edible films of arrowroot starch[J]. Drying Technology, 2019, 37(4): 448-457.
[21]	石洁, 王雪嵘, 徐朝阳. 壳聚糖/明胶/苹果多酚复合膜的制备及性能研究[J]. 包装工程, 2023, 44(1): 1-6.
	SHI Jie, WANG Xuerong, XU Zhaoyang. Preparation and properties of chitosan/gelatin/apple polyphenol composite films[J]. Packaging Engineering, 2023, 44(1): 1-6.
[22]	蒋庆玥. 壳聚糖/花青素智能标签的制备及应用[D]. 武汉: 武汉轻工大学, 2021.
	JIANG Qingyue. Preparation and application of chitosan/anthocyanin smart tag[D]. Wuhan: Wuhan Polytechnic University, 2021.
[23]	朱桂兰, 郭娜, 马文艺, 等. 结冷胶-茶多酚复合膜性能的研究[J]. 食品与发酵工业, 2019, 45(14): 72-77.
	ZHU Guilan, GUO Na, MA Wenyi, et al. Properties of gellan gum-tea polyphenols compounded films[J]. Food and Fermentation Industries, 2019, 45(14): 72-77.
[24]	胡熠, 周伟, 唐艳, 等. 香豆素对鱼鳞明胶可食性膜结构及性能的影响[J]. 食品科学, 2018, 39(12): 112-118.
	HU Yi, ZHOU Wei, TANG Yan, et al. Effect of coumarin on structure and properties of fish scale gelatin edible film[J]. Food Science, 2018, 39(12): 112-118.
[25]	HONG Jing, CHEN Rujiao, ZENG Xinan, et al. Effect of pulsed electric fields assisted acetylation on morphological, structural and functional characteristics of potato starch[J]. Food Chemistry, 2016, 192: 15-24.
[26]	PEREIRA Valdir Aniceto, DE ARRUDA Iza Natália Queiroz, STEFANI Ricardo. Active chitosan/PVA films with anthocyanins from Brassica Oleraceae (Red Cabbage) as time-temperature indicators for application in intelligent food packaging[J]. Food Hydrocolloids, 2015, 43: 180-188.
[27]	蒋光阳, 侯晓艳, 任文, 等. 淀粉-羧甲基纤维素钠-花青素指示膜的制备及在鱼肉鲜度指示中的应用[J]. 食品科学, 2020, 41(12): 250-258.
	JIANG Guangyang, HOU Xiaoyan, REN Wen, et al. Preparation of indicator films based on sodium carboxymethyl cellulose/starch and purple sweet potato anthocyanins for monitoring fish freshness[J]. Food Science, 2020, 41(12): 250-258.
[28]	GASTI Tilak, DIXIT Shruti, D’SOUZA Oshin J, et al. Smart biodegradable films based on chitosan/methylcellulose containing Phyllanthus reticulatus anthocyanin for monitoring the freshness of fish fillet[J]. International Journal of Biological Macromolecules, 2021, 187: 451-461.
[29]	KELISHOMI Zahra Habibi, GOLIAEI Bahram, MAHDAVI Hossein, et al. Antioxidant activity of low molecular weight alginate produced by thermal treatment[J]. Food Chemistry, 2016, 196: 897-902.
[30]	PANDA Pradeep Kumar, YANG Jen-Ming, CHANG Yen-Hsiang, et al. Modification of different molecular weights of chitosan by p-coumaric acid: Preparation, characterization and effect of molecular weight on its water solubility and antioxidant property[J]. International Journal of Biological Macromolecules, 2019, 136: 661-667.
[31]	RODE Tone Mari, HOVDA Maria Befring. High pressure processing extend the shelf life of fresh salmon, cod and mackerel[J]. Food Control, 2016, 70: 242-248.

花青素添加量/mg	含水量MC/%	溶胀度SR/%	水溶性WS/%
0	64.31	75.38	67.46
10	64.58	85.71	66.59
20	65.67	75.86	64.96
30	67.73	79.66	64.35
40	67.95	83.38	62.81
50	68.62	73.92	59.85

花青素添加量/mg	含水量MC/%	溶胀度SR/%	水溶性WS/%
0	64.31	75.38	67.46
10	64.58	85.71	66.59
20	65.67	75.86	64.96
30	67.73	79.66	64.35
40	67.95	83.38	62.81
50	68.62	73.92	59.85

Preparation and properties of CS/SA composite gel membrane based on blueberry anthocyanins

