Abstract: The preparation of heterogeneous chiral catalysts for asymmetric hydrogenation by the immobilization of homogeneous catalysts on polymer，Fe₃O₄ nanoparticles or functionalized molecular sieves was reviewed. The interaction between the negatively charged molecular sieve framework and the cation of the organometallic complex; modification of chiral micromolecular (such as Cinchona alkaloid) and application of natural chiral biopoly mers were discussed. Their activities，enantioselectivities，and characteristics in asymmetric hydrogenation were also introduced.