化工进展 ›› 2017, Vol. 36 ›› Issue (S1): 489-494.DOI: 10.16085/j.issn.1000-6613.2017-0415

• 资源与环境化工 • 上一篇    下一篇

超声波-破乳联用技术处理大庆落地油泥

赵晓非, 葛丹, 张晓阳   

  1. 东北石油大学化学化工学院, 黑龙江 大庆 163318
  • 收稿日期:2017-03-15 修回日期:2017-03-24 出版日期:2017-12-31 发布日期:2017-12-13
  • 通讯作者: 葛丹,硕士研究生。研究方向为油田化学。
  • 作者简介:赵晓非(1967-),男,博士,教授,主要从事与油田化学添加剂的开发与其现场应用。E-mail:dqpifzx@163.com。

Treatment of oily sludge in Daqing by ultrasonic-demulsification hyphenated technique

ZHAO Xiaofei, GE Dan, ZHANG Xiaoyang   

  1. Chemistry and Chemical Engineering of Northeast Petroleum University, Daqing 163318, Heilongjiang, China
  • Received:2017-03-15 Revised:2017-03-24 Online:2017-12-31 Published:2017-12-13

摘要: 以大庆落地油泥为研究对象,采用超声波-破乳联用技术进行脱油处理,研究了超声频率、超声功率、超声温度、超声作用时间、药剂加量等参数对除油效果的影响。采用显微镜对超声波-破乳处理前后的油泥微观结构进行表征。结果表明:在超声频率40kHz、超声功率70W、超声温度40℃、超声时间10min、破乳剂加入量3mg/L的最佳处理条件下,含油污泥除油率最佳,为96.8%,比单一破乳法提高了9.4%。显微镜结果显示:与单一破乳处理的油泥相比,经过超声-破乳处理后的油泥,无明显的油珠和水滴,表面较为平整且杂质含量少。说明超声波的空化作用具有提高油泥破乳效果增大除油率的作用。证明了超声波-破乳联用技术能够有效去除油泥中污油。

关键词: 超声波-破乳联用技术, 落地油泥, 显微镜, 空化作用

Abstract: Ultrasonic-demulsification hyphenated technique was adopted to remove waste oil from oil sludge which were generated in Daqing. The effects of ultrasonic frequency, ultrasonic power, ultrasonic temperature, ultrasonic time and demulsifier dosage on the oil removal efficiency were studied. The microscopic structure of the sludge before and after ultrasonic-demulsification were analyzed by microscopy. The experimental results show that the best oil removal rate of oily sludge is 96.8% under the optimum condition of ultrasonic frequency of 40kHz, ultrasonic power of 70W, ultrasonic temperature of 40℃,ultrasonic time of 10min, and the demulsifier dosage is 3mg/L,which are 9.4% higher than a single demulsification technique. Microscopic results show that:compared with a single demulsification treatment of sludge, after ultrasonic-demulsification treatment of sludge, no obvious oil droplets and water droplets, the surface is relatively smooth and less impurity content. It is shown that the cavitation effect of ultrasonic wave has the effect of increasing the oil removal efficiency. It is proved that the ultrasonic-demulsification hyphenated technique can effectively remove waste oil sludge.

Key words: ultrasonic-demulsification hyphenated techniques, oil sludge, microscope, cavitation

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