Preparation and catalytic oxidation of CO with specific morphology and porous nano CeO2

doi:10.16085/j.issn.1000-6613.2016-2206

Abstract

Abstract: Ce is a very versatile rare earth metal and its metal oxide CeO₂ showed good catalytic performance in redox reaction,organic synthesis and degradation of organic pollutants due to its excellent oxygen storage capacity,especially in the catalytic oxidation of CO.This paper introduces the latest research progress on the preparation methods,morphology and channel control of pure CeO₂ and CeO₂ composite catalyst and their catalytic oxidation of CO.Firstly,this paper introduces different synthesis methods of nanometer CeO₂ from the aspects of process,cost,and the synthetic conditions and summarizes their advantages and disadvantages.Then this paper discusses the nanometer CeO₂ catalyst with specific morphology for catalytic oxidation of CO performance,describes the catalytic mechanism and the influence of the morphology on the catalytic performance.It was found that the catalytic activity of nano-CeO₂ with specific morphology and porous structure was improved,but the structure was unstable and tthe preparation process can be simplified in the future work to improve the structure stability of CeO₂ and the oxidation mechanism of CO will be explored using in situ characterization and computer simulation.

Key words: cerium oxide (CeO₂), morphology, catalysis, oxidation, mechanism, reactivity

摘要： Ce是一种用途十分广泛的稀土金属，其金属氧化物CeO₂由于具有优异的储放氧性能，使其在氧化还原、有机合成和有机污染物降解等反应过程中呈现出良好的催化性能，尤其是在CO的催化氧化反应中表现出了优异的活性。本文综述了纯CeO₂及复合CeO₂催化剂的制备方法、形貌与孔道控制及其对CO催化氧化性能等方面的最新研究进展。首先介绍了液相法、固相法和气相法等不同合成纳米CeO₂的方法，通过对不同制备方法的工艺、成本、合成条件分析对比后，对其优缺点进行了系统的总结。随后讨论了利用不同制备方法及添加不同表面活性剂或模板剂所制备出的特定形貌及多孔纳米CeO₂催化剂对CO的催化氧化性能，描述了CeO₂对CO催化氧化的作用机理及形貌结构对催化性能的影响。最后根据对相关结果的总结发现，特定形貌及多孔结构的纳米CeO₂ 催化CO活性虽有提高，但存在结构不稳定、工艺复杂等问题。而且，对于催化反应过程中的反应机理，形貌与结构变化的研究较少。希望在今后的工作中简化制备工艺，提高CeO₂材料结构的稳定性，并用原位表征、模拟计算等方法来探究CO的氧化机理。

关键词: 二氧化铈, 形貌, 催化, 氧化, 机理, 活性

CLC Number:

HOU Fulin, LI Hongxin, YANG Yang, DONG Han, CUI Lifeng, ZHANG Xiaodong. Preparation and catalytic oxidation of CO with specific morphology and porous nano CeO₂[J]. Chemical Industry and Engineering Progress, 2017, 36(07): 2481-2487.

侯扶林, 李红欣, 杨阳, 董寒, 崔立峰, 张晓东. 特定形貌和多孔纳米CeO₂的制备及其CO催化氧化研究进展[J]. 化工进展, 2017, 36(07): 2481-2487.

