Chemical Industry and Engineering Progress ›› 2021, Vol. 40 ›› Issue (5): 2917-2927.DOI: 10.16085/j.issn.1000-6613.2020-1272
• Resources and environmental engineering • Previous Articles Next Articles
LU Yao1(), WANG Peng2(), YIN Mengnan1, YANG Mingyi1, ZHANG Huang3,4()
Received:
2020-07-06
Online:
2021-05-24
Published:
2021-05-06
Contact:
ZHANG Huang
鲁遥1(), 王朋2(), 尹梦楠1, 杨名毅1, 张凰3,4()
通讯作者:
张凰
作者简介:
鲁遥(1995—),女,硕士研究生,研究方向为土壤中持久性自由基的稳定机制。E-mail:基金资助:
CLC Number:
LU Yao, WANG Peng, YIN Mengnan, YANG Mingyi, ZHANG Huang. Characteristics and influencing factors of environmental persistent free radicals of humic acid extracts from different types of soil[J]. Chemical Industry and Engineering Progress, 2021, 40(5): 2917-2927.
鲁遥, 王朋, 尹梦楠, 杨名毅, 张凰. 不同类型土壤胡敏酸提取物环境持久性自由基特征及影响因素[J]. 化工进展, 2021, 40(5): 2917-2927.
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样品 | g值 | 线宽ΔH | 自旋密度/spin·g-1 |
---|---|---|---|
B-HA-1 | 2.0034 | 4.36 | 7.42×1016 |
B-HA-2 | 2.0035 | 4.52 | 4.37×1016 |
B-HA-3 | 2.0036 | 4.58 | 2.99×1016 |
B-HA-4 | 2.0039 | 4.66 | 2.13×1016 |
R-HA-1 | 2.0041 | 4.66 | 3.66××1016 |
R-HA-2 | 2.0040 | 4.35 | 4.91××1016 |
R-HA-3 | 2.0039 | 4.38 | 2.94××1016 |
R-HA-4 | 2.0038 | 4.66 | 2.43××1016 |
Y-HA-1 | 2.0040 | 4.36 | 3.03×1016 |
Y-HA-2 | 2.0039 | 4.51 | 1.11×1016 |
Y-HA-3 | 2.0040 | 4.58 | 1.14×1016 |
Y-HA-4 | 2.0039 | 4.66 | 0.84×1016 |
样品 | g值 | 线宽ΔH | 自旋密度/spin·g-1 |
---|---|---|---|
B-HA-1 | 2.0034 | 4.36 | 7.42×1016 |
B-HA-2 | 2.0035 | 4.52 | 4.37×1016 |
B-HA-3 | 2.0036 | 4.58 | 2.99×1016 |
B-HA-4 | 2.0039 | 4.66 | 2.13×1016 |
R-HA-1 | 2.0041 | 4.66 | 3.66××1016 |
R-HA-2 | 2.0040 | 4.35 | 4.91××1016 |
R-HA-3 | 2.0039 | 4.38 | 2.94××1016 |
R-HA-4 | 2.0038 | 4.66 | 2.43××1016 |
Y-HA-1 | 2.0040 | 4.36 | 3.03×1016 |
Y-HA-2 | 2.0039 | 4.51 | 1.11×1016 |
Y-HA-3 | 2.0040 | 4.58 | 1.14×1016 |
Y-HA-4 | 2.0039 | 4.66 | 0.84×1016 |
样品 | 元素分析(质量分数) | 灰分 /% | E285 | E4/E6 | |||||
---|---|---|---|---|---|---|---|---|---|
C/% | H/% | O/% | N/% | C/H比 | (N+O)/C比 | ||||
B-HA-1 | 54.39 | 4.26 | 37.36 | 3.06 | 1.04 | 0.57 | 0.9 | 0.95 | 4.23 |
B-HA-2 | 54.63 | 4.53 | 36.99 | 3.24 | 1.00 | 0.56 | 1.1 | 0.87 | 4.33 |
B-HA-3 | 54.70 | 4.87 | 36.40 | 3.59 | 0.94 | 0.55 | 1.1 | 0.83 | 4.35 |
B-HA-4 | 54.81 | 5.24 | 35.72 | 3.82 | 0.87 | 0.54 | 1.2 | 0.64 | 4.38 |
R-HA-1 | 53.75 | 5.03 | 37.44 | 3.20 | 0.89 | 0.57 | 2.6 | 0.89 | 3.71 |
R-HA-2 | 53.88 | 5.22 | 37.12 | 3.22 | 0.86 | 0.56 | 1.4 | 0.75 | 3.93 |
R-HA-3 | 54.57 | 5.39 | 36.23 | 3.27 | 0.84 | 0.54 | 2.2 | 0.73 | 4.05 |
R-HA-4 | 55.34 | 5.79 | 34.93 | 3.32 | 0.80 | 0.52 | 2.0 | 0.68 | 4.16 |
Y-HA-1 | 51.13 | 5.14 | 39.83 | 3.57 | 0.83 | 0.64 | 2.7 | 0.74 | 4.15 |
Y-HA-2 | 51.30 | 5.34 | 38.31 | 4.42 | 0.80 | 0.63 | 1.7 | 0.62 | 4.23 |
Y-HA-3 | 51.59 | 5.70 | 37.82 | 4.26 | 0.75 | 0.62 | 2.6 | 0.51 | 4.27 |
Y-HA-4 | 51.72 | 5.86 | 36.87 | 4.92 | 0.73 | 0.61 | 2.4 | 0.41 | 4.30 |
