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多级孔道沸石用于甲醇制丙烯反应研究进展

严丽霞,虞贤波,王靖岱,阳永荣   

  1. 化学工程国家重点实验室(浙江大学),浙江大学化学工程与生物工程学系,浙江 杭州 310027
  • 出版日期:2011-09-05 发布日期:2011-09-05

Research progress of hierarchical zeolites for methanol to propylene reaction

YAN Lixia,YU Xianbo,WANG Jingdai,YANG Yongrong   

  1. State Key Laboratory of Chemical Engineering,Department of Chemical and Biochemical Engineering,Zhejiang University,Hangzhou 310027,Zhejiang,China
  • Online:2011-09-05 Published:2011-09-05

摘要:

综述了多级孔道沸石结构、性能及制备方法的最新研究进展。多级孔道沸石因为介孔的引入强化了分子在孔道内的扩散,提高了目标产物的收率和选择性,在催化反应领域具有非常大的应用潜力。针对ZSM-5SAPO-34两种不同的分子筛体系,介绍了多级孔道沸石制备的后处理法与模板法,指出控制后处理脱硅脱铝的程度以及探寻合适且廉价的模板剂是发展多级孔道材料的关键技术。最后对多级孔道沸石在甲醇制丙烯反应中的应用前景作了展望,得出保证分子筛合理的微孔/介孔比例、分布及催化剂合适的强度,是该材料应用于甲醇制丙烯反应的关键。

Abstract:

Recent research progress of hierarchical zeolites is reviewed with respect to their structuresproperties and synthesis. Due to the insertion of mesoporousthe yield and selectivity of target products are improvedthus the hierarchical zeolites have large potential applications in catalysis. The synthesis of hierarchical zeolites using two kinds of molecular sieve is discussedespecially the methods of post-processing and templating. The degree of desilication or dealuminationand suitable but cheap templates are essential techniques to develop hierarchical zeolite materials. The application prospect of hierarchical zeolites in methanol to propylene reaction is discussedand an appropriate ratio of micro/ mesoporesappropriate distribution as well as intensity of catalyst are the key issues for its application.

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