References

[1] ZHANG X D,QU Z P,YU F L,et al. High-temperature diffusion induced high activity of SBA-15 supported Ag particles for low temperature CO oxidation at room temperature[J]. Journal of Catalysis,2013,297:264-271.
[2] ZHANG X D,DONG H,WANG Y,et al. Study of catalytic activity at the Ag/Al-SBA-15 catalysts for CO oxidation and selective CO oxidation[J]. Chemical Engineering Journal,2016,283:1097-1107.
[3] MONTINI T,MELCHIONNA M,MONAI M,et al. Fundamentals and catalytic applications of CeO₂-based materials[J]. Chemical Reviews,2016,116(10):5987-6041.
[4] 冯长根,樊国栋,刘霞. 三效催化剂中促进剂氧化铈的作用研究进展[J]. 化工进展,2005,24(3):227-230. FENG C G,FAN G D,LIU X. Review of ceria as promoters in three-way catalysis[J]. Chemical Industry and Engineering Progress,2005,24(3):227-230.
[5] LIANG X,XIAO J J,CHEN B H. Catalytically stable and active CeO₂ mesoporous spheres[J]. Inorganic Chemistry,2010,49(18):8188-8190.
[6] TAREK A,HESHMAT N,WANG Y M,et al. Ionic liquid-assisted sonochemical preparation of CeO₂ nanoparticles for CO oxidation[J]. ACS Sustainable Chemistry & Engineering,2014,3(1):42-54.
[7] ZHANG D S,PAN C G,SHI L Y,et al. A highly reactive catalyst for CO oxidation:CeO₂ nanotubes synthesized using carbon nanotubes as removable templates[J]. Microporous & Mesoporous Materials,2009,117(s1/s2):193-200.
[8] 耿九光,臧文杰,李毅,等. 纳米二氧化铈的制备及光催化性能[J]. 化工进展,2014,33(3):720-723. GENG J G,ZANG W J,LI Y,TAO J Q. Preparation and photocatalytic performance of nano-ceria[J]. Chemical Industry and Engineering Progress,2014,33(3):720-723.
[9] AHMED M A,BISHAY S T,MAI E M. Structural and topographic study of ceria nanoparticles prepared via different techniques[J]. Superlattices& Microstructures,2015,77:240-255.
[10] 王敏炜,魏文龙,罗来涛. CeO₂的制备及其在催化剂载体中的应用研究进展[J]. 化工进展,2006,25(5):517-519. WANG M W,WEI W L,LUO L T. Preparation of CeO₂ and its role as catalyst support[J]. Chemical Industry and Engineering Progress,2006,25(5):517-519.
[11] PAN P S,ZHANG D S,SHI L Y,et al. Template-free synthesis,controlled conversion,and CO oxidation properties of CeO₂ nanorods,nanotubes,nanowires,and nanocubes[J]. European Journal of Inorganic Chemistry,2008(15):2429-2436.
[12] GAO W,ZHANG Z Y,LI J,et al. Surface engineering on CeO₂ nanorods by chemical redoxetching and their enhanced catalytic activity for CO oxidation[J]. Nanoscale,2015,7(27):11686-11691.
[13] YANG J X,LUKASHUK L,LI H,et al. High surface area ceria for CO oxidation prepared from cerium t-butoxide by combined sol-gel and solvothermal processing[J]. Catalysis Letters,2014,144:403-412.
[14] POURNAJAF R,HASSANZADEH-TABRIZI S A,JAFARI M. Reverse microemulsion synthesis of CeO₂ nanopowder using polyoxyethylene(23)lauryl ether as a surfactant[J]. Ceramics International,2014,40(6):8687-8692.
[15] HE H Y,YANG P,LI J,et al. Controllable synthesis,characterization,and CO oxidation activity of CeO₂ nanostructures with various morphologies[J]. Ceramics International,2016,42(6):7810-7818.
[16] DENG W,WANG X Y,JIAO F,et al. A platelet-like CeO₂ mesocrystal enclosed by {100} facets:synthesis and catalytic properties[J]. Journal of Nanoparticle Research,2013,15(10):1-10.
[17] RAO R H,YANG M,LING Q,et al. Mesoporous CeO₂ nanobelts synthesized by a facile hydrothermal route via controlling cationic type and concentration of alkali[J]. Microporous and Mesoporous Materials,2013,169(10):81-87.
[18] XIE A R,WANG S P,LIU W,et al. Rapid hydrothermal synthesis of CeO₂ nanoparticles with(220)-dominated surface and its CO catalytic performance[J]. Materials Research Bulletin,2015,62:148-152.
