Chemical Industry and Engineering Progress ›› 2020, Vol. 39 ›› Issue (2): 567-576.DOI: 10.16085/j.issn.1000-6613.2019-0544
• Industrial catalysis • Previous Articles Next Articles
Jingyu CHEN(),Jianhong ZHANG,Hao SHENG,Dakai WU,Xinhua GAO(),Qingxiang MA,Jianli ZHANG(),Subing FAN,Tiansheng ZHAO
Received:
2019-04-09
Online:
2020-03-12
Published:
2020-02-05
Contact:
Xinhua GAO,Jianli ZHANG
陈静宇(),张建红,盛浩,吴大凯,高新华(),马清祥,张建利(),范素兵,赵天生
通讯作者:
高新华,张建利
作者简介:
陈静宇(1993—),女,硕士研究生,研究方向为煤基应用催化。E-mail:基金资助:
CLC Number:
Jingyu CHEN,Jianhong ZHANG,Hao SHENG,Dakai WU,Xinhua GAO,Qingxiang MA,Jianli ZHANG,Subing FAN,Tiansheng ZHAO. Design and preparation of CuZnTiO2/SAPO-34 bifunctional catalyst and its catalytic performance in CO2 hydrogenation to light olefins[J]. Chemical Industry and Engineering Progress, 2020, 39(2): 567-576.
陈静宇,张建红,盛浩,吴大凯,高新华,马清祥,张建利,范素兵,赵天生. CuZnTiO2/SAPO-34双功能催化剂的设计、制备及其用于CO2加氢制烯烃性能[J]. 化工进展, 2020, 39(2): 567-576.
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催化剂 | 弱酸 | 强酸 | 总酸量/mmol·g-1 | ||
---|---|---|---|---|---|
温度/℃ | 酸量/mmol·g-1 | 温度/℃ | 酸量/mmol·g-1 | ||
CZT | — | — | — | — | — |
CZT/SAPO-34(2∶1) | 168 | 0.02 | 341 | 0.02 | 0.04 |
CZT/SAPO-34(1∶1) | 163 | 0.03 | 375 | 0.02 | 0.04 |
CZT/SAPO-34(1∶2) | 166 | 0.05 | 396 | 0.09 | 0.14 |
SAPO-34 | 172 | 0.13 | 389 | 0.09 | 0.22 |
Zn-SAPO-34 | 174 | 0.27 | 442 | 0.08 | 0.35 |
CZT/Zn-SAPO-34(1∶2) | 169 | 0.04 | — | 0.02 | 0.06 |
催化剂 | 弱酸 | 强酸 | 总酸量/mmol·g-1 | ||
---|---|---|---|---|---|
温度/℃ | 酸量/mmol·g-1 | 温度/℃ | 酸量/mmol·g-1 | ||
CZT | — | — | — | — | — |
CZT/SAPO-34(2∶1) | 168 | 0.02 | 341 | 0.02 | 0.04 |
CZT/SAPO-34(1∶1) | 163 | 0.03 | 375 | 0.02 | 0.04 |
CZT/SAPO-34(1∶2) | 166 | 0.05 | 396 | 0.09 | 0.14 |
SAPO-34 | 172 | 0.13 | 389 | 0.09 | 0.22 |
Zn-SAPO-34 | 174 | 0.27 | 442 | 0.08 | 0.35 |
CZT/Zn-SAPO-34(1∶2) | 169 | 0.04 | — | 0.02 | 0.06 |
催化剂 | 比表面积/m2·g-1 | 总孔体积/cm3·g-1 | 孔径/nm |
---|---|---|---|
CZT | 36.4 | 0.12 | 2.86 |
CZT/SAPO-34(1∶2) | 64.6 | 0.10 | 2.60 |
CZT/Zn-SAPO-34(1∶2) | 60.7 | 0.09 | 2.11 |
SAPO-34 | 492.6 | 0.31 | 0.45 |
Zn-SAPO-34 | 416.3 | 0.32 | 0.45 |
催化剂 | 比表面积/m2·g-1 | 总孔体积/cm3·g-1 | 孔径/nm |
---|---|---|---|
CZT | 36.4 | 0.12 | 2.86 |
CZT/SAPO-34(1∶2) | 64.6 | 0.10 | 2.60 |
CZT/Zn-SAPO-34(1∶2) | 60.7 | 0.09 | 2.11 |
SAPO-34 | 492.6 | 0.31 | 0.45 |
Zn-SAPO-34 | 416.3 | 0.32 | 0.45 |
催化剂 | CO2转化率/% | 产物选择性/% | 烃类选择性/% | O/P | |||||
---|---|---|---|---|---|---|---|---|---|
CO | CH | CH3OH | CH4 | ||||||
CZT | 17.93 | 93.34 | 2.55 | 4.11 | 94.62 | 2.56 | 2.82 | 0 | 0.91 |
CZT/SAPO-34(2∶1) | 11.7 | 83.94 | 16.06 | — | 54.77 | 26.08 | 19.14 | 0 | 1.36 |
CZT/SAPO-34(1∶1) | 7.38 | 82.96 | 17.04 | — | 58.87 | 16.96 | 24.17 | 0 | 0.7 |
CZT/SAPO-34(1∶2) | 9.23 | 86.12 | 13.88 | — | 38.98 | 14.28 | 45.51 | 1.23 | 0.31 |
CZT/Zn-SAPO-34(1∶2) | 5.34 | 76.18 | 23.82 | — | 22.37 | 59.2 | 16.81 | 1.63 | 3.52 |
催化剂 | CO2转化率/% | 产物选择性/% | 烃类选择性/% | O/P | |||||
---|---|---|---|---|---|---|---|---|---|
CO | CH | CH3OH | CH4 | ||||||
CZT | 17.93 | 93.34 | 2.55 | 4.11 | 94.62 | 2.56 | 2.82 | 0 | 0.91 |
CZT/SAPO-34(2∶1) | 11.7 | 83.94 | 16.06 | — | 54.77 | 26.08 | 19.14 | 0 | 1.36 |
CZT/SAPO-34(1∶1) | 7.38 | 82.96 | 17.04 | — | 58.87 | 16.96 | 24.17 | 0 | 0.7 |
CZT/SAPO-34(1∶2) | 9.23 | 86.12 | 13.88 | — | 38.98 | 14.28 | 45.51 | 1.23 | 0.31 |
CZT/Zn-SAPO-34(1∶2) | 5.34 | 76.18 | 23.82 | — | 22.37 | 59.2 | 16.81 | 1.63 | 3.52 |
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