样品 | 元素分析(质量分数) | 灰分 /% | E285 | E4/E6 | |||||
---|---|---|---|---|---|---|---|---|---|
C/% | H/% | O/% | N/% | C/H比 | (N+O)/C比 | ||||
B-HA-1 | 54.39 | 4.26 | 37.36 | 3.06 | 1.04 | 0.57 | 0.9 | 0.95 | 4.23 |
B-HA-2 | 54.63 | 4.53 | 36.99 | 3.24 | 1.00 | 0.56 | 1.1 | 0.87 | 4.33 |
B-HA-3 | 54.70 | 4.87 | 36.40 | 3.59 | 0.94 | 0.55 | 1.1 | 0.83 | 4.35 |
B-HA-4 | 54.81 | 5.24 | 35.72 | 3.82 | 0.87 | 0.54 | 1.2 | 0.64 | 4.38 |
R-HA-1 | 53.75 | 5.03 | 37.44 | 3.20 | 0.89 | 0.57 | 2.6 | 0.89 | 3.71 |
R-HA-2 | 53.88 | 5.22 | 37.12 | 3.22 | 0.86 | 0.56 | 1.4 | 0.75 | 3.93 |
R-HA-3 | 54.57 | 5.39 | 36.23 | 3.27 | 0.84 | 0.54 | 2.2 | 0.73 | 4.05 |
R-HA-4 | 55.34 | 5.79 | 34.93 | 3.32 | 0.80 | 0.52 | 2.0 | 0.68 | 4.16 |
Y-HA-1 | 51.13 | 5.14 | 39.83 | 3.57 | 0.83 | 0.64 | 2.7 | 0.74 | 4.15 |
Y-HA-2 | 51.30 | 5.34 | 38.31 | 4.42 | 0.80 | 0.63 | 1.7 | 0.62 | 4.23 |
Y-HA-3 | 51.59 | 5.70 | 37.82 | 4.26 | 0.75 | 0.62 | 2.6 | 0.51 | 4.27 |
Y-HA-4 | 51.72 | 5.86 | 36.87 | 4.92 | 0.73 | 0.61 | 2.4 | 0.41 | 4.30 |
样品 | 脂肪碳 (δ0~45) | 烷氧基碳 (δ45~110) | 芳香碳 (δ110~165) | 羧基碳 (δ165~190) | 羰基碳 (δ190~220) | 芳香性/% | 脂肪性/% |
---|---|---|---|---|---|---|---|
B-HA-1 | 19.95 | 13.05 | 45.02 | 13.08 | 8.90 | 57.69 | 42.31 |
B-HA-2 | 21.14 | 13.86 | 42.95 | 16.18 | 5.87 | 55.13 | 44.87 |
B-HA-3 | 22.45 | 15.55 | 40.96 | 17.08 | 3.96 | 51.89 | 48.10 |
B-HA-4 | 24.66 | 17.34 | 39.96 | 11.09 | 6.95 | 48.78 | 51.22 |
R-HA-1 | 24.75 | 16.83 | 37.62 | 12.87 | 7.93 | 47.50 | 52.50 |
R-HA-2 | 27.27 | 15.15 | 37.37 | 16.16 | 4.05 | 46.83 | 53.16 |
R-HA-3 | 31.63 | 12.24 | 36.73 | 17.35 | 2.05 | 45.57 | 54.43 |
R-HA-4 | 30.00 | 19.00 | 36.36 | 11.11 | 3.53 | 41.86 | 58.14 |
Y-HA-1 | 26.26 | 17.17 | 36.63 | 11.98 | 7.98 | 45.68 | 54.32 |
Y-HA-2 | 24.63 | 18.81 | 35.35 | 12.12 | 9.09 | 44.87 | 55.13 |
Y-HA-3 | 21.11 | 28.29 | 32.35 | 9.43 | 8.82 | 39.76 | 60.24 |
Y-HA-4 | 27.35 | 23.65 | 30.50 | 14.50 | 4.00 | 37.04 | 62.96 |
样品 | 脂肪碳 (δ0~45) | 烷氧基碳 (δ45~110) | 芳香碳 (δ110~165) | 羧基碳 (δ165~190) | 羰基碳 (δ190~220) | 芳香性/% | 脂肪性/% |
---|---|---|---|---|---|---|---|
B-HA-1 | 19.95 | 13.05 | 45.02 | 13.08 | 8.90 | 57.69 | 42.31 |
B-HA-2 | 21.14 | 13.86 | 42.95 | 16.18 | 5.87 | 55.13 | 44.87 |
B-HA-3 | 22.45 | 15.55 | 40.96 | 17.08 | 3.96 | 51.89 | 48.10 |
B-HA-4 | 24.66 | 17.34 | 39.96 | 11.09 | 6.95 | 48.78 | 51.22 |
R-HA-1 | 24.75 | 16.83 | 37.62 | 12.87 | 7.93 | 47.50 | 52.50 |
R-HA-2 | 27.27 | 15.15 | 37.37 | 16.16 | 4.05 | 46.83 | 53.16 |
R-HA-3 | 31.63 | 12.24 | 36.73 | 17.35 | 2.05 | 45.57 | 54.43 |
R-HA-4 | 30.00 | 19.00 | 36.36 | 11.11 | 3.53 | 41.86 | 58.14 |
Y-HA-1 | 26.26 | 17.17 | 36.63 | 11.98 | 7.98 | 45.68 | 54.32 |
Y-HA-2 | 24.63 | 18.81 | 35.35 | 12.12 | 9.09 | 44.87 | 55.13 |
Y-HA-3 | 21.11 | 28.29 | 32.35 | 9.43 | 8.82 | 39.76 | 60.24 |
Y-HA-4 | 27.35 | 23.65 | 30.50 | 14.50 | 4.00 | 37.04 | 62.96 |
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