[19] SLAVINSKAYA E M,GULYAEV R V,ZADESENETS A V,et al. Low-temperature CO oxidation by Pd/CeO₂ catalysts synthesized using the coprecipitation method[J]. Applied Catalysis B:Environmental,2015,166/167:91-103.
[20] LEONARDO F P,TISCORNIA I S,Eduardo E M. Study of the synthesis of CeO₂ nanoparticles for their use in CO preferential oxidation (COPrOx)[J]. Chemical Engineering Journal,2013,223(5):507-515.
[21] ZHONG L S,HU J S,CAO A M,et al. 3D flowerlike ceria micro/nanocomposite structure and its application for water treatment and CO removal[J]. Chemistry of Materials,2007,19(7):1648-1655.
[22] WU H J,WANG L D. Shape effect of microstructured CeO₂ with various morphologies on CO catalytic oxidation[J]. Catalysis Communications,2011,12(14):1374-1379.
[23] LIU Y,WEN C,GUO Y,et al. Effects of surface area and oxygen vacancies on ceria in CO oxidation:differences and relationships[J]. Journal of Molecular Catalysis A:Chemical,2010,316(s1/s2):59-64.
[24] 陶宇,王辉,纪俊玲,等. 微波辅助法制备形貌可控CeO₂纳米材料[J]. 中国稀土学报,2010,28(4):414-419. TAO Y,WANG H,JI J L,et al. Synthesis of shape-controlled CeO₂ nanomaterials via microwave-assisted method[J]. Chinese Journal of Rare Earths,2010,28(4):414-419.
[25] BONDIOLI F,CORRADI A B,LEONELLI C,et al. Nanosized CeO₂ powders obtained by flux method[J]. Materials Research Bulletin,1999,34(14/15):2159-2166.
[26] HU Y D,GUAN T,WU X D,et al. Preparation technology and research progress of nano-CeO₂[J]. Advances in Condensed Matter Physics,2015,4(4):113-118.
[27] VALENZUELA R X,BUENO G,SOLBES A,et al. Nanostructured ceria-based catalysts for oxide hydrogenation of ethane with CO₂[J]. Topics in Catalysis,2001,15(2):181-188.
[28] RAO R H,YANG M,LI C S,et al. A facile synthesis for hierarchical porous CeO₂ nanobundles and their superior catalytic performance for CO oxidation[J]. Journal of Materials Chemistry A,2015,3:782-788.
[29] LI J F,LU G Z,LI H F,et al. Facile synthesis of 3D flowerlike CeO₂ microspheres under mild condition with high catalytic performance for CO oxidation[J]. Journal of Colloid and Interface Science,2011,360(1):93-99.
[30] XIE A,LIU W,WANG S P,et al. Template-free hydrothermal synthesis and CO oxidation properties of flower-like CeO₂ nanostructures[J]. Materials Research Bulletin,2014,59(16):18-24.
[31] SHEN Y,LI C,YANG Z H,et al. Shape-controllable synthesis of CeO₂ particles in CO₂-expanded ethanol towards CO oxidation application[J]. RSC Advance,2013,3(16):5302-5304.
[32] LIU X F,LIU W,ZHANG X Y,et al. Zr-doped CeO₂ hollow slightly-truncated nano-octahedrons:one-pot synthesis,characterization and their application in catalysis of CO oxidation[J]. Crystal Research & Technology,2014,49(6):383-392.
[33] ZHANG D S,YAN T T,PAN C G,et al. Carbon nanotube-assisted synthesis and high catalytic activity of CeO₂ hollow nanobeads[J]. Materials Chemistry and Physics,2009,113(2/3):527-530.
[34] HE Y H,LIANG X,CHEN B H. Globin-like mesoporous CeO₂:a CO-assisted synthesis based on carbonate hydroxide precursors and its applications in low temperature CO oxidation[J]. Nano Research,2015,8(4):1269-1278.
[35] NISHA S,ANUMOL E A,RAVISHANKAR N,et al. Influence of CeO₂ morphology on the catalytic activity of CeO₂-Pt hybrids for CO oxidation[J]. Dalton Transactions,2013,42(43):15343-54.
[36] QIAN J C,CHEN Z G,LIU C B,et al. Biotemplated fabrication of hierarchical mesoporous CeO₂ derived from diatom and its application for catalytic oxidation of CO[J]. Chinese Science Bulletin,2014,59(26):3260-3265.
