化工进展

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铜/氧化锆催化剂的制备及应用研究进展

王 嵩,毛东森,吴贵升,郭晓明,卢冠忠   

  1. 上海应用技术学院化学工程系应用催化研究所;华东理工大学工业催化研究所
  • 出版日期:2008-06-05 发布日期:2008-06-05

Progress in preparation and application of zirconia-supported copper catalysts

WANG Song,MAO Dongsen,WU Guisheng,GUO Xiaoming,LU Guanzhong   

  1. Research Institute of Applied Catalysis,Department of Chemical Engineering,Shanghai Institute of Technology; Research Institute of Industrial Catalysis,East China University of Science and Technology
  • Online:2008-06-05 Published:2008-06-05

摘要: 介绍了Cu/ZrO2催化剂的制备方法,阐述了助剂对Cu/ZrO2催化剂物化及催化性能的影响,综述了Cu/ZrO2催化剂在CO和/或CO2加氢合成甲醇、醇类水蒸气重整制氢、二乙醇胺脱氢合成亚氨基二乙酸盐、环己醇脱氢制环己酮和环己醇还原氨化制环己胺反应中的应用。

Abstract: The preparation methods of the Cu/ZrO2 catalyst are introduced. The effects of promoters on the physiochemical and catalytic properties of the Cu/ZrO2 catalyst are presented. The applications of the Cu/ZrO2 catalyst in the synthesis of methanol from hydrogenation of CO and/or CO2,production of hydrogen from steam reforming of alcohols,dehydrogenation of diethanolamine to diglycolamidic salt,dehydrogenation of cyclohexanol to cyclohexanone,and reductive amination of cyclohexanol to cyclohexylamine are summarized.

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