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微乳液法制备Pt/Al2O3催化剂及其催化氯代硝基苯选择加氢活性

宋 华1,汪淑影1,李 锋1,李瑞峰2   

  1. 1东北石油大学化学化工学院,黑龙江 大庆163318;2大庆化工研究中心,黑龙江 大庆 163714
  • 出版日期:2011-04-05 发布日期:2011-04-05

Preparation of Pt/Al2O3 catalyst by microemulsion and its activity in selective hydrogenation of chloronitrobenzene

SONG Hua1,WANG Shuying1,LI Feng1,LI Ruifeng2   

  1. 1School of Chemistry and Chemical Engineering,Northeast Petroleum University,Daqing 163318,Heilongjiang,China;2Daqing Chemical Engineering Research Center,Daqing 163714,Heilongjiang,China
  • Online:2011-04-05 Published:2011-04-05

摘要:

采用十六烷基三甲基溴化铵(CTAB/正丁醇/环己烷/H2PtCl6溶液的微乳体系,以N2H4·H2O为还原剂,Al2O3为载体制备Pt/Al2O3催化剂。以邻氯硝基苯(o-CNB)选择加氢反应为探针,考察微乳液组成对Pt/Al2O3催化剂选择加氢活性的影响。运用XRDXPSIRTEMEDS对载体和催化剂进行表征。结果表明,微乳体系中CTAB正丁醇环己烷质量比921703.6% H2PtCl6溶液中制备的Pt/Al2O3催化剂的o-CNB选择加氢活性最高。Pt粒子粒径5 nm左右,与载体之间没有明显的电子效应。对于取代位置不同的间、对氯硝基苯(m-CNBp-CNB)加氢,Pt/Al2O3催化剂也表现出较高的催化活性。

Abstract:

Pt/Al2O3 catalyst was prepared from CTAB/butarol/cyclohexane/H2PtCl6 microemulsionwith hydrazine as reductant and Al2O3 as support. The effect of composition of microemulsion on the activity for selective hydrogenation over Pt/Al2O3 catalysts was studied by using o-chloronitrobenzene selective hydrogenation as a probe reaction. The support and catalyst were characterized by XRDXPSIRTEM and EDS.  The results showed that the Pt/Al2O3 catalyst made from the microemulsion with CTABbutarolcyclohexane mass ratio of 92170 and H2PtCl6 concentration of 3.6% exhibited the highest activity in selective hydrogenation of o-CNB. Pt particle size was about 5 nmand the electronic effect between Pt particle and carrier was not significant. It was also found that Pt/Al2O3 catalyst also exhibited higher activity for the hydrogenation of m-chloronitrobenzene and p-chloronitrobenzene with different substituted positions.

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