[37] GU C L,MIAO J,LIU Y,et al. Meso-macroporous monolithic CuO-CeO₂/γ-Al₂O₃ catalysts and their catalytic performance for preferential oxidation of CO[J]. Journal of Materials Science,2010,45(20):5660-5668.
[38] XIE S H,DAI H X,DENG J G,et al. Preparation and high catalytic performance of Au/3DOM Mn₂O₃ for the oxidation of carbon monoxide and toluene[J]. Journal of Hazardous Materials,2014,279:392-401.
[39] ZHANG K F,LIU Y X,DENG J G,et al. Fe₂O₃/3DOM BiVO₄:high-performance photocatalysts for the visible light-driven degradation of 4-nitrophenol[J]. Applied Catalysis B:Environmental,2017,202:569-579.
[40] JIN B,WEI Y,ZHAO Z,et al. Effects of Au-Ce strong interactions on catalytic activity of Au/CeO₂/3DOM Al₂O₃ catalyst for soot combustion under loose contact conditions[J]. Chinese Journal of Catalysis,2016,37(6):23-933.
[41] FANG J,WANG M H,LIN D H,et al. Enhanced transport of CeO₂ nanoparticles in porous media by macropores[J]. Science of the Total Environment,2016,543:223-229.
[42] 李朝玉,江学良,晏爽,等. 溶胶-凝胶模板法制备三维有序大孔CeO₂微球的研究[J]. 化工新型材料,2011,39(4):49-52. LI C Y,JIANG X L,YAN S,et al. Preparation of ordered macroporous CeO₂ balls by sol-gel templating method[J]. New Chemical Materials,2011,39(4):49-52.
[43] XIE S H,LIU Y X,DENG J G,et al. Three-dimensionally ordered macroporous CeO₂-supported Pd@Co nanoparticles:highly active catalysts for methane oxidation[J]. Journal of Catalysis,2016,342:17-26.
[44] WATERHOUSE G I N,METSON J B,IDRISS H,et al. Physical and optical properties of inverse opal CeO₂ photonic crystals[J]. Chemistry of Materials,2008,20(3):1183-1190.
[45] MU G,LIU C,WEI Q L,et al. Three dimensionally ordered macroporous CeO₂-ZnO catalysts for enhanced CO oxidation[J]. Materials Letters,2016,181:161-164.
[46] LIU Z,YANG Y,MI J H,et al. Dual-templating fabrication of three-dimensionally ordered macroporous ceria with hierarchical pores and its use as a support for enhanced catalytic performance of preferential CO oxidation[J]. International Journal of Hydrogen Energy,2013,38(11):4445-4455.
[47] ZHANG H,ZHANG L,DENG J G,et al. Dual-templating preparation and enhanced low-temperature reducibility of three-dimensionally ordered macroporous ceria with mesoporous walls[J]. Chinese Journal of Catalysis,2011,32(5):842-852.
[48] PORSIN A V,ALIKIN E A,BUKHTIYAROV V I. A low-temperature method for measuring oxygen storage capacity of ceria-containing oxides[J]. Catalysis Science & Technology,2016(6):5891-5898.
[49] 詹望成,郭耘,龚学庆,等. 二氧化铈表面氧的活化及对氧化反应的催化作用[J]. 中国科学:化学,2012(4):433-445. ZHAN W C,GUO Y,GONG X Q,et al. Surface oxygen activation on CeO₂ and its catalytic performances for oxidation reactions[J]. Scientia Sinica Chimica,2012(4):433-445.
[50] ESCH F,FABRIS S,ZHOU L,et al. Electron localization determines defect formation on ceria substrates[J]. Science,2005,309(5735):752-755.
[51] WU L,WIESMANN H J,MOODENBAUGH A R,et al. Oxidation state and lattice expansion of CeO₂-x nanoparticles as a function of particle size[J]. Physical Review B,2004,69(12):125415.
[52] AYODELE B V,KHAN M R,CHENG C K,et al. Catalytic performance of ceria-supported cobalt catalyst for CO-rich hydrogen production from dry reforming of methane[J]. International Journal of Hydrogen Energy,2015,41(1):198-207.

Preparation and catalytic oxidation of CO with specific morphology and porous nano CeO₂

特定形貌和多孔纳米CeO₂的制备及其CO催化氧化研究进展

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