Abstract: A new method, i.e.，air flow aided volatilization-condensation process, to separate azeotropic mixtures was proposed. The separation of azeotrope cyclohexane-ethanol was studied to investigate the separation effect of the new method. The experimental results showed that a breakdown of azeotropic composition was achieved for two different feed compositions. Compared with extraction using water as extracting agent, the method of air flow aided volatilization-condensation process has the advantage of not forming a new azeotrope.