基于蓝莓花青素的CS/SA智能指示复合凝胶膜的制备及性能

RichHTML

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 17

References 31

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	LI Peiyi, SUN Bolong, LIU Ruiyan, ZHOU Xinyao, LIU Ruilin, HU Yuanyuan, XU Gongtao, LI Xinping. Preparation of sodium alginate/titanium dioxide composite porous material and its application in oil-water separation [J]. Chemical Industry and Engineering Progress, 2025, 44(6): 3053-3061.
[2]	WU Zhe, QU Shuguang, FENG Lianxiang, ZENG Xiangchu. Adsorption performance and mechanism of sodium alginate/microcrystalline cellulose composite hydrogel for aqueous methyl orange and methylene blue [J]. Chemical Industry and Engineering Progress, 2024, 43(8): 4681-4693.
[3]	DONG Xiaohan, TIAN Yue, SU Yi. Study on the preparation of composite adsorbent with titanium-containing blast furnace slag and chromium adsorption performance [J]. Chemical Industry and Engineering Progress, 2024, 43(3): 1552-1564.
[4]	WANG Bicong, PAN Dawei, XIE Rui, JU Xiaojie, LIU Zhuang, WANG Wei, CHU Liangyin. Fabrication of multi-enzyme@ZIF-8 for extraction of anthocyanins from black rice [J]. Chemical Industry and Engineering Progress, 2024, 43(3): 1403-1411.
[5]	ZHAO Huangshiyu, ZHOU Kuan, DENG Siwei, LIU Longyu, ZHU Weiwei, YU Jiang. Remediation of polymetallic contaminated soil with modified chitosan materials [J]. Chemical Industry and Engineering Progress, 2024, 43(10): 5881-5889.
[6]	WANG Shaofan, ZHOU Ying, HAO Kang’an, HUANG Anrong, ZHANG Ruju, WU Chong, ZUO Xiaoling. Self-healing and blue-light hydrogel with pH responsiveness [J]. Chemical Industry and Engineering Progress, 2023, 42(9): 4837-4846.
[7]	WANG Lin, XIN Meihua, LI Mingchun, CHEN Qi, MAO Yangfan. Preparation of quaternized/sulfonated chitosan and its anti-biofilm activity [J]. Chemical Industry and Engineering Progress, 2023, 42(5): 2577-2585.
[8]	WANG Lin, XIN Meihua, LI Mingchun, ZHANG Tao, MAO Yangfan. Preparation of alkyl quaternized chitosan and its anti-biofilm activity [J]. Chemical Industry and Engineering Progress, 2023, 42(4): 1995-2002.
[9]	FENG Ying, ZHAO Mengjie, CUI Qian, XIE Yuju, ZHANG Jianwei, DONG Xin. Research progress of molecular simulation technology in the development and application of chitosan functional materials [J]. Chemical Industry and Engineering Progress, 2022, 41(8): 4241-4253.
[10]	YUAN Xiaolu, LI Baoxia, HUANG Yayan, YANG Yucheng, YE Jing, ZHANG Na, ZHANG Xueqin, ZHENG Bingde, XIAO Meitian. Progress in preparation and application of sodium alginate microcapsules [J]. Chemical Industry and Engineering Progress, 2022, 41(6): 3103-3112.
[11]	ZHOU Lisha, LI Ruonan, BIAN Yujie, CHEN Shunsheng. Preparation of TOCNF and magnetic carboxymethyl chitosan nanoparticles composite and adsorption properties of Pb²⁺ [J]. Chemical Industry and Engineering Progress, 2022, 41(2): 901-910.
[12]	LI Saisai, ZHAN Shuo, LI Jiding, HE Jing, WANG Luying. Preparation and performance control of calcium lignosulfonate/sodium alginate pervaporation membrane [J]. Chemical Industry and Engineering Progress, 2021, 40(S1): 311-318.
[13]	Ximing ZHENG, Rongyu FAN. Covalent modification of chitosan quaternary ammonium salt on microporous polypropylene membrane and its antibacterial properties [J]. Chemical Industry and Engineering Progress, 2021, 40(1): 332-338.
[14]	Qihai LIU, Wanting XIE, Zhenyu JIA, Xiaohua ZHU, Ronghui WANG. Preparation of chitosan capsule materials and its sustained release properties [J]. Chemical Industry and Engineering Progress, 2021, 40(1): 339-345.
[15]	Xuguang LIU, Meihua XIN, Mingchun LI, Junkai XU, Lin WANG. Preparation and properties of chitosan/N-vinyl pyrrolidone copolymer [J]. Chemical Industry and Engineering Progress, 2020, 39(9): 3